3-cyanoperylene | 35426-74-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 3-cyanoperylene
• 英文别名: 3-Perylenecarbonitrile；perylene-3-carbonitrile
• CAS: 35426-74-5
• 化学式: C₂₁H₁₁N
• 分子量: 277.325
• InChiKey: NLNUJONONMSVMF-UHFFFAOYSA-N

物化性质

• 熔点：
  228 °C
• 沸点：
  534.3±19.0 °C(Predicted)
• 密度：
  1.32±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  22
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2926909090

反应信息

• 作为反应物：
  描述：

  3-cyanoperylene 在 1,4-二氧六环 、 sodium hydroxide 、 乙醇 作用下， 生成 3-perylenecarboxylic acid
  参考文献：
  名称：

  Buu-Hoi; Long, Recueil des Travaux Chimiques des Pays-Bas, 1956, vol. 75, p. 1221,1225

  摘要：

  DOI：
• 作为产物：
  描述：

  perylene-3-carbaldehyde-oxime 在 乙酸酐 作用下， 生成 3-cyanoperylene
  参考文献：
  名称：

  Buu-Hoi; Long, Recueil des Travaux Chimiques des Pays-Bas, 1956, vol. 75, p. 1221,1225

  摘要：

  DOI：

文献信息

• [EN] ZINC POLYAZAMACROCYCLIC COMPLEXES<br/>[FR] COMPLEXES POLYAZAMACROCYCLIQUES DE ZINC
  申请人：ENI SPA

  公开号：WO2016046779A1

  公开（公告）日：2016-03-31

  Zinc polyazamacrocyclic complex having the general formula (la) or (Ib), which may advantageously be used as a spectrum converter in luminescent solar concentrators (LSCs) which are in their turn capable of improving the performance of photovoltaic devices (or solar devices) selected, for example, from photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), whether on a rigid or a flexible support.

  具有一般公式（la）或（Ib）的锌聚合物大环配合物，可以优势地用作荧光太阳能浓缩器（LSC）中的光谱转换器，LSC能够改善光伏设备（或太阳能设备）的性能，例如光伏电池（或太阳能电池），光伏模块（或太阳能模块），无论是在刚性支撑还是柔性支撑上。
• A laser trapping-spectroscopy study on the photocyanation of perylene across a single micrometre-sized oil droplets/water interface: droplet-size effects on photoreaction quantum yield
  作者：Fumihiko Kitagawa、Noboru Kitamura

  DOI：10.1039/b203259g

  日期：2002.9.6

  Photoirradiation of perylene in the presence of 1,4-dicyanobenzene and NaCN in a benzonitrile (BN)/water emulsion under vigorous stirring gave 1- and 3-cyanoperylene in a total yield of 15%. For kinetic and mechanistic studies of the photoreaction, we conducted single-droplet measurements by using a laser trapping-microspectroscopy technique. Although determination of the incident light intensity absorbed by a solute in the emulsion is in general very difficult owing to strong light scattering, that in single laser-trapped BN droplets dispersed in water was successful on the basis of the photooxidation reaction of 9,10-disubstituted anthracene. The quantum yield of the photocyanation of perylene (ΦCN) was then determined to be 4.9 × 10−3. Furthermore, we found that ΦCN was linearly proportional to the inverse of the droplet radius: the reaction efficiency increased with decreasing droplet size through an increase in the surface area/volume (A/V) ratio of a droplet. This is the first demonstration of micrometre droplet size effects on the quantum yield for a photoreaction across the droplet/water interface.

  在剧烈搅拌下，1,4-二氰基苯和 NaCN 在苯腈（BN）/水乳液中对过烯烃进行光照射，可得到 1-和 3-氰基过炔，总产率为 15%。为了对光反应的动力学和机理进行研究，我们采用激光捕获-微光谱技术进行了单液滴测量。虽然由于强烈的光散射，测定乳液中溶质吸收的入射光强度通常非常困难，但根据 9,10-二取代蒽的光氧化反应，成功测定了分散在水中的单个激光捕获 BN 液滴的入射光强度。随后测定的过炔光氰化量子产率（ΦCN）为 4.9 × 10-3。此外，我们还发现 ΦCN 与液滴半径的倒数成线性关系：液滴的表面积/体积（A/V）比增加，反应效率随液滴尺寸的减小而提高。这是首次证明微米级液滴大小对液滴/水界面光反应量子产率的影响。
• Photolytically and Environmentally Stable Multilayer Structure for High Efficiency Electromagnetic Energy Conversion and Sustained Secondary Emission
  申请人：Kingsley Edward D.

  公开号：US20120080613A1

  公开（公告）日：2012-04-05

  A multilayer structure for sustained conversion of a primary electromagnetic radiation into another electromagnetic radiation characterized by a spectrum of a higher average wavelength is disclosed. Also disclosed are methods of creating and using the inventive multilayer structure.
• PHOTOLYTICALLY AND ENVIRONMENTALLY STABLE MULTILAYER STRUCTURE FOR HIGH EFFICIENCY ELECTROMAGENTIC ENERGY CONVERSION AND SUSTAINED SECONDARY EMISSION
  申请人：Kingsley Edward D.

  公开号：US20120080615A1

  公开（公告）日：2012-04-05

  A multilayer structure for use in authentication that includes an energy conversion, at least one stability enhancement layer and at least one blocking layer is disclosed. Also disclosed are methods of creating and using the inventive multilayer structure for use in authentication.
• PHOTOLYTICALLY AND ENVIRONMENTALLY STABLE MULTILAYER STRUCTURE FOR HIGH EFFICIENCY ELECTROMAGNETIC ENERGY CONVERSION AND SUSTAINED SECONDARY EMISSION
  申请人：PERFORMANCE INDICATOR, LLC

  公开号：US20130175456A1

  公开（公告）日：2013-07-11

  Disclosed is a method for converting a primary electromagnetic radiation to a longer output wavelength that includes providing an energy conversion layer having a first photoluminescent material and a second photoluminescent material, exposing the energy conversion layer to the primary electromagnetic radiation, and transferring at least a portion of absorbed energy from the first photoluminescent material to the second photoluminescent material by dipolar coupling, such that the second photoluminescent material subsequently emits the longer output wavelength.