Tetradecyl-nitrat | 24152-76-9

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: Tetradecyl-nitrat
• 英文别名: n-Tetradecylnitrat；nitric acid tetradecyl ester；Salpetersaeure-tetradecylester；1-Tetradecyl nitrate；tetradecyl nitrate
• CAS: 24152-76-9
• 化学式: C₁₄H₂₉NO₃
• 分子量: 259.389
• InChiKey: DUNXOJJZJRNHEK-UHFFFAOYSA-N

物化性质

• 沸点：
  144-145 °C(Press: 2 Torr)
• 密度：
  0.930±0.06 g/cm3(Predicted)
• 保留指数：
  1819

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  55
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  十四醇 在 硝酸 、 乙酸酐 作用下， 生成 Tetradecyl-nitrat
  参考文献：
  名称：

  Nitrate esters: Novel sex pheromone components of the cotton leafperforator, Bucculatrix thurberiella busck. (Lepidoptera: Lyonetiidae)

  摘要：

  (Z)-9-Tetradecenyl nitrate and (Z)-8-tridecenyl nitrate have been identified in volatiles from virgin female cotton leafperforator moths, Bucculatrix thurberiella, and shown to elicit electroantennogram responses from male moths. A 100:2 blend of the synthetic compounds is highly attractive to male moths in the field, and these compounds are proposed to be components of the female sex pheromone.

  DOI：

  10.1016/s0040-4039(00)61292-3

文献信息

• Schneider, Manfred; Ballschmiter, Karlheinz, Chemistry - A European Journal, 1996, vol. 2, # 5, p. 539 - 544
  作者：Schneider, Manfred、Ballschmiter, Karlheinz

  DOI：——

  日期：——
• Bouveault; Wahl, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1903, vol. 136, p. 1564
  作者：Bouveault、Wahl

  DOI：——

  日期：——
• ORGANIC NITRATES AS IGNITION ENHANCERS
  申请人：SHELL OIL COMPANY

  公开号：US20130160354A1

  公开（公告）日：2013-06-27

  A diesel fuel composition comprising an organic nitrate is described. The organic nitrate may be a terpene nitrate. Methods of using an organic nitrate for achieving a desired cetane number, and uses of organic nitrates for the purpose of reducing the ignition delay of the fuel and/or for increasing its cetane number to a defined level are also described, as are methods of operating a compression ignition engine.
• US4365973A
  申请人：——

  公开号：US4365973A

  公开（公告）日：1982-12-28
• [EN] ORGANIC NITRATES AS IGNITION ENHANCERS<br/>[FR] NITRATES ORGANIQUES EN TANT QU'AMPLIFICATEURS D'ALLUMAGE
  申请人：SHELL INT RESEARCH

  公开号：WO2013093100A1

  公开（公告）日：2013-06-27

  The use of an organic nitrate in a diesel fuel composition is described for the purpose of reducing the ignition delay of the fuel and/or for increasing its cetane number to a defined level. The organic nitrate may be a terpene nitrate. Methods of using a organic nitrate for achieving a desired cetane number, diesel fuel compositions comprising the organic nitrate, and methods of operating a compression ignition engine are also described.