PRIPOLC36 dimer diacid | 96672-94-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: PRIPOLC36 dimer diacid
• 英文别名: EMPOL 1008 C36 dimer diacid；10,11-Dioctyl-eikosandisaeure；10,11-dioctylicosanedioic Acid
• CAS: 96672-94-5
• 化学式: C₃₆H₇₀O₄
• 分子量: 566.949
• InChiKey: CDPWAVDXAFFUOR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.6
• 重原子数：
  40
• 可旋转键数：
  33
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  PRIPOLC36 dimer diacid 、 乙二胺 在 4-二甲氨基吡啶 N,N'-二环己基碳二亚胺 作用下， 以 二氯甲烷 为溶剂， 反应 2.33h， 生成 N,N'-bis(2-aminoethyl)-10,11-dioctylicosanediamide
  参考文献：
  名称：

  Process for making curable amide gellant compounds

  摘要：

  本发明揭示了一种制备式为的化合物的方法，其中R1是具有至少一个乙烯不饱和度的烷基基团、具有至少一个乙烯不饱和度的芳基烷基基团或具有至少一个乙烯不饱和度的烷基芳基基团，R2和R3各自独立地是烷基、芳基、芳基烷基或烷基芳基基团，R4和R5各自独立地是氢原子或烷基基团，n是表示重复酰胺单位数的整数，且至少为1，所述方法包括：(a)在催化剂、溶剂和偶联剂存在下，反应式为HOOC-R2-COOH的二酸和式为的二胺以形成寡酰胺中间体；(b)将寡酰胺中间体与式为R1-OH的醇反应以形成产物。

  公开号：

  US07271284B2
• 作为产物：
  描述：

  油酸 以 水 为溶剂， 170.0 ℃ 、2.76 MPa 条件下， 反应 3.0h， 生成 PRIPOLC36 dimer diacid 、 硬脂酸
  参考文献：
  名称：

  饱和甲基支链脂肪酸异构体的选择性微生物降解

  摘要：

  AbstractThree strains of Pseudomonas (P.) bacteria were screened for their capabilities of degrading chemically synthesized saturated branched‐chain fatty acids (sbc–FA). Mixtures of sbc–FA with the methyl‐branch located at various locales along the fatty acid were used as a carbon feedstock in shake‐flask culture. Utilization (and hence degradability) of the sbc–FA was monitored based on positive bacterial growth, fatty acid recovery rates and chromatographic (gas chromatography (GC) and GC‐mass spectroscopy (MS)) analysis of the recovered carbon source. P. putida KT2442 and P. oleovorans NRRL B‐14683 were both able to grow on sbc–FA utilizing 35 wt% and 27 wt% of the carbon source, respectively after 144 h. In contrast, P. resinovorans NRRL B‐2649 exhibited the most efficient use of the carbon source by utilizing 89 % of the starting material after 96 h resulting in a cell dry weight (CDW) of 3.1 g/L. GC and GC–MS analysis of the recovered carbon source revealed that the bacterial strains selectively utilized the isostearic acid in the sbc–FA mixture, and a new group of C10, C12, C14 and C16‐linear and/or branched‐chain fatty acids (approximately 4–29 wt%) were formed during degradation.

  DOI：

  10.1007/s11746-012-2092-0

文献信息

• Process for preparing amide gellant compounds with aromatic end groups
  申请人：Chopra Naveen

  公开号：US08581000B2

  公开（公告）日：2013-11-12

  Disclosed is a process for preparing a compound of the formula wherein R1 and R1′, R2 and R2′, and R3 are as defined herein, said process comprising (I) reacting a diacid of the formula HOOC—R2—COOH with a diamine of the formula H2N—R3—NH2 to form an acid-terminated oligoamide intermediate of the formula HOOC—R2—CONH—R3—HNCO—R2′—COOH; and (II) reacting the acid-terminated oligoamide intermediate with a monoalcohol of the formula R1—OH in the presence of a tin or organic titanate catalyst, in the absence of a coupling agent, and in the absence of a solvent to form the product. Also disclosed is a composition prepared by the process.

  本发明揭示了一种制备公式化合物的方法，其中R1和R1'，R2和R2'，以及R3如此定义，所述方法包括(I)将公式HOOC-R2-COOH的二酸与公式H2N-R3-NH2的二胺反应，形成公式HOOC-R2-CONH-R3-HNCO-R2'-COOH的酸端寡聚酰胺中间体；和(II)在无偶联剂和无溶剂的情况下，在锡或有机钛催化剂的存在下，将酸端寡聚酰胺中间体与公式R1-OH的单醇反应，形成产物。本发明还揭示了由该方法制备的组合物。
• Organic Phase Change Carriers Containing Nanoparticles, Phase Change Inks Including Same and Methods for Making Same
  申请人：Breton Marcel P.

  公开号：US20070283846A1

  公开（公告）日：2007-12-13

  Disclosed is an organic phase change carrier and a method for forming same, and a phase change ink including same. The organic phase change carrier comprises a colloidal dispersion of nanoparticles exhibiting a substantially uniform distribution of said nanoparticles discretely distributed therewithin, at least one curable monomer; a phase change inducing component, and an initiator. The organic phase change carrier exhibits a substantially uniform distribution of the nanoparticles so that they are discretely distributed therewithin, and are substantially resistant to the aggregation of the nanoparticles distributed therewithin.

  本发明公开了一种有机相变载体及其制备方法，以及包括该载体的相变墨水。所述有机相变载体包括一种胶体分散体，其中包含一种呈现出基本均匀分布的纳米粒子，至少一种可固化单体，一种相变诱导成分和一种引发剂。所述有机相变载体呈现出纳米粒子的基本均匀分布，以便它们被离散地分布在其中，并且对分布在其中的纳米粒子聚集具有相当的抵抗力。
• ORGANIC PHASE CHANGE CARRIERS CONTAINING NANOPARTICLES, PHASE CHANGE INKS INCLUDING SAME AND METHODS FOR MAKING SAME
  申请人：Breton Marcel P.

  公开号：US20100116424A1

  公开（公告）日：2010-05-13

  Disclosed is an organic phase change carrier and a method for forming same, and a phase change ink including same. The organic phase change carrier comprises a colloidal dispersion of nanoparticles exhibiting a substantially uniform distribution of said nanoparticles discretely distributed therewithin, at least one curable monomer; a phase change inducing component, and an initiator. The organic phase change carrier exhibits a substantially uniform distribution of the nanoparticles so that they are discretely distributed therewithin, and are substantially resistant to the aggregation of the nanoparticles distributed therewithin.

  本发明公开了一种有机相变载体及其制备方法，以及包含该载体的相变墨水。该有机相变载体包括一种胶体分散体，其中包含一种呈现出离散分布在其中的纳米颗粒的基本均匀分布的纳米颗粒；至少一种可固化单体；一种相变诱导组分和一种引发剂。该有机相变载体呈现出纳米颗粒的基本均匀分布，使其在其中离散分布，并且对其中分布的纳米颗粒的聚集具有相当的抵抗力。
• CURABLE GELLANT INK COMPOSITION
  申请人：Xerox Corporation

  公开号：EP3222683A1

  公开（公告）日：2017-09-27

  A curable phase change gellant ink composition including a phase change ink vehicle comprising at least one acrylate monomer, oligomer, or prepolymer; acryloylmorpholine; at least one gellant, wherein the gellant is miscible with the phase change ink vehicle; a photoinitiator; and an optional colorant.

  一种可固化相变胶凝剂油墨组合物，包括相变油墨载体，其中包含至少一种丙烯酸酯单体、低聚物或预聚物；丙烯酰吗啉；至少一种胶凝剂，其中胶凝剂可与相变油墨载体混溶；一种光引发剂；以及一种可选着色剂。
• Nanostructured Particles, Phase Change Inks Including Same and Methods for Making Same
  申请人：Xerox Corporation

  公开号：EP1918294B1

  公开（公告）日：2011-08-31