Phosphorigsaeure-bis-(2-chlorethylester) | 1189-32-8

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: Phosphorigsaeure-bis-(2-chlorethylester)
• 英文别名: Bis-(2-chlorethyl)-phosphit；Bis(2-chloroethyl) phosphonate；bis(2-chloroethyl) hydrogen phosphite
• CAS: 1189-32-8
• 化学式: C₄H₉Cl₂O₃P
• 分子量: 206.993
• InChiKey: GGCXLVWDCPTFMN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 海关编码：
  2920901900

反应信息

• 作为反应物：
  描述：

  1,1-二氯丙酮 、 Phosphorigsaeure-bis-(2-chlorethylester) 生成 (2,2-dichloro-1-hydroxy-1-methyl-ethyl)-phosphonic acid bis-(2-chloro-ethyl) ester
  参考文献：
  名称：

  Abramov,V.S. et al., Journal of general chemistry of the USSR, 1968, vol. 38, p. 1266 - 1271

  摘要：

  DOI：
• 作为产物：
  描述：

  2-氯乙醇 在 二乙基亚磷酸氢酯 、 磷酸 作用下， 生成 Phosphorigsaeure-bis-(2-chlorethylester)
  参考文献：
  名称：

  Petrov,K.A. et al., Journal of general chemistry of the USSR, 1962, vol. 32, # 11, p. 3643 - 3646

  摘要：

  DOI：

文献信息

• Phosphate-containing and phosphonate-containing phosphate esters
  申请人：Stauffer Chemical Company

  公开号：US04697030A1

  公开（公告）日：1987-09-29

  There are disclosed multiphosphorus-containing compounds comprising phosphonate-containing or phosphate-containing phosphate esters. The compounds can be prepared by: (a) reacting a phosphonate-containing or phosphate-containing alcohol with phosphorus pentoxide following by reaction with an epoxide, (b) reacting a phosphonate-containing or phosphate-containing alcohol with a phosphorus oxyhalide, hydrolyzing any phosphorus halogen bonds and then reacting the resulting phosphoric acid derivative with an epoxide, (c) transesterifying a phosphonate-containing or phosphate-containing alcohol with a dialkyl phosphite, oxidizing the resulting compound to yield a phosphoric acid derivative and reacting the phosphoric acid derivative with an epoxide. The compounds are useful as flame retardant additives for polyurethanes and textiles.

  揭示了包含膦酸酯或磷酸酯的多磷含化合物。这些化合物可以通过以下方法制备：(a)将含膦酸酯或磷酸酯的醇与五氧化二磷反应，然后与环氧化合物反应；(b)将含膦酸酯或磷酸酯的醇与磷氧卤化物反应，水解任何磷卤键，然后将产生的磷酸衍生物与环氧化合物反应；(c)将含膦酸酯或磷酸酯的醇与二烷基磷酸酯发生酯交换反应，氧化产生的化合物以得到磷酸衍生物，然后将磷酸衍生物与环氧化合物反应。这些化合物可用作聚氨酯和纺织品的阻燃添加剂。
• Synthesis of organic phosphate-phosphonates
  申请人：Stauffer Chemical Company

  公开号：US04407765A1

  公开（公告）日：1983-10-04

  A process for the preparation of organic phosphate-phosphonates comprises the steps of reacting an organic acylating agent with an organophosphite triester to form an intermediate followed by reacting the intermediate with an organophosphite diester. Typically benzoyl chloride is the acylating agent, triethyl phosphite and bis (.beta.-chloroethyl) phosphite the sequential reactants, and the second step is carried out in the presence of a catalytic amount of a tertiary amine. A solvent such as methylene dichloride may be employed. Organic phosphate-phosphonates are useful as flame retardants, especially in urethane foams.

  一种制备有机磷酸酯磷酸盐的方法，包括以下步骤：将有机酰基化试剂与有机磷酸三酯反应，形成中间体，然后将中间体与有机磷酸二酯反应。通常，苯甲酰氯是酰基化试剂，三乙基磷酸酯和双（β-氯乙基）磷酸酯是连续的反应物，第二步在三级胺的催化下进行。可以使用诸如二氯甲烷之类的溶剂。有机磷酸酯磷酸盐在阻燃剂中很有用，特别是在聚氨酯泡沫中。
• Process for preparing a Methacrylic resin composition having a high solar radiant energy absorbing property
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP0019097A1

  公开（公告）日：1980-11-26

  An organic compound (A) containing cupric ion and a compound (B) having at least one P-O-H bond in a molecule are contained into the methacrylic resin selected from poly(methyl methacrylate) or methacrylic polymers containing at least 50% by weight of a methyl methacrylate unit.

  将含有铜离子的有机化合物 (A) 和分子中至少有一个 P-O-H 键的化合物 (B) 加入甲基丙烯酸树脂中，该树脂选自聚甲基丙烯酸甲酯或甲基丙烯酸聚合物，其中甲基丙烯酸甲酯单元的重量至少占 50%。
• Phosphosulfonate herbicides
  申请人：ROHM AND HAAS COMPANY

  公开号：EP0511826A2

  公开（公告）日：1992-11-04

  This invention concerns phosphosulfonates having the general formula wherein (1) Y is phenyl ; naphthyl ; benzyl ; (C5-C8)cycloalkyl ; a 5-membered heteroaromatic ring having from one to four heteroatoms each being independently N, O or S, provided that no more than one is O or S ; a 6-membered heteroaromatic ring having 1, 2 or 3 nitrogen atoms ; or a fused 5,6- or 6,6-membered heteroaromatic ring having from one to four heteroatoms each being independently N, O or S, provided that no more than one is O or S ; wherein Y optionally has up to three substituents, each being independently halogen, cyano, nitro, (C1-C6)alkoxy, halo(C1-C4)alkoxy, (C1-C6)alkyl, halo(C1-C4)alkyl, phenyl, (C1-C4)alkylcarbonyloxy, di(C1-C4)alkylcarbamoyl or (C1-C4)alkoxycarbonyl, provided that (a) no more than one of said substituents is present when Y is a thiadiazolyl ring or a tetrazolyl ring, and (b) no more than two of said substituents is present when Y is a triazolyl ring, a thiazolyl ring, or an isothiazolyl ring, except that when Y is phenyl, naphthyl or benzyl, it may have up to five substituents each being independently halogen, acetoxy, methyl, methoxy or halomethoxy, but no more than two of which are acetoxy, methyl, methoxy, or halomethoxy; (2) X is oxygen or sulfur ; and (3) R1 and R2 are each independently chloro, or (C1-C6)alkyl, (C1-C6)alkoxy, halo(C2-C4)alkoxy, (C1-C4)alkylthio, (C3-C4)alkenyloxy, (C3-C4)alkynyloxy, (C1-C4)alkoxy(C1-C4)alkoxy, (C4-C8)cycloalkyloxy, (C3-C6)cycloalkyl(C1-C3)alkoxy, cyano(C1-C4)alkoxy, (C2-C4)alkylideneiminooxy or amino each optionally substituted with one or two of (C1-C4)alkyl, (C2-C4)alkenyl or phenyl ; provided that there is not more than one phenyl group on the amino group ; also provided that R1 may additionally be phenyl or phenoxy; and also provided that R1 and R2 may both be alkoxy so as to form together with the phosphorus atom a 6-membered oxygen-containing ring ; except that when R1 and R2 are both alkoxy, Y is not phenyl, 4-methylphenyl, 4-chlorophenyl, 4-bromophenyl or 3-nitrophenyl ; compositions containing these compounds and their use as herbicides.

  本发明涉及通式如下的磷磺酸盐 其中 (1) Y 是苯基；萘基；苄基；(C5-C8)环烷基；具有 1 至 4 个杂原子的 5 元杂芳环，每个杂原子独立地为 N、O 或 S，但 O 或 S 不超过一个；具有 1、2 或 3 个氮原子的 6 元杂芳环；或融合的 5、6 或 6、6 元杂芳环，其 1 至 4 个杂原子各自独立地为 N、O 或 S，但 O 或 S 原子不得多于 1 个； 其中 Y 可任选具有最多三个取代基，每个取代基独立为卤素、氰基、硝基、(C1-C6)烷氧基、卤代(C1-C4)烷氧基、(C1-C6)烷基、卤代(C1-C4)烷基、苯基、(C1-C4)烷基羰氧基、二(C1-C4)烷基氨基甲酰基或(C1-C4)烷氧基羰基，条件是 (a) 当 Y 为噻二唑环或四唑环时，上述取代基中存在的不超过一个，且 (b) 当 Y 为三唑环、噻唑环或异噻唑环时，所述取代基不超过两个，但当 Y 为苯基、萘基或苄基时，最多可有五个取代基，每个取代基独立地为卤素、乙酰氧基、甲基、甲氧基或卤代甲氧基，但其中乙酰氧基、甲基、甲氧基或卤代甲氧基不超过两个； (2) X 是氧或硫；以及 (3) R1 和 R2 各自独立地是氯、或 (C1-C6)烷基、(C1-C6)烷氧基、卤代(C2-C4)烷氧基、(C1-C4)烷硫基、(C3-C4)烯氧基、(C3-C4)炔氧基、(C1-C4)烷氧基（C1-C4）烷氧基、(C4-C8)环烷氧基、(C3-C6)环烷基(C1-C3)烷氧基、氰基(C1-C4)烷氧基、(C2-C4)亚烷基亚氨基氧基或氨基，各自任选被一个或两个(C1-C4)烷基、(C2-C4)烯基或苯基取代；前提是氨基上的苯基不超过一个；此外，R1 还可以是苯基或苯氧基；R1 和 R2 还可以都是烷氧基，以便与磷原子一起形成一个 6 元含氧环；但当 R1 和 R2 都是烷氧基时，Y 不是苯基、4-甲基苯基、4-氯苯基、4-溴苯基或 3-硝基苯基；含有这些化合物的组合物及其作为除草剂的用途。
• Polymeric material, method for its manufacture, and its utilization
  申请人：——

  公开号：US20010023276A1

  公开（公告）日：2001-09-20

  The invention relates to a polymeric material on the basis of renewable raw materials, containing a reaction product from 10-90% by mass of a triglyceride with at least 2 epoxy and/or aziridine groups and 5-90% by mass of a polycarboxylic acid anhydride with 0.01-20% by mass of a polycarboxylic acid.

  本发明涉及一种以可再生原料为基础的聚合物材料，其反应产物含有 10-90%（以质量计）的甘油三酯（其中至少含有 2 个环氧基和/或氮丙啶基）和 5-90%（以质量计）的聚羧酸酐（其中含有 0.01-20%（以质量计）的聚羧酸）。