methylcyclononan | 874-99-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 英文名称: methylcyclononan
• 英文别名: methylcyclononane；Cyclononane, methyl
• CAS: 874-99-7
• 化学式: C₁₀H₂₀
• 分子量: 140.269
• InChiKey: LFYYWGDFLAUSLV-UHFFFAOYSA-N

物化性质

• 保留指数：
  1106

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  cis-1-Methyl-cyclononen 在 palladium on activated charcoal 氢气 作用下， 以 乙醚 为溶剂， 生成 methylcyclononan
  参考文献：
  名称：

  Alkali metal reduction studies of cis- and trans-bicyclo[6.1.0]nona-2,4,6-trienes in liquid ammonia. Evidence for the high basicity of monohomocyclooctatetraene dianions

  摘要：

  DOI：

  10.1021/ja00828a021

文献信息

• Synthese und NMR-Spektren von Nonafulven sowie Vergleich mit 10-Phenylnonafulven
  作者：Jürg Furrer、Peter Bönzli、Alfred Frey、Markus Neuenschwander、Peter Engel

  DOI：10.1002/hlca.19870700327

  日期：1987.5.6

  Synthesis and NMR Spectra of Nonafulvene and Comparison with 10-Phenylnonafulvene

  壬基富烯的合成，核磁共振谱图及与10-苯基壬基富烯的比较
• Amine Oxides. VIII. Medium-sized Cyclic Olefins from Amine Oxides and Quaternary Ammonium Hydroxides^1,2
  作者：Arthur C. Cope、Engelbert Ciganek、Charles F. Howell、Edward E. Schweizer

  DOI：10.1021/ja01502a053

  日期：1960.9

  Thermal decompositions of the N-oxides derived from N,N-dimethyl-1-methylcycloalk,lamines II having eight-, nine- and ten-membered rings yield olefin mixtures containing 98.6, 94.0 and 97.5%, respectively, of 1-methylcycloalkenes. Considerable amounts of the trans isomers are formed from the nine- and ten-membered N-oxides. Pyrolyses of the corresponding quaternary hydroxides produce mixtures of methylenecycloalkanes and 1-methylcycloalkenes (predominantly cis), violation of the Hofmann rule being at a maximum in the decomposition of the nine-membered quaternary hydroxide. Importance of relative product stabilities and the operation of non-bonded interactions are discussed as possible explanations for the observed directions of elimination. Thermal decompositions of the N-oxides and quaternary hydroxides of dimethylcycloalkvimethylamines IV containing eight-, nine- and ten-membered rings proceed as expected with formation of the corresponding methylenecycloalkanes.
• FURRER J.; BONZLI P.; FREY A.; NEUENSCHWANDER M.; ENGEL P., HELV. CHIM. ACTA, 70,(1987) N 3, 862-880
  作者：FURRER J.、 BONZLI P.、 FREY A.、 NEUENSCHWANDER M.、 ENGEL P.

  DOI：——

  日期：——
• Alkali metal reduction studies of cis- and trans-bicyclo[6.1.0]nona-2,4,6-trienes in liquid ammonia. Evidence for the high basicity of monohomocyclooctatetraene dianions
  作者：Steven V. Ley、Leo A. Paquette

  DOI：10.1021/ja00828a021

  日期：1974.10