4,4,5,5,5-pentafluoro-2-iodopentyl acetate | 148043-71-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 4,4,5,5,5-pentafluoro-2-iodopentyl acetate
• 英文别名: (4,4,5,5,5-Pentafluoro-2-iodopentyl) acetate
• CAS: 148043-71-4
• 化学式: C₇H₈F₅IO₂
• 分子量: 346.036
• InChiKey: DEKRRXDNZIENCW-UHFFFAOYSA-N

物化性质

• 沸点：
  203.1±40.0 °C(Predicted)
• 密度：
  1.782±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  4,4,5,5,5-pentafluoro-2-iodopentyl acetate 在 chromium(VI) oxide 、 sodium hydroxide 、 偶氮二异丁腈 、 三正丁基氢锡 、 溶剂黄146 作用下， 反应 27.0h， 生成 4,4,5,5,5-五氟戊酸
  参考文献：
  名称：

  Larsson, Ulf; Carlson, Rolf; Leroy, Jacques, Acta Chemica Scandinavica, 1993, vol. 47, # 4, p. 380 - 390

  摘要：

  DOI：
• 作为产物：
  描述：

  五氟碘乙烷 、 乙酸烯丙酯 在 偶氮二异丁腈 作用下， 反应 5.0h， 生成 4,4,5,5,5-pentafluoro-2-iodopentyl acetate
  参考文献：
  名称：

  An approach to fluorinated surface coatings via photoinitiated cationic cross-linking of mixed epoxy and fluoroepoxy systems

  摘要：

  The synthesis and characterisation of four polyfluorinated monoepoxides is described. These fluoroepoxy monomers were cationically polymerised either neat or as mixtures with diglycidylether of bisphenol-A using the initiator system (CH3CH2)(3)Al/H2O (2/1) or the photoinitiator Ph2I+, PF6-. Contact angle measurements indicated that, in favourable cases, the fluorinated epoxide monomer surface segregated at low loadings to give significant lowering of the surface free energy of photocured films of diglycidylether of bisphenol-A. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-1139(99)00288-2

文献信息

• Verfahren zur Herstellung von Pentafluorpentanol
  申请人：BAYER AG

  公开号：EP0909749B1

  公开（公告）日：2002-08-28
• US6002053A
  申请人：——

  公开号：US6002053A

  公开（公告）日：1999-12-14
• Larsson, Ulf; Carlson, Rolf; Leroy, Jacques, Acta Chemica Scandinavica, 1993, vol. 47, # 4, p. 380 - 390
  作者：Larsson, Ulf、Carlson, Rolf、Leroy, Jacques

  DOI：——

  日期：——
• An approach to fluorinated surface coatings via photoinitiated cationic cross-linking of mixed epoxy and fluoroepoxy systems
  作者：Stephen Matuszczak、W.James Feast

  DOI：10.1016/s0022-1139(99)00288-2

  日期：2000.3

  The synthesis and characterisation of four polyfluorinated monoepoxides is described. These fluoroepoxy monomers were cationically polymerised either neat or as mixtures with diglycidylether of bisphenol-A using the initiator system (CH3CH2)(3)Al/H2O (2/1) or the photoinitiator Ph2I+, PF6-. Contact angle measurements indicated that, in favourable cases, the fluorinated epoxide monomer surface segregated at low loadings to give significant lowering of the surface free energy of photocured films of diglycidylether of bisphenol-A. (C) 2000 Elsevier Science S.A. All rights reserved.