(4Z)-4-((E)-3-(4-(dimethylamino)phenyl)allylidene)-2-phenyloxazol-5(4H)-one | 1400771-19-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (4Z)-4-((E)-3-(4-(dimethylamino)phenyl)allylidene)-2-phenyloxazol-5(4H)-one
• 英文别名: (4Z)-4-[(E)-3-[4-(dimethylamino)phenyl]prop-2-enylidene]-2-phenyl-1,3-oxazol-5-one
• CAS: 1400771-19-8
• 化学式: C₂₀H₁₈N₂O₂
• 分子量: 318.375
• InChiKey: HGXWJHWDCNQNAD-WNQIWMROSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  41.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  马尿酸 、 3-(4-dimethylamino-phenyl)-propenal 在 三聚氯氰 、 sodium carbonate 、 三苯基膦 作用下， 以 四氢呋喃 为溶剂， 反应 0.02h， 以85%的产率得到(4Z)-4-((E)-3-(4-(dimethylamino)phenyl)allylidene)-2-phenyloxazol-5(4H)-one
  参考文献：
  名称：

  溶剂辅助研磨可方便地合成4-亚芳基-2-苯基-5（4 H）-恶唑酮

  摘要：

  已经开发了一种简便而有效的合成4-亚芳基-2-苯基-5（4 H）-恶唑酮的方法。在2,4,6-三氯-1,3,5-三嗪，催化三苯膦和碳酸钠存在下的溶剂辅助研磨下，室温下几分钟之内，马来酸与芳族醛的脱水-缩合反应迅速进行，从而得到产品的良率到优等。

  DOI：

  10.1016/j.tetlet.2016.06.029

文献信息

• Light emitting markers for use with substrates
  申请人：——

  公开号：US20030015284A1

  公开（公告）日：2003-01-23

  A method of determining whether a substrate has been subjected to an energy source. In one embodiment, the method includes the steps of providing a polymeric surface, providing a light emitting material having a specified emission spectrum that changes upon exposure to an energy source on the surface or embedded in said substrate and applying said energy source to said surface with said light emitting material. This method can be particularly useful for detecting the bond quality in medical devices.

  一种确定基底是否经受过能量源的方法。在一个实施方案中，该方法包括以下步骤：提供聚合物表面；提供具有特定发射光谱的发光材料，该材料在表面或嵌入所述基底中暴露于能量源后会发生变化；将所述能量源与所述发光材料一起应用于所述表面。这种方法尤其适用于检测医疗设备的粘接质量。
• Two-photon absorption properties of push–pull oxazolones derivatives
  作者：Catarina A.B. Rodrigues、Inês F.A. Mariz、Ermelinda M.S. Maçôas、Carlos A.M. Afonso、José M.G. Martinho

  DOI：10.1016/j.dyepig.2012.06.005

  日期：2012.12

  New fluorescent oxazolone derivatives with high two-photon absorption cross-section were synthesized. Electron donor (phenyl, dimethylaniline and furanyl) and acceptor (nitrobenzene and ethenyl-phenyl-benzimidazol) groups have been appended to the methylene end of 4-(methylidene)-2-phenyl-1,3-oxazol-5(4H)-one in order to produce an highly conjugated pi-system with push pull geometry. The linear and nonlinear optical properties of the oxazolones have been determined. The compounds with a high charge transfer from the substituent group to the oxazolone ring have relatively high two-photon absorption cross-sections (80-100 GM). The best performing nonlinear fluorophore being the benzimidazol derivative with a two-photon absorption cross-section of 80 GM and a relatively high emission quantum yield, phi = 0.31. (c) 2012 Elsevier Ltd. All rights reserved.
• CURE-INDICATING MOLDING AND COATING COMPOSITION
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0767809B1

  公开（公告）日：2004-01-21
• DENTAL IMPRESSION MATERIAL WITH CURE-INDICATING DYE
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0768860A2

  公开（公告）日：1997-04-23
• 硬化指示性成形及びコーティング組成物
  申请人：スリーエム カンパニー

  公开号：JP3928070B2

  公开（公告）日：2007-06-13