2-phenyldibenzo[f,h]quinoxaline | 859798-47-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2-phenyldibenzo[f,h]quinoxaline
• 英文别名: 2-phenyl-dibenzo[f,h]quinoxaline；2-Phenyl-dibenzo[f,h]chinoxalin；3-phenylphenanthro[9,10-b]pyrazine
• CAS: 859798-47-3
• 化学式: C₂₂H₁₄N₂
• 分子量: 306.367
• InChiKey: GGTXYOVKMNRYMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  24
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  iridium(III) chloride 、 2-phenyldibenzo[f,h]quinoxaline 以 乙二醇乙醚 、 2-phenyldibenzo[f,h]quinoxaline 、 水 为溶剂， 反应 5.0h， 以78%的产率得到μ-dichloro-bis[bis(2-phenyldibenzo[f,h]quinoxalinato)iridium(III)]
  参考文献：
  名称：

  Organometallic complex, and light-emitting element, light-emitting device, and electronic device including the organometallic complex

  摘要：

  公开号：

  EP1939208B1
• 作为产物：
  描述：

  菲醌 以 四氢呋喃 、 二丁醚 、 甲苯 为溶剂， 反应 24.5h， 生成 2-phenyldibenzo[f,h]quinoxaline
  参考文献：
  名称：

  具有二苯并[f，h]喹 啉的电致发光金属络合物

  摘要：

  本发明涉及式(I)或(II)的电致发光金属络合物，它们的制备方法，包含所述金属络合物的电子装置，和它们在电子装置、尤其是有机发光二极管(OLEDs)中的用途，用作氧敏指示剂，用作生物测定中的磷光指示剂，以及用作催化剂。

  公开号：

  CN101970448B
• 作为试剂：
  描述：

  iridium(III) chloride 、 2-phenyldibenzo[f,h]quinoxaline 以 乙二醇乙醚 、 2-phenyldibenzo[f,h]quinoxaline 、 水 为溶剂， 反应 5.0h， 以78%的产率得到μ-dichloro-bis[bis(2-phenyldibenzo[f,h]quinoxalinato)iridium(III)]
  参考文献：
  名称：

  Organometallic complex, and light-emitting element, light-emitting device, and electronic device including the organometallic complex

  摘要：

  公开号：

  EP1939208B1

文献信息

• 발광 소자, 발광 장치 및 전자기기
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD. 가부시키가이샤 한도오따이 에네루기 켄큐쇼(519980839048)

  公开号：KR101548306B1

  公开（公告）日：2015-08-28

  본 발명은 발광 효율이 높고, 또한 장수명의 발광 소자를 제공한다. 또한, 이 발광 소자를 이용하여 발광 장치를 제작함으로써, 소비 전력이 적고 수명이 긴 발광 장치를 제공한다. 양극으로서 기능하는 제 1 전극(301)과 음극으로서 기능하는 제 2 전극(302 사이에, 발광층(313)을 가지고, 발광층(313)이 홀 수송성을 가지는 제 1 유기 화합물(322)과, 디벤조[f,h]퀴녹살린 골격을 배위자로서 가지는 유기 금속 착체(323)를 포함하는 발광 소자를 제조한다. 또한, 이 발광 소자를 이용하여 발광 장치를 제조한다.

  该专利提供了一种发光效率高且具有长寿命的发光器件。通过利用这种发光器件制造发光装置，提供了功耗低且寿命长的发光装置。该发光器件包括具有发光层(313)的第一极(301)作为阳极和第二极(302)作为阴极，发光层(313)包括具有空穴传输性质的第一有机化合物(322)和具有二苯并[f,h]喹喔啉骨架的有机金属配合物(323)。此外，利用该发光器件制造发光装置。
• HETEROCYCLIC COMPOUND, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：Kadoma Hiroshi

  公开号：US20110210316A1

  公开（公告）日：2011-09-01

  An object is to provide a novel heterocyclic compound which can be used for a light-emitting element, as a host material of a light-emitting layer in which a light-emitting substance is dispersed. Other objects are to provide a light-emitting element having low driving voltage, a light-emitting element having high current efficiency, and a light-emitting element having a long lifetime. Provided are a light-emitting element including a compound in which a dibenzo[f,h]quinoxaline ring and a hole-transport skeleton are bonded through an arylene group, and a light-emitting device, an electronic device, and a lighting device each using this light-emitting element. The heterocyclic compound represented by General Formula (G1) below is provided.

  本发明的目的是提供一种新颖的杂环化合物，可用作发光元件，作为发光物质分散的发光层的主体材料。另一个目的是提供具有低驱动电压、高电流效率和长寿命的发光元件。提供了一种包括通过芳基基团连接的二苯并[f，h]喹喔啉环和空穴传输骨架的化合物的发光元件，以及使用该发光元件的发光装置、电子装置和照明装置。提供了下述通式（G1）所表示的杂环化合物。
• HETEROCYCLIC COMPOUND
  申请人：Kadoma Hiroshi

  公开号：US20120193613A1

  公开（公告）日：2012-08-02

  Provided is a novel heterocyclic compound which can be used for a light-emitting element, as a host material of a light-emitting layer in which a light-emitting substance is dispersed. A heterocyclic compound represented by a general formula (G1) is provided. In the formula, A represents any of a substituted or unsubstituted dibenzothiophenyl group, a substituted or unsubstituted dibenzofuranyl group, and a substituted or unsubstituted carbazolyl group, R 11 to R 19 separately represent any of hydrogen, an alkyl group having 1 to 4 carbon atoms, and a substituted or unsubstituted aryl group having 6 to 13 carbon atoms, and Ar represents a substituted or unsubstituted arylene group having 6 to 13 carbon atoms.

  提供了一种新型的杂环化合物，可用于光发射元件，作为光发射物质分散的发光层的主体材料。该杂环化合物由通式（G1）表示。在该式中，A代表取代或未取代的二苯并硫代基团、取代或未取代的二苯并呋喃基团和取代或未取代的咔唑基团，R11到R19分别代表氢、具有1至4个碳原子的烷基团和具有6至13个碳原子的取代或未取代的芳基团，Ar代表取代或未取代的具有6至13个碳原子的芳亚基基团。
• Dibenzo[f,h]Quinoxaline Derivative, Method of Synthesizing the Same, Light-Emitting Element, Light-Emitting Device, Electronic Appliance, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20150080574A1

  公开（公告）日：2015-03-19

  A dibenzo[f,h]quinoxaline derivative in which impurities are reduced and a novel method of synthesizing the dibenzo[f,h]quinoxaline derivative in which impurities are reduced are provided. In addition, a light-emitting element, a light-emitting device, an electronic appliance, or a lighting device with high emission efficiency and high reliability in which the dibenzo[f,h]quinoxaline derivative is used as an EL material is provided. In the synthesis method, a 2-(chloroaryl)dibenzo[f,h]quinoxaline derivative is used as a synthetic intermediate in a synthetic pathway so that an impurity contained in a final product can be removed easily by purification by sublimation.

  提供一种二苯并[f,h]喹噁啉衍生物，其中杂质得到减少，并提供一种减少杂质的二苯并[f,h]喹噁啉衍生物的新合成方法。此外，提供一种使用二苯并[f,h]喹噁啉衍生物作为EL材料的发光元件、发光装置、电子设备或照明装置，具有高发射效率和高可靠性。在合成方法中，使用2-(氯芳基)二苯并[f,h]喹噁啉衍生物作为合成中间体，以便通过升华纯化轻松去除最终产品中含有的杂质。
• Organometallic complex, and light-emitting element, light-emitting device and electronic device including the organometallic compex
  申请人：Inoue Hideko

  公开号：US20080160345A1

  公开（公告）日：2008-07-03

  An object is to provide an organometallic complex that can emit red light. Another object is to provide an organometallic complex having high emission efficiency. Still another object is to provide an organometallic complex that can emit red light with high luminous efficiency. The present invention provides an organometallic complex having a structure represented by the following general formula (G1′). In the formula, Ar represents an aryl group having 6 to 25 carbon atoms; R 1 represents any one of hydrogen, an alkyl group having 1 to 4 carbon atoms, and an alkoxy group having 1 to 4 carbon atoms; R 2 to R 8 each represent any one of hydrogen, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, and a halogen group; at least one of pairs R 3 and R 4 , R 4 and R 5 , and R 5 and R 6 may be bound to each other to form a ring; and M represents a central metal of Group 9 elements and Group 10 elements.

  本发明的一个目的是提供一种可以发出红光的有机金属配合物。另一个目的是提供一种具有高发射效率的有机金属配合物。还有一个目的是提供一种可以以高亮度效率发出红光的有机金属配合物。本发明提供了一种具有以下一般式（G1'）所表示结构的有机金属配合物。 在公式中，Ar代表具有6至25个碳原子的芳基基团；R1代表氢、具有1至4个碳原子的烷基基团和具有1至4个碳原子的烷氧基团中的任意一种；R2至R8分别代表氢、具有1至4个碳原子的烷基基团、具有1至4个碳原子的烷氧基团和卤素基团中的任意一种；R3和R4、R4和R5以及R5和R6中的至少一对可以结合形成环；M代表第9族元素和第10族元素的中心金属。