N-phenyl-2-(phenylamino)-2-thioxoacetamide | 78121-70-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-phenyl-2-(phenylamino)-2-thioxoacetamide
• 英文别名: 2-anilino-N-phenyl-2-sulfanylideneacetamide
• CAS: 78121-70-7
• 化学式: C₁₄H₁₂N₂OS
• 分子量: 256.328
• InChiKey: FYPFCJBVOFXOGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  73.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-phenyl-2-(phenylamino)-2-thioxoacetamide 在 sodium hydroxide 、 双氧水 作用下， 生成 草酰苯胺
  参考文献：
  名称：

  Frerichs; Wildt, Justus Liebigs Annalen der Chemie, 1908, vol. 360, p. 110

  摘要：

  DOI：
• 作为产物：
  描述：

  草酰苯胺 在 劳森试剂 作用下， 以 甲苯 为溶剂， 以80 %的产率得到N-phenyl-2-(phenylamino)-2-thioxoacetamide
  参考文献：
  名称：

  带有N,N'-二芳基二草酰胺酯和N,N'-二芳基二硫代草酰胺酯配体的铝配合物在ε-己内酯开环聚合中的比较研究

  摘要：

  本研究合成了一系列具有N , N'-二芳基草酰胺酯和N , N'-二芳基二硫代草酰胺酯配体的Al催化剂，并测定了它们的ε-己内酯聚合速率。在带有N , N '-二芳基二硫代草酰胺酸酯的 Al 配合物中，[Ph H NCS] 2 Al 2 Me 4表现出最高的催化活性（聚ε-己内酯的转化率 = 94%；[ε-己内酯]:[ [ Ph H NCS] 2 Al 2 Me 4 ]:[苯甲醇] = 100:0.5:2，[ε-己内酯] = 2 M，在 25 °C 下 20 分钟后），以及带有 N , N '-二芳基二草酰胺酸酯的Al配合物，[Ph H NCO] 2 Al 2 Me 4表现出最高的催化活性（聚ε-己内酯的转化率 = 94%；[ε-己内酯]:[ O H Al 2 Me 4 ]:[苯甲醇] = 100： 0.5:2，[ε-己内酯] = 2 M，25 °C，30 分钟后）。带有N , N'-二芳

  DOI：

  10.1021/acs.organomet.3c00317

文献信息

• Domino Reactions of 1,2-Diimidoyl-1,2-dichloroethanes. Synthesis of 3-Imino-1,2-dithia-3<i>H</i>-cyclopent-4-enes, 3-Amino-2-thioxo-2,5<i>H</i>-pyrrol-5-ones, 2,3-Diamino-4-thioxo-4<i>H</i>-thiopyrans, and 6-Imino-6<i>H</i>-1,3-oxazines
  作者：Esen Bellur、Helmar Görls、Peter Langer

  DOI：10.1021/jo052450l

  日期：2006.3.1

  The reaction of mono- and dilithiated ethyl thioglycolate with 1,2-diimidoyl-1,2-dichloroethanes, aza-analogues of oxalyl chloride, afforded (depending on the reaction conditions) 3-imino-1,2-dithia-3H-cyclopent-4-enes, 3-amino-2-thioxo-2,5H-pyrrol-5-ones, and 2,3-diamino-4-thioxo-4H-thiopyrans. The reaction of the dianion of ethyl hippurate with 1,2-diimidoyl-1,2-dichloroethanes afforded 6-imino-6H-1

  单-和二锂化巯基乙酸乙酯与1,2- diimidoyl -1,2-二氯乙烷，草酰氯氮杂类似物，得到（取决于反应条件）3-亚氨基-1,2-二硫杂3的反应ħ -环戊-4-烯，3-氨基-2-硫代氧杂2，5 H-吡咯-5-酮和2，3-二氨基-4-硫代氧杂4 H-噻喃。马来酸乙酯的二价阴离子与1,2-二亚氨基-1,2-二氯乙烷的反应，得到6-亚氨基-6 H -1,3-恶嗪。
• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。
• Non-toxic corrosion-protection pigments based on rare earth elements
  申请人：——

  公开号：US20040104377A1

  公开（公告）日：2004-06-03

  A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.

  一种缓蚀颜料，由稀土元素和价态稳定剂结合形成稀土/价态稳定剂复合物。稀土元素选自铈、铽、镨或它们的组合，至少有一种稀土元素处于四价氧化态。使用无机或有机材料来稳定四价稀土离子，以形成稀溶于水的化合物。选择特定的稳定剂是为了控制四价铈、铽或镨在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。本文介绍了许多稀土-价稳定剂组合，其性能可与传统的六价铬体系媲美。
• Shibata, Kogyo Kagaku zasshi / Journal of the Society of Chemical Industry, 1929, vol. 32, p. 953,956
  作者：Shibata

  DOI：——

  日期：——
• Shibata, Technology Reports of the Tohoku University, 1929, vol. 8, p. 497,503
  作者：Shibata

  DOI：——

  日期：——