di(hexan-2-yl) adipate | 89837-82-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: di(hexan-2-yl) adipate
• 英文别名: Dihexan-2-yl hexanedioate
• CAS: 89837-82-1
• 化学式: C₁₈H₃₄O₄
• 分子量: 314.466
• InChiKey: XHLGUXMIRSHANO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  22
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-己醇 、 一氧化碳 、 1,3-丁二烯 在 palladium(II) trifluoroacetate 、 HeMaRaphos 、 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 120.0 ℃ 、4.0 MPa 条件下， 反应 24.0h， 以76%的产率得到di(hexan-2-yl) adipate
  参考文献：
  名称：

  通过钯催化的 1,3-二烯羰基化直接合成己二酸酯

  摘要：

  尼龙前体己二酸及其酯的羰基化途径是大规模生产的，主要用于生产尼龙。但是，标准路线需要大量腐蚀性硝酸。J. 杨等人。提出了一种有效的替代路线，其中钯催化剂将一氧化碳添加到丁二烯的每个末端（参见 Schaub 的观点）。两种反应物都可以在商品规模上获得，并且反应不会产生副产物。带有用于质子穿梭的吡啶取代基的优化双齿膦配体证明是获得必要选择性的关键。科学，这个问题 p。1514; 另见第。1447 钯上优化的双齿膦配体促进了尼龙前体的有效替代途径。1的直接羰基化，3-丁二烯为工业上重要的己二酸衍生物提供了一种更具成本效益和环境友好性的途径的潜力。然而，由于区域异构羰基化和异构化途径的复杂反应网络，迄今为止证明该过程的选择性实用催化剂难以捉摸。在这里，我们报告了一种吡啶基取代的双齿膦配体 (HeMaRaphos) 的设计，该配体与钯配位后，以 97% 的选择性和 100% 的原子经济性催化 1,3

  DOI：

  10.1126/science.aaz1293

文献信息

• Efficient Palladium‐Catalyzed Carbonylation of 1,3‐Dienes: Selective Synthesis of Adipates and Other Aliphatic Diesters
  作者：Ji Yang、Jiawang Liu、Yao Ge、Weiheng Huang、Francesco Ferretti、Helfried Neumann、Haijun Jiao、Robert Franke、Ralf Jackstell、Matthias Beller

  DOI：10.1002/anie.202015329

  日期：2021.4.19

  The dicarbonylation of 1,3‐butadiene to adipic acid derivatives offers the potential for a more cost‐efficient and environmentally benign industrial process. However, the complex reaction network of regioisomeric carbonylation and isomerization pathways, make a selective and direct transformation particularly difficult. Here, we report surprising solvent effects on this palladium‐catalysed process

  将1,3-丁二烯二羰基化为己二酸衍生物可为更具成本效益和环境友好的工业生产提供潜力。然而，区域异构体羰基化和异构化途径的复杂反应网络使得选择性和直接转化特别困难。在这里，我们报道了在存在1,2-双-二叔丁基膦膦-二甲苯（d t bpx）配体的情况下，钯催化的这一过程产生了令人惊讶的溶剂影响，这些配体允许由1,3-丁二烯，碳形成己二酸酯二酯。一氧化碳和甲醇，在可扩展条件下具有97％的选择性和100％的原子经济性。在最佳条件下，可以以高至极好的收率获得各种1,2-和1,3-二烯的二酯和三酯。
• Aqueous thermoplastic coating composition for plastics materials and coating method using same
  申请人：KANSAI PAINT CO. LTD.

  公开号：EP0379158A2

  公开（公告）日：1990-07-25

  Disclosed are (1) an aqueous thermoplastic coating composition for coating plastics substrates, the composition consisting essentially of: (A) an aqueous acrylic resin and (B) a urethane resin emulsion, the component (B) being a self-emulsifiable urethane emulsion prepared by subjecting a urethane prepolymer to reaction for chain extension by water and emulsification after or during neutralization of the urethane prepolymer with a tertiary amine, the urethane prepolymer consisting essentially of (i) an aliphatic and/or an alicyclic diisocyanate, (ii) a polyether diol and/or polyester diol both having a number-average molecular weight of about 500 to about 5000, (iii) a low-molecular weight polyhydroxyl compound and (iv) a dimethylolalkanoic acid in NCO/OH equivalent ratio of 1.1-1.9 : 1, the amount of the component (A) being about 1 to about 12% by weight and the amount of the component (B) being about 99 to about 88% by weight, based on the combined weight (calculated as solids) of the two components; and (2) a two-coat coating method for coating a plastics substrate, the method comprising the steps of coating a plastics substrate with a base-coat composition containing a coloring pigment and/or metallic pigment, applying a clear coat composition to the cured or uncured coating for forming a transparent coating and curing the clear coating or the two coatings at the same time at a temperature lower than about 120°C, the method being characterized by the use of the aqueous thermoplastic coating composition as defined above in (1) as the base-coat composition.

  公开了 (1) 一种用于涂覆塑料基材的水性热塑性涂料组合物，该组合物主要由以下成分组成： (A) 丙烯酸树脂水溶液和 (B) 聚氨酯树脂乳液、 成分（B）是一种可自乳化的聚氨酯乳液，其制备方法是在聚氨酯预聚物与叔胺中和之后或中和过程中，使聚氨酯预聚物与水发生链延伸反应并乳化、该聚氨酯预聚物主要包括(i)脂肪族和/或脂环族二异氰酸酯，(ii)聚醚二元醇和/或聚酯二元醇，二者的数均分子量约为 500 至约 5000，(iii)低分子量聚羟基化合物和(iv)二甲基醇烷酸，二者的 NCO/OH 当量比为 1.1-1.9∶1，组分(A)的量按重量计约为 1%至约 12%，组分(B)的量按重量计约为 99%至约 88%，以两种组分的总重量(以固体计算)为基础；和 (2) 用于涂覆塑料基材的双涂层涂覆方法，该方法包括以下步骤：用含有着色颜料和/或金属颜料的基涂层组合物涂覆塑料基材，在固化或未固化的涂层上涂覆透明涂层组合物以形成透明涂层，并在低于约 120°C 的温度下同时固化透明涂层或两种涂层，该方法的特征在于使用如上文(1)中定义的水性热塑性涂层组合物作为基涂层组合物。
• Liquid composition for metachromatic members, and its use
  申请人：THE PILOT INK CO., LTD.

  公开号：EP1600482A1

  公开（公告）日：2005-11-30

  In a liquid composition for metachromatic members which is to be applied to a metachromatic member having a support and provided thereon a porous layer formed by fixing therein a low refractive index pigment in a disperse state together with a binder resin, the liquid composition has a liquid medium and dissolved and/or dispersed therein a solid matter having a refractive index of from 1.3 to 1.8. Also disclosed is a metachromatic member set having this liquid composition and a metachromatic member. The liquid composition for metachromatic members satisfies permanent preservability of images, having superior density retention and shape retention of images formed in the metachromatic member and being suitable for uses in which impressions of hands, feet and the like are taken and preserved or in which written images or stamped images are preserved.

  在一种用于变色构件的液体组合物中，该液体组合物具有液体介质，并溶解和/或分散有折射率为 1.3 至 1.8 的固体物质。此外，还公开了一种变色构件组，它具有这种液体组合物和一种变色构件。用于变色构件的液体组合物可永久保存图像，对在变色构件中形成的图像具有优异的密度保持力和形状保持力，适用于拍摄和保存手、脚等印模或保存书面图像或印章图像的用途。
• Polyvinyl acetal resin composition, film for laminated glass, and laminated glass
  申请人：SKC Co., Ltd.

  公开号：US11248146B2

  公开（公告）日：2022-02-15

  The polyvinyl acetal resin composition includes: a polyvinyl acetal resin, a plasticizer, a metal salt compound, and a benzotriazole-based compound, wherein the metal salt compound is a metal salt of hydroxyl carboxyl acid having two to sixteen carbon atoms, wherein the metal salt compound is included in an amount of less than 0.05 wt % based on a total weight of the polyvinyl acetal resin composition, and wherein the metal salt compound is included in an amount of 16 parts by weight or less based on the benzotriazole-based compound of 100 parts by weight.

  聚乙烯醇缩醛树脂组合物包括：聚乙烯醇缩醛树脂、增塑剂、金属盐化合物和苯并三唑基化合物，其中金属盐化合物是具有 2 至 16 个碳原子的羟基羧酸的金属盐，其中金属盐化合物的加入量小于 0.05 重量％，其中金属盐化合物的加入量为 100 重量份苯并三唑基化合物的 16 重量份或以下。
• Composition and method for manufacturing a film comprising thiourethane layer
  申请人：SKC Co., Ltd.

  公开号：US11434336B2

  公开（公告）日：2022-09-06

  A film for glass bonding includes a thiourethane layer comprising a heterocyclo-alkanediyl-based repeat unit indicated by Formula 1, and a linear alkanediyl-based repeat unit indicated by Formula 2, and a base layer, disposed on a surface of the thiourethane layer, comprising a polyvinyl acetal resin and a plasticizer. In the Formula 1, R1 is —O— or —S—, and X is a heterocyclo-alkanediyl group having carbon atoms of 3 to 10 and sulfur atoms of 1 to 5, and in the Formula 2, R2 is —O— or —S—, and n2 is an integer of 4 to 10.

  用于玻璃粘接的薄膜包括一层硫代氨基甲酸乙酯，该层由式 1 所示的杂环烷二基重复单元组成、 和式 2 所示的线性烷二基重复单元、 和底层，底层置于硫氨酯层的表面，由聚乙烯醇缩醛树脂和增塑剂组成。在式 1 中，R1 是-O-或-S-，X 是具有 3 至 10 个碳原子和 1 至 5 个硫原子的杂环烷二基，在式 2 中，R2 是-O-或-S-，n2 是 4 至 10 的整数。