ethyl 2-diethylaminopropanoate | 82614-48-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: ethyl 2-diethylaminopropanoate
• 英文别名: ethyl N,N-diethylalanine；N,N-diethyl-DL-alanine ethyl ester；N,N-Diaethyl-DL-alanin-aethylester；DL-2-Diaethylamino-propionsaeure-aethylester；N,N-Diaethyl-alanin-aethylester；Diaethyl-dl-alanin-aethylester；Diethylamino propionic acid ethyl ester；ethyl 2-(diethylamino)propanoate
• CAS: 82614-48-0
• 化学式: C₉H₁₉NO₂
• mdl: MFCD08753073
• 分子量: 173.255
• InChiKey: LLPAFEBSSXDCES-UHFFFAOYSA-N

物化性质

• 沸点：
  85-88 °C(Press: 12 Torr)
• 密度：
  0.920±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.888
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  ethyl 2-diethylaminopropanoate 在 copper chromite 、 乙醇 作用下， 175.0 ℃ 、23.53 MPa 条件下， 生成 2-(二乙基氨基)-1-丙醇
  参考文献：
  名称：

  使用径向静电应力和延伸桥形状的反馈控制来稳定导电毛细管桥

  摘要：

  使用由同心环电极施加的静电应力，密度匹配的电绝缘浴中的导电圆柱形液桥稳定在瑞利-高原 (RP) 极限之外。当细长 S=L/2R 超过 π 时，在真实或模拟零重力下，长度为 L 和半径为 R 的圆形液体圆柱体变得不稳定。初始不稳定性涉及桥的所谓 (2, 0) 模式的增长，其中一侧变薄而另一侧变圆。模式传感光学系统检测 (2, 0) 模式的增长，模拟反馈系统将适当的电压施加到位于桥端附近的一对同心环电极，以抵消 (2, 0) 模式的增长。 , 0) 模式并防止桥的断裂。导电桥在接地的金属盘之间形成。测试了三种反馈算法，发现每种算法都能够使桥梁稳定得远远超出 RP 限制。所有三种算法都稳定...

  DOI：

  10.1063/1.870354
• 作为产物：
  描述：

  Methyl(1-phenylethyl)malonsaeure-diethylester 在 盐酸 、 氢氧化钾 、 sodium azide 、 9,10-二氢蒽 、 氯甲酸乙酯 、 sodium cyanoborohydride 、 溶剂黄146 作用下， 以 乙醇 、 甲苯 、 乙腈 、 均三甲苯 为溶剂， 反应 5.0h， 生成 ethyl 2-diethylaminopropanoate
  参考文献：
  名称：

  Schulze, Rainer; Beckhaus, Hans-Dieter; Ruechardt, Christoph, Chemische Berichte, 1993, vol. 126, # 4, p. 1031 - 1038

  摘要：

  DOI：

文献信息

• Theophyllinyl-alkyl-oxadiazoles, process for the preparation thereof and
  申请人：Chinoin Gyogyszer-es Vegyeszeti Termekek Gyara R.T.

  公开号：US04565817A1

  公开（公告）日：1986-01-21

  Antitussive compounds of the formula I ##STR1## or physiologically acceptable acid addition salts thereof are disclosed, where A stands for straight or branched chain C.sub.1-5 alkylene or ##STR2## R.sub.1 stands for straight or branched chain C.sub.1-10 alkyl, halogenoalkyl, hydroxyalkyl, C.sub.5-6 cycloalkyl, vinyl, 2-ethoxyethyl, carbonylalkyl or aminoalkyl of the formula ##STR3## wherein R stands for hydrogen or methyl, n is 0 to 3, R.sub.2 stands for hydrogen or straight or branched chain alkyl, R.sub.3 stands for hydrogen or straight or branched chain alkyl or, R.sub.2 and R.sub.3 together with the nitrogen atom may form a 5-6 membered ring, which ring can optionally contain an oxygen or a second nitrogen atom, the latter, optionally substituted by methyl or, R.sub.1 can stand for a phenyl group of the formula R.sub.4 R.sub.5 C.sub.6 H.sub.3 wherein R.sub.4 and R.sub.5 represent independently hydrogen, chlorine, hydroxy, methoxy, ethoxy, methyl or amino or, R.sub.1 may further stand for hydroxy, in this case the compound of the formula I may exist according to the conditions in the form of tautomers of the formula Ia ##STR4## and R.sub.1 may further stand for benzyl, 2,2-diphenylethyl or theophyllin-7-yl-methyl.

  公开了式I的镇咳化合物或其生理上可接受的酸加合物盐，其中A代表直链或支链C.sub.1-5烷基或##STR2##，R.sub.1代表直链或支链C.sub.1-10烷基，卤代烷基，羟基烷基，C.sub.5-6环烷基，乙烯基，2-乙氧基乙基，羰基烷基或公式##STR3##的氨基烷基，其中R代表氢或甲基，n为0至3，R.sub.2代表氢或直链或支链烷基，R.sub.3代表氢或直链或支链烷基，或R.sub.2和R.sub.3与氮原子一起可以形成5-6成员环，该环可以选择性地含有一个氧或第二个氮原子，后者可以被甲基取代，或R.sub.1可以代表公式R.sub.4R.sub.5C.sub.6H.sub.3的苯基，其中R.sub.4和R.sub.5分别独立表示氢，氯，羟基，甲氧基，乙氧基，甲基或氨基，或R.sub.1还可以代表羟基，在这种情况下，公式I的化合物可以根据公式Ia的构象存在，其中R.sub.1还可以代表苄基，2,2-二苯乙基或茶碱-7-基甲基。
• POLYMERIZABLE COMPOSITION, COLOR FILTER, AND METHOD OF PRODUCING THE SAME, SOLID-STATE IMAGING DEVICE, AND PLANOGRAPHIC PRINTING PLATE PRECURSOR, AND NOVEL COMPOUND
  申请人：Makino Masaomi

  公开号：US20120176571A1

  公开（公告）日：2012-07-12

  Disclosed is a photopolymerizable composition which contains a photopolymerization initiator (A) that has a partial structure represented by the following Formula (1) and a polymerizable compound (B). In General formula (1), R 3 and R 4 each independently represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group or an alkoxy group; R 3 and R 4 may form a ring with each other; and X represents OR 5 , SR 6 , or NR 17 R 18 . The photopolymerizable composition is capable of forming a cured film that has high sensitivity, excellent intra-membrane curability and excellent adhesion to a support. The cured film is able to maintain a patterned shape even during post-heating after development and has good pattern formability, while coloring due to heating with passage of time being suppressed.

  本发明公开了一种光聚合组合物，其包含具有以下式（1）所表示的部分结构的光聚合引发剂（A）和可聚合化合物（B）。在通式（1）中，R3和R4各自独立地表示氢原子、烷基、烯基、炔基、芳基、杂芳基或烷氧基；R3和R4可以互相形成环；X表示OR5、SR6或NR17R18。该光聚合组合物能够形成具有高灵敏度、优异的内膜可固化性和与支撑体良好的附着性的固化膜。该固化膜能够在显影后的后热处理期间保持呈图案状，并具有良好的图案成形性，同时抑制由于时间加热而导致的着色。
• Polymerizable composition, color filter, and method of producing the same, solid-state imaging device, and planographic printing plate precursor, and novel compound
  申请人：Makino Masaomi

  公开号：US08691352B2

  公开（公告）日：2014-04-08

  Disclosed is a photopolymerizable composition which contains a photopolymerization initiator (A) that has a partial structure represented by the following Formula (1) and a polymerizable compound (B). In General formula (1), R3 and R4 each independently represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group or an alkoxy group; R3 and R4 may form a ring with each other; and X represents OR5, SR6, or NR17R18. The photopolymerizable composition is capable of forming a cured film that has high sensitivity, excellent intra-membrane curability and excellent adhesion to a support. The cured film is able to maintain a patterned shape even during post-heating after development and has good pattern formability, while coloring due to heating with passage of time being suppressed.

  本发明揭示了一种光聚合组合物，它包含具有以下式（1）表示的部分结构的光聚合引发剂（A）和可聚合化合物（B）。在通式（1）中，R3和R4各自独立地表示氢原子，烷基，烯基，炔基，芳基，杂芳基或烷氧基；R3和R4可以相互形成环；并且X表示OR5，SR6或NR17R18。该光聚合组合物能够形成具有高灵敏度，优异的内膜固化能力和对支撑体的优良附着力的固化膜。固化膜能够在显影后的后热处理期间保持图案形状，并具有良好的图案成形性，同时由于时间加热而引起的着色被抑制。
• PHOTOPOLYMERIZABLE COMPOSITION, COLOR FILTER, METHOD FOR PRODUCING SAME, SOLID-STATE IMAGE PICKUP ELEMENT, LIQUID CRYSTAL DISPLAY DEVICE, LITHOGRAPHIC PRINTING ORIGINAL PLATE, AND NOVEL COMPOUND
  申请人：FUJIFILM Corporation

  公开号：EP2479613A1

  公开（公告）日：2012-07-25

  Disclosed is a photopolymerizable composition which contains a photopolymerization initiator (A) that has a partial structure represented by the following Formula (1) and a polymerizable compound (B). In General formula (1), R3 and R4 each independently represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group or an alkoxy group; R3 and R4 may form a ring with each other; and X represents OR5, SR6, or NR17R18. The photopolymerizable composition is capable of forming a cured film that has high sensitivity, excellent infra-membrane curability and excellent adhesion to a support. The cured film is able to maintain a patterned shape even during post-heating after development and has good pattern formability, while coloring due to heating with passage of time being suppressed.

  本发明公开了一种可光聚合组合物，该组合物包含具有下式（1）所代表的部分结构的光聚合引发剂（A）和可聚合化合物（B）。在通式（1）中，R3 和 R4 各自独立地代表氢原子、烷基、烯基、炔基、芳基、杂芳基或烷氧基；R3 和 R4 可相互形成环；X 代表 OR5、SR6 或 NR17R18。这种可光聚合组合物能够形成具有高灵敏度、优异的膜下固化性和对支持物的优异粘附性的固化膜。固化膜即使在显影后的加热过程中也能保持图案形状，并具有良好的图案成形性，同时还能抑制因加热时间过长而引起的着色。
• Fuson, Journal of the American Chemical Society, 1928, vol. 50, p. 1446 Anm.5
  作者：Fuson

  DOI：——

  日期：——