4,12-Dioxa-1,7,9,15-tetrathia-8-stannaspiro[7.7]pentadecane | 88127-75-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4,12-Dioxa-1,7,9,15-tetrathia-8-stannaspiro[7.7]pentadecane
• CAS: 88127-75-7；88079-62-3
• 化学式: C₈H₁₆O₂S₄Sn
• 分子量: 391.188
• InChiKey: AHSGVLLBSMJDGV-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  -0.19
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  22.5
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  四氯化锡 、 2-巯基乙醚 在 Na 作用下， 以 乙醇 、 苯 为溶剂， 以52%的产率得到4,12-Dioxa-1,7,9,15-tetrathia-8-stannaspiro[7.7]pentadecane
  参考文献：
  名称：

  Crystal and molecular structures of spiro-bis(trithiastannocane), Sn(SCH2CH2SCH2CH2S)2, and spiro-bis(oxadithiastannocane), Sn(SCH2CH2OCH2CH2S)2. Distortion of the SnS4 tetrahedral coordination produced by transannular Sn⋯X (X = S, O) interactions

  摘要：

  The title compounds, prepared from X(CH2CH2SNa)(2) (X = S, O) and SnCl4 were investigated by X-ray diffraction. In both compounds transannular secondary Sn ... X interactions in the eight-membered rings produce a distortion of the SnS4 tetrahedron. This consists of an enlargement of S-Sn-S angle [to 126.1 degrees when X = S and 118.9 degrees (118.4 degrees) when X = O] with simultaneous decrease of the opposite tetrahedral angle [to 93.2 degrees when X = S and 94.4 degrees (93.2 degrees) when X = O]. The coordination geometry in both compounds can be described as based upon a bicapped tetrahedron.

  DOI：

  10.1016/0277-5387(94)00302-u

文献信息

• Tzschach, A.; Scheer, M.; Jurkschat, K., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Tzschach, A.、Scheer, M.、Jurkschat, K.、Zschunke, A.、Muegge, C.

  DOI：——

  日期：——
• TZSCHACH, A.;SCHEER, M.;JURKSCHAT, K.;ZSCHUNKE, A.;MUEGGE, C., Z. ANORG. UND ALLG. CHEM., 1983, 502, N 7, 158-164
  作者：TZSCHACH, A.、SCHEER, M.、JURKSCHAT, K.、ZSCHUNKE, A.、MUEGGE, C.

  DOI：——

  日期：——
• Crystal and molecular structures of spiro-bis(trithiastannocane), Sn(SCH2CH2SCH2CH2S)2, and spiro-bis(oxadithiastannocane), Sn(SCH2CH2OCH2CH2S)2. Distortion of the SnS4 tetrahedral coordination produced by transannular Sn⋯X (X = S, O) interactions
  作者：Raymundo Cea-Olivares、Viviana Lomelí、Simón Hernández-Ortega、Ionel Haiduc

  DOI：10.1016/0277-5387(94)00302-u

  日期：1995.3

  The title compounds, prepared from X(CH2CH2SNa)(2) (X = S, O) and SnCl4 were investigated by X-ray diffraction. In both compounds transannular secondary Sn ... X interactions in the eight-membered rings produce a distortion of the SnS4 tetrahedron. This consists of an enlargement of S-Sn-S angle [to 126.1 degrees when X = S and 118.9 degrees (118.4 degrees) when X = O] with simultaneous decrease of the opposite tetrahedral angle [to 93.2 degrees when X = S and 94.4 degrees (93.2 degrees) when X = O]. The coordination geometry in both compounds can be described as based upon a bicapped tetrahedron.