1-methyl-1-benzoylethyl pentadecafluorooctanoate | 1242448-77-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-methyl-1-benzoylethyl pentadecafluorooctanoate
• 英文别名: (2-Methyl-1-oxo-1-phenylpropan-2-yl) 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoate；(2-methyl-1-oxo-1-phenylpropan-2-yl) 2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctanoate
• CAS: 1242448-77-6
• 化学式: C₁₈H₁₁F₁₅O₃
• 分子量: 560.26
• InChiKey: XPEOXIXFEOKSOR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  36
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为产物：
  描述：

  全氟辛酰氯 、 2-羟基-2-甲基-1-苯基-1-丙酮 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 1-methyl-1-benzoylethyl pentadecafluorooctanoate
  参考文献：
  名称：

  A Fluorinated Photoinitiator for Surface Oxygen Inhibition Resistance

  摘要：

  A novel photoinitiator called 2-methyl-2-benzoylethanolpentadecafluorooctanote (1173-F) was synthesized and characterized. 1173-F is an efficient photoinitiator for free radical photopolymerization in the presence of oxygen and has ability of moving to the surface. The oxygen inhibition of the photopolymerization surface could be decreased because the large amount of photoinitiator at the top to be consumed by oxygen. UV absorption spectroscopy, X-ray photoelectron spectroscopy, gel permeation chromatography, and EDS-line mapping were used to prove the migratory of 1173-F in monomers. Real time FTIR analysis was taken to investigate the ability of 1173-F to overcome oxygen inhibition.

  DOI：

  10.1021/ma2023759

文献信息

• A Fluorinated Photoinitiator for Surface Oxygen Inhibition Resistance
  作者：Fei Xu、Jin-Liang Yang、Yu-Shan Gong、Gui-Ping Ma、Jun Nie

  DOI：10.1021/ma2023759

  日期：2012.2.14

  A novel photoinitiator called 2-methyl-2-benzoylethanolpentadecafluorooctanote (1173-F) was synthesized and characterized. 1173-F is an efficient photoinitiator for free radical photopolymerization in the presence of oxygen and has ability of moving to the surface. The oxygen inhibition of the photopolymerization surface could be decreased because the large amount of photoinitiator at the top to be consumed by oxygen. UV absorption spectroscopy, X-ray photoelectron spectroscopy, gel permeation chromatography, and EDS-line mapping were used to prove the migratory of 1173-F in monomers. Real time FTIR analysis was taken to investigate the ability of 1173-F to overcome oxygen inhibition.