10,10-Diethoxy-1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluoro-decane | 133377-48-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 10,10-Diethoxy-1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluoro-decane
• 英文别名: 2-(Perfluoro-N-octyl)acetaldehyde diethyl acetal；10,10-diethoxy-1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluorodecane
• CAS: 133377-48-7
• 化学式: C₁₄H₁₃F₁₇O₂
• 分子量: 536.229
• InChiKey: IHGUGSBDMLHOJL-UHFFFAOYSA-N

物化性质

• 沸点：
  98,5°C 10mm
• 密度：
  1,518 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  33
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  19

安全信息

• 安全说明：
  S26,S36
• 危险类别码：
  R36/37/38

反应信息

• 作为产物：
  描述：

  全氟辛基碘烷 在 锌 作用下， 以 二氯甲烷 为溶剂， 反应 10.0h， 生成 10,10-Diethoxy-1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-heptadecafluoro-decane
  参考文献：
  名称：

  Synthése de fluoroalkyl éthanl : RFCH2CHO

  摘要：

  Aldehydes RFCH2CHO (R(F) is a linear perfluoroalkyl chain) have been obtained in the addition reaction of R(F)I to vinyl acetate in the presence of zinc. RFCH2CHIOAc is formed as an intermediate in the course of the reaction. Under appropriate conditions, RFCH2CHO and its acylal or acetal derivatives are obtained in good yields.

  DOI：

  10.1016/s0040-4039(00)92222-6

文献信息

• Alkoxyperfluoroalkylation of enol ethers catalysed by iron complexes
  作者：Shin-ichi Sasaoka、Mitsunari Uno、Takashi Joh、Hideyuki Lmazaki、Shigetoshi Takahashi

  DOI：10.1039/c39910000086

  日期：——

  The iron-catalysed coupling reaction of three components, perfluoroalkyl iodides, enol ethers and alcohols, in the presence of a base gives directly perfluoroalkyl-substituted acetals in good to excellent yields.

  在碱存在下，铁催化全氟烷基碘化物、烯醇醚和醇这三种成分的偶联反应可直接生成全氟烷基取代的乙醛，收率从良好到极佳。
• Synthesis of vicinal perfluoroalkyl enol ethers
  作者：H. Zoghlami、I. Chehidi、M.M. Chaabouni、A. Baklouti

  DOI：10.1016/j.jfluchem.2004.07.001

  日期：2004.12

  A convenient preparation of vicinal perfluoroalkyl enol ethers, by the action of alcohols on 1-bromo-1-perfluoroalkylethylenes to the presence of potassium hydroxide, is described. Some aspects of their reactivity are reported. (C) 2004 Elsevier B.V. All rights reserved.
• Synthése de fluoroalkyl éthanl : RFCH2CHO
  作者：Ph. Laurent、H. Blancou、A. Commeyras

  DOI：10.1016/s0040-4039(00)92222-6

  日期：1992.4

  Aldehydes RFCH2CHO (R(F) is a linear perfluoroalkyl chain) have been obtained in the addition reaction of R(F)I to vinyl acetate in the presence of zinc. RFCH2CHIOAc is formed as an intermediate in the course of the reaction. Under appropriate conditions, RFCH2CHO and its acylal or acetal derivatives are obtained in good yields.