3-<(Z)-pentadec-8-enyl>anisole | 40586-09-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3-<(Z)-pentadec-8-enyl>anisole
• 英文别名: 3-(Pentadecen-(8c)-yl)-anisol；O-Methyl-ginkgol；1-methoxy-3-[(Z)-pentadec-8-enyl]benzene
• CAS: 40586-09-2
• 化学式: C₂₂H₃₆O
• 分子量: 316.527
• InChiKey: NLGAKMJVJUUZEQ-HJWRWDBZSA-N

物化性质

• 沸点：
  186-189 °C(Press: 0.8 Torr)
• 密度：
  0.892±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  23
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-<(Z)-pentadec-8-enyl>anisole 在 selenium 作用下， 生成 3-(pentadecen-(8t)-yl)-anisole
  参考文献：
  名称：

  Cashew Nut Shell Liquid. X. An Investigation of the Geometrical Configurations of the Olefinic Components of Cardanol and Some Observations Concerning Ginkgol¹

  摘要：

  DOI：

  10.1021/ja01536a036
• 作为产物：
  描述：

  3-(pentadec-8-ynyl)anisole 在 palladium on barium sulfate 喹啉 、 氢气 作用下， 以 乙酸乙酯 为溶剂， 反应 0.25h， 生成 3-<(Z)-pentadec-8-enyl>anisole
  参考文献：
  名称：

  Caplin, Joseph; Tyman, John H. P., Journal of Chemical Research, Miniprint, 1982, # 2, p. 321 - 351

  摘要：

  DOI：

文献信息

• CASHEW NUT SHELL LIQUID. IV. ON THE HETEROGENEOUS NATURE OF THE MONOPHENOLIC FRACTION OF CASHEW NUT SHELL LIQUID. THE STRUCTURE OF THE MONO-OLEFINIC COMPONENT¹
  作者：MEYER SLETZINGER、CHARLES R. DAWSON

  DOI：10.1021/jo01156a022

  日期：1949.7
• Backer; Haack, Recueil des Travaux Chimiques des Pays-Bas, 1941, vol. 60, p. 661,666
  作者：Backer、Haack

  DOI：——

  日期：——
• Furukawa, Scientific Papers of the Institute of Physical and Chemical Research (Japan), 1934, vol. 24, p. 314,318
  作者：Furukawa

  DOI：——

  日期：——
• The Importance of Social Context in Cross-Cultural Comparisons: First Graders in Colombia and the United States
  作者：Colleen Pilgrim、Alba Rueda-Riedle

  DOI：10.1080/00221320209598684

  日期：2002.9

  The authors explored the cultural constructs of individualism and collectivism by investigating the prosocial behavior of 1st graders (N = 202; 110 girls, 92 boys) in countries typically classified as collectivist (Colombia, South America) and individualist (United States). Contrary to expectations, U.S. children shared more than Colombian children did. However, U.S. children were more likely to take candy from another child without permission (demonstrating individualism). Results indicated that in both countries sharing was greater with friends than with other fellow classmates, and children frequently reported friendship as the reason they shared. Findings support the importance of the social context, such as the relationship between participants, in cross-cultural research and suggest that simple dichotomies of culture often overlook complex associations between culture and behavioral differences.
• Synthetic Method
  申请人：University Court of the University of St. Andrews

  公开号：US20170174608A1

  公开（公告）日：2017-06-22

  The invention relates to a method of alkene metathesis. In the method, at least one monoalkene is subjected to ethenolysis in the presence of a diene. The invention also relates to the use of a diene to promote an ethenolysis reaction conducted on a monoalkene.