1,4-bis[(2-propenyloxy)methyl]cyclohexane | 5592-70-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,4-bis[(2-propenyloxy)methyl]cyclohexane
• 英文别名: 1,4-bis(prop-2-enoxymethyl)cyclohexane
• CAS: 5592-70-1
• 化学式: C₁₄H₂₄O₂
• 分子量: 224.343
• InChiKey: XVDVZDBFCWQINP-UHFFFAOYSA-N

物化性质

• 沸点：
  94-95 °C(Press: 0.8 Torr)
• 密度：
  0.895±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,4-bis[(2-propenyloxy)methyl]cyclohexane 在 sodium silicate 、 双氧水 作用下， 以 甲醇 、 水 、 乙腈 为溶剂， 反应 11.0h， 以85.5%的产率得到1,4-双[(缩水甘油氧)甲基]环己烷
  参考文献：
  名称：

  METHOD FOR PRODUCING EPOXY COMPOUND BY OXIDATION

  摘要：

  公开号：

  EP2602251B1
• 作为产物：
  描述：

  1,4-环己烷二甲醇 、 3-溴丙烯 在 sodium hydroxide 、 四丁基溴化铵 作用下， 以 甲苯 为溶剂， 生成 1,4-bis[(2-propenyloxy)methyl]cyclohexane
  参考文献：
  名称：

  REACTIVE ORGANOSILICON COMPOUNDS

  摘要：

  公开号：

  EP0869964B1

文献信息

• Reactive organosilicon compounds
  申请人：E. I. du Pont de Nemours and Company

  公开号：US05719251A1

  公开（公告）日：1998-02-17

  Organosilicon compounds are described which contain a cyclic organic moiety between at least two reactive silane groups. The compounds are useful in coatings, adhesives, and sealants, and the like.

  描述了含有至少两个反应性硅烷基之间的环状有机基团的有机硅化合物。这些化合物在涂料、粘合剂、密封剂等方面有用。
• CONDUCTIVE ADHESIVE, ANISOTROPIC CONDUCTIVE FILM AND ELECTRONIC DEVICES USING BOTH
  申请人：SHOWA DENKO K.K.

  公开号：US20160060490A1

  公开（公告）日：2016-03-03

  [Problem] To provide: a conductive adhesive which contains an epoxy (meth)acrylate resin and which can form a bonded zone that is not susceptible to being deteriorated by halogen; an anisotropic conductive film; and electronic devices using both. [Solution] A conductive adhesive and an anisotropic conductive film which each contain a conductive filler and a binder resin, wherein: the binder resin comprises an epoxy (meth)acrylate resin that is a product of addition reaction of (meth)acrylic acid and an epoxy compound having a sum of total chlorine atom concentration and total bromine atom concentration of 300 massppm or less, preferably 50 massppm or less; and the conductive filler is dispersed in the binder resin which comprises such an epoxy (meth)acrylate resin. The epoxy (meth)acrylate resin is preferably prepared by subjecting a starting compound (substrate) having a carbon-carbon double bond to epoxidation of the double bond with an oxidizing agent consisting of hydrogen peroxide, and then subjecting the obtained epoxy compound to addition reaction with (meth)acrylic acid.

  [问题] 提供一种导电粘合剂，其中包含环氧（甲基）丙烯酸酯树脂，可以形成一个不容易被卤素恶化的粘合区域；一种各向异性导电膜；以及同时使用两种的电子设备。 [解决方案] 一种导电粘合剂和一种各向异性导电膜，它们各自包含导电填料和粘合剂树脂，其中：粘合剂树脂包括环氧（甲基）丙烯酸酯树脂，是由（甲基）丙烯酸和总氯原子浓度和总溴原子浓度之和小于300质量ppm，优选小于50质量ppm的环氧化合物进行加成反应制得的；导电填料分散在包含这种环氧（甲基）丙烯酸酯树脂的粘合剂树脂中。环氧（甲基）丙烯酸酯树脂最好是通过将具有碳-碳双键的起始化合物（基质）经过过氧化氢的双键环氧化，然后将所得到的环氧化合物与（甲基）丙烯酸进行加成反应制备而成。
• PHOTOCURABLE COMPOSITION AND CURED PRODUCT
  申请人：Kaneka Corporation

  公开号：EP2343326A1

  公开（公告）日：2011-07-13

  It is an object of the present invention to provide: a curable composition that has photocurability and provides a cured product excellent in insulating properties; and the cured product. This can be achieved by a photocurable composition that contains, as essential components, (A) a modified polyorganosiloxane compound having a photopolymerizable functional group and an SiH group, (B) a compound having a carbon-carbon double bond, and (C) a photopolymerization initiator. A thin film produced from the curable composition of the present invention has excellent insulating properties. Since the curable composition of the present invention can form a film by solution coating, it is applicable to provide thin-film insulating materials that can be formed by solution coating.

  本发明的目的是提供：一种具有光可控性并能提供绝缘性能优异的固化产品的可固化组合物；以及固化产品。本发明的目的可以通过一种光固化组合物来实现，该组合物的基本成分包括：(A) 具有可光聚合官能团和 SiH 基团的改性聚有机硅氧烷化合物；(B) 具有碳碳双键的化合物；(C) 光聚合引发剂。用本发明的可固化组合物制成的薄膜具有优异的绝缘性能。由于本发明的可固化组合物可通过溶液涂覆形成薄膜，因此适用于提供可通过溶液涂覆形成薄膜的绝缘材料。
• Manufacture of epoxyethyl ethers or glycidyl ethers
  申请人：Momentive Specialty Chemicals Research Belgium S.A.

  公开号：EP2357180A1

  公开（公告）日：2011-08-17

  The invention relates to a process for the manufacture of an epoxyethyl ether or glycidyl ether by catalytic oxidation of a vinyl or allyl ether using an oxidant, preferably hydrogen peroxide, and a manganese complex wherein the catalytic oxidation is performed in an aqueous reaction medium, comprising water with less than 10% by volume of cosolvents, wherein a water-soluble manganese complex is used as oxidation catalyst, characterized in that the water-soluble manganese complex is a mononuclear species of the general formula (I): [LMnX3]Y (I) or a binuclear species of the general formula (II): [LMn(µ-X)3MnL]Y2 (II) wherein Mn is a manganese; L or each L independently is a polydentate ligand, each X independently is a coordinating species and each µ-X independently is a bridging coordinating species, whereas Y is an oxidatively-stable counter ion, and wherein the epoxidation is carried out at a pH in the range of from 1.0 to 6.0. This invention also relates to epoxyethyl ethers.

  本发明涉及一种通过使用氧化剂（最好是过氧化氢）和锰络合物对乙烯基醚或烯丙基醚进行催化氧化来制造环氧乙基醚或缩水甘油醚的工艺，其中催化氧化是在水性反应介质中进行的，该介质包括水和少于10%体积的共溶剂，其中水溶性锰络合物被用作氧化催化剂、 其特征在于，水溶性锰络合物是通式（I）的单核物质： [LMnX3]Y (I) 或通式（II）的双核物质： [LMn(µ-X)3MnL]Y2 (II) 其中 Mn 是锰；L 或每个 L 独立地是多齿配位体，每个 X 独立地是配位体，每个 µ-X 独立地是桥接配位体，而 Y 是氧化性稳定的反离子，其中环氧化是在 pH 值为 1.0 至 6.0 的范围内进行的。 本发明还涉及环氧乙基醚。
• CURABLE RESIN COMPOSITION, CURED ARTICLE, FUEL CELL, AND SEALING METHOD
  申请人：Three Bond Co., Ltd.

  公开号：EP3486288A1

  公开（公告）日：2019-05-22

  The present invention aims to provide a curable resin composition which has low viscosity as well as properties such as rubber physical property and hydrogen gas barrier property. The present invention provides a curable resin composition comprising the following ingredients (A) to (D): ingredient (A): a vinyl-based polymer having one or more alkenyl groups in one molecule, ingredient (B): a compound having one or more hydrosilyl groups in one molecule, ingredient (C): a hydrosilylation catalyst, and ingredient (D): a plasticizer having at least two peaks in a molecular weight distribution measured by GPC.

  本发明旨在提供一种可固化树脂组合物，该组合物具有低粘度以及橡胶物理性能和氢气阻隔性能等特性。本发明提供了一种可固化树脂组合物，该组合物包含以下成分（A）至（D）：成分 （A）：在一个分子中含有一个或多个烯基的乙烯基聚合物；成分（B）：在一个分子中含 有一个或多个氢硅基的化合物；成分（C）：氢硅烷化催化剂；以及成分（D）：在 GPC 测定的分子量分布中至少有两个峰的增塑剂。