(1R*,2S*,6R*,7S*)-10-oxa-tricyclo[5.2.1.0(2,6)]decane-3,5-dione | 41426-20-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (1R*,2S*,6R*,7S*)-10-oxa-tricyclo[5.2.1.0(2,6)]decane-3,5-dione
• 英文别名: 10-Oxa-tricyclo[5.2.1.0*2,6*]decane-3,5-dione；10-oxatricyclo[5.2.1.02,6]decane-3,5-dione
• CAS: 41426-20-4
• 化学式: C₉H₁₀O₃
• 分子量: 166.177
• InChiKey: UITACZFIINUHQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.1
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (1R*,2S*,6R*,7S*)-10-oxa-tricyclo[5.2.1.0(2,6)]decane-3,5-dione 在 五氯化磷 作用下， 以 氯仿 为溶剂， 反应 5.0h， 生成 (1R*,2S*,6R*,7S*)-5-chloro-10-oxa-tricyclo[5.2.1.0(2,6)]dec-4-en-3-one
  参考文献：
  名称：

  [EN] NOVEL HERBICIDES
  [FR] NOUVEAUX HERBICIDES

  摘要：

  公开号：

  WO2009030450A8
• 作为产物：
  描述：

  10-Oxa-tricyclo[5.2.1.0*2,6*]dec-8-ene-3,5-dione 在 钯 作用下， 以 甲醇 为溶剂， 反应 4.0h， 以to afford (1RS,2SR,6RS,7SR)-10-oxatricyclo[5.2.1.02,6]decane-3,5-dione的产率得到(1R*,2S*,6R*,7S*)-10-oxa-tricyclo[5.2.1.0(2,6)]decane-3,5-dione
  参考文献：
  名称：

  Herbicides

  摘要：

  公式（I）中的化合物，其中取代基如权利要求1所定义的那样，适用于用作除草剂。

  公开号：

  US08754242B2

文献信息

• [EN] HERBICIDALLY ACTIVE 2-(SUBSTITUTED-PHENYL)-CYCLOPENTANE-1,3-DIONE COMPOUNDS AND DERIVATIVES THEREOF<br/>[FR] COMPOSÉS DE 2-(PHÉNYL SUBSTITUÉ)-CYCLOPENTANE-1,3-DIONE PRÉSENTANT UNE ACTIVITÉ HERBICIDE, ET LEURS DÉRIVÉS
  申请人：SYNGENTA LTD

  公开号：WO2014170413A1

  公开（公告）日：2014-10-23

  The present invention relates to a compound of formula (I): wherein the substituents are as defined herein, and wherein the compound of formula (I) is optionally present as an agrochemically acceptable salt thereof. These compounds are thought to be suitable for use as herbicides. The invention therefore also relates to a method of controlling weeds, especially grassy monocotyledonous weeds, in crops of useful plants, comprising applying a compound of formula (I), or a herbicidal composition comprising such a compound, to the plants or to the locus thereof.

  本发明涉及一种化合物，其化学式为（I）：其中取代基如本文所定义，并且化合物（I）可以选择地以其农药可接受的盐的形式存在。这些化合物被认为适合用作除草剂。因此，本发明还涉及一种控制杂草的方法，特别是在有用植物的作物中控制禾本科杂草，包括将化合物（I）或包含这种化合物的除草剂组合物施用于植物或其生长地点。
• [EN] 2-(SUBSTITUTED-PHENYL)-CYCLOPENTANE-1,3-DIONE COMPOUNDS, AND DERIVATIVES THEREOF<br/>[FR] COMPOSÉS DE 2-(PHÉNYL SUBSTITUÉ)-CYCLOPENTANE-1,3-DIONES ET LEURS DÉRIVÉS
  申请人：SYNGENTA LTD

  公开号：WO2013079708A1

  公开（公告）日：2013-06-06

  The present invention relates to a compound of formula (I): wherein: X is methyl or chlorine; R1 is methyl or chlorine; R2 is hydrogen, methyl, ethyl, n-propyl, cyclopropyl, vinyl, ethynyl, fluorine, chlorine, bromine, methoxy, ethoxy or fluoromethoxy; and G, R3, R4, R5 and R6 are as defined herein; wherein the compound of formula (I) is optionally present as an agrochemically acceptable salt thereof. These compounds are suitable for use as herbicides. The invention therefore also relates to a method of controlling weeds, especially grassy monocotyledonous weeds, in crops of useful plants, comprising applying a compound of formula (I), or a herbicidal composition comprising such a compound, to the plants or to the locus thereof.

  本发明涉及一种具有以下式（I）的化合物：其中：X为甲基或氯；R1为甲基或氯；R2为氢、甲基、乙基、正丙基、环丙基、乙烯基、乙炔基、氟、氯、溴、甲氧基、乙氧基或氟甲氧基；以及G、R3、R4、R5和R6如本文所定义；其中式（I）的化合物可以作为农药中可接受的盐存在。这些化合物适用于用作除草剂。因此，本发明还涉及一种控制杂草，特别是草本单子叶杂草，在有用植物作物中的方法，包括将式（I）的化合物或包含这种化合物的除草剂组合物施用于植物或其生长地点。
• 2-(SUBSTITUTED-PHENYL)-CYCLOPENTANE-1,3-DIONE COMPOUNDS, AND DERIVATIVES THEREOF
  申请人：Syngenta Limited

  公开号：US20140323303A1

  公开（公告）日：2014-10-30

  The present invention relates to a compound of formula (I): wherein: X is methyl or chlorine; R 1 is methyl or chlorine; R 2 is hydrogen, methyl, ethyl, n-propyl, cyclopropyl, vinyl, ethynyl, fluorine, chlorine, bromine, methoxy, ethoxy or fluoromethoxy; and G, R 3 , R 4 , R 5 and R 6 are as defined herein; wherein the compound of formula (I) is optionally present as an agrochemically acceptable salt thereof. These compounds are suitable for use as herbicides. The invention therefore also relates to a method of controlling weeds, especially grassy monocotyledonous weeds, in crops of useful plants, comprising applying a compound of formula (I), or a herbicidal composition comprising such a compound, to the plants or to the locus thereof.

  本发明涉及一种具有以下式（I）的化合物：其中：X为甲基或氯；R1为甲基或氯；R2为氢、甲基、乙基、正丙基、环丙基、乙烯基、乙炔基、氟、氯、溴、甲氧基、乙氧基或氟甲氧基；以及G、R3、R4、R5和R6如本文所定义；其中该式（I）的化合物可以作为农药可接受的盐存在。这些化合物适用于用作除草剂。因此，本发明还涉及一种控制杂草，特别是草本单子叶杂草，在有用植物作物中的方法，包括将式（I）的化合物或包含这种化合物的除草剂组合物施用于植物或其生长地点。
• [EN] HERBICIDALLY ACTIVE (ALKYNYL-PHENYL)-SUBSTITUTED CYCLIC DIONE COMPOUNDS AND DERIVATIVES THEREOF<br/>[FR] COMPOSÉS DIONE CYCLIQUES (ALKYNYL-PHÉNYLE)-SUBSTITUÉS À ACTIVITÉ HERBICIDE ET LEURS DÉRIVÉS
  申请人：SYNGENTA LTD

  公开号：WO2014191534A1

  公开（公告）日：2014-12-04

  The present invention relates to a compound of formula (I): wherein: X is methyl or chlorine; R1 is fluorine or bromine; R2 is ethynyl, C1-C3alkoxy, C1-C3haloalkoxy, or C1-C3alkoxy-C1-C3alkoxy-; and Q is a pyran-3,5-dione-4-yl, a thiopyran-3,5-dione-4-yl, a piperidine-3,5-dione-4-yl, a cyclopentane-1,3-dione-2-yl, a cyclohexane-1,3, 5-trione-2-yl, a cyclohexane-1,3-dione-2-yl, or a cycloheptane-1,3-dione-2-yl, or a derivative thereof (e.g. a fused such as fused bicyclic derivative, and/or a spirocyclic derivative), or an enol ketone tautomer derivative thereof, wherein Q is further defined herein; and wherein the compound of formula (I) is optionally present as an agrochemically acceptable salt thereof. Preferably, X is methyl; and/or R1 is fluorine; and/or R2 is -O-R2A, wherein R2A is methyl, ethyl, trifluoromethyl, difluoromethyl, trifluoroethyl, or -CH2CH2OCH3. These compounds are suitable for use as herbicides. The invention therefore also relates to a method of controlling weeds, especially grassy monocotyledonous weeds, in crops of useful plants, comprising applying a compound of formula (I), or a herbicidal composition comprising such a compound, to the weeds and/or to the plants and/or to the locus thereof.

  本发明涉及一种具有以下结构的化合物（I）：其中：X是甲基或氯；R1是氟或溴；R2是乙炔基，C1-C3烷氧基，C1-C3卤代烷氧基，或C1-C3烷氧基-C1-C3烷氧基；Q是吡喃-3,5-二酮-4-基，硫代吡喃-3,5-二酮-4-基，哌啶-3,5-二酮-4-基，环戊二酮-2-基，环己三酮-2-基，环己二酮-2-基，或环庚二酮-2-基，或其衍生物（例如，融合的如融合的双环衍生物和/或螺环衍生物），或其烯醇酮互变异构体衍生物，其中Q在此进一步定义；化合物（I）可作为农药接受的盐存在。优选，X是甲基；和/或R1是氟；和/或R2是-O-R2A，其中R2A是甲基，乙基，三氟甲基，二氟甲基，三氟乙基，或-CH2CH2OCH3。这些化合物适用于作为除草剂使用。因此，本发明还涉及一种控制杂草，特别是草本单子叶杂草，在有用植物作物中的方法，包括将化合物（I）或含有该化合物的除草剂组合物施用于杂草和/或植物和/或其生长环境。
• [EN] HERBICIDALLY ACTIVE 2-(SUBSTITUTED-PHENYL)-CYCLOPENTANE-1,3-DIONE COMPOUNDS AND DERIVATIVES THEREOF<br/>[FR] COMPOSÉS DE 2-(PHÉNYL SUBSTITUÉ)-CYCLOPENTANE-1,3-DIONE À ACTIVITÉ HERBICIDE ET LEURS DÉRIVÉS
  申请人：SYNGENTA LTD

  公开号：WO2014195327A1

  公开（公告）日：2014-12-11

  The present invention relates to a compound of formula (I): wherein: R8 and R9, independently of each other, are hydrogen, fluorine or C1-C3alkyl; R10 is hydrogen or methyl (preferably hydrogen); and the other substituents are as defined herein; and wherein the compound of formula (I) is optionally present as an agrochemically acceptable salt thereof. These compounds are thought to be suitable for use as herbicides. The invention therefore also relates to a method of controlling weeds, especially grassy monocotyledonous weeds, in crops of useful plants, comprising applying a compound of formula (I), or a herbicidal composition comprising such a compound, to the plants or to the locus thereof.

  本发明涉及一种化合物，其化学式为（I）：其中：R8和R9，独立地，分别为氢、氟或C1-C3烷基；R10为氢或甲基（最好是氢）；其它取代基的定义如本文所述；化合物的化学式（I）可选择地存在于其农药学上可接受的盐中。这些化合物被认为适用于用作除草剂。因此，本发明还涉及一种控制杂草，特别是草本单子叶杂草，在有用植物作物中的方法，包括将化合物的化学式（I）或包含这种化合物的除草剂组合物施用于植物或其生长地点。