8-((pyridin-3-yl)methylthio) quinoline | 904565-57-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 8-((pyridin-3-yl)methylthio) quinoline
• 英文别名: 8-((pyridin-3-yl)methylthio)quinoline；8-[(pyridin-3-yl)methylthio]quinoline；8-(3-Pyridinylmethylthio)quinoline；8-(pyridin-3-ylmethylsulfanyl)quinoline
• CAS: 904565-57-7
• 化学式: C₁₅H₁₂N₂S
• 分子量: 252.34
• InChiKey: DLWRMPQTHMXHJT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  51.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  8-((pyridin-3-yl)methylthio) quinoline 、 copper(II) trifluoroacetate 以 乙醇 、 氯仿 为溶剂， 以65%的产率得到poly(copper(8-((pyridin-3-yl)(methylthio) quinoline)) trifluoroacetate)
  参考文献：
  名称：

  Syntheses, crystal structures and antimicrobial activities of thioether ligands containing quinoline and pyridine terminal groups and their transition metal complexes

  摘要：

  Eleven transition metal complexes of three asymmetrical tridentate thioether ligands, 8-((pyridin-2-yl)methylthio) quinoline (TQMP2), 8-((pyridin-3-yl)methylthio) quinoline (TQMP3), 8-((pyridin-4-yl) methylthio) quinoline (TQMP4) and one symmetrical pentadentate ligand 2,6-bis (8-quinolinylthiomethyl) pyridine (DTQMP) were prepared. The structures of all these complexes were identified by means of elemental analysis (EA), infrared spectra (IR) and single-crystal diffraction, providing three different kinds of basic conformations, (1) discrete mononuclear structures, (2) dinuclear rings and (3) 1D polymer chains. The antibacterial, antifungal and pesticide activities of the four ligands and 11 complexes were also studied. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.073

文献信息

• Syntheses, structures and bioactivities of silver(I) complexes with a tridentate heterocyclic N- and S-ligand
  作者：Jing-An Zhang、Mei Pan、Jian-Yong Zhang、Hai-Ke Zhang、Zhi-Jin Fan、Bei-Sheng Kang、Cheng-Yong Su

  DOI：10.1016/j.poly.2008.09.029

  日期：2009.1

  Three silver(I) complexes of the asymmetric tridentate ligand 8-((pyridin-3-yl)methylthio)quinoline (TQMP3), namely [Ag-2(TQMP3)(2)(NO3)(2)] (1), [Ag-2(TQMP3)(2)(CF3CO2)(2)] (2) and [Ag-2(TQMP3)(2)](CF3SO3)(2) (H2O)}(n) (3), have been prepared by the method of layering and diffusing of diethyl ether. The structures of the complexes have been identified by elemental analysis (EA), infrared spectra (IR) and single-crystal diffraction, and are composed of discrete binuclear rings in complexes 1 and 2, with pi-pi interactions or H-bonds further extending the structures into 2D nets, while in complex 3, Ag center dot center dot center dot Ag interactions between the rings result in a 1D polymer chain. The antibacterial, antifungal and pesticide activities of the three complexes were tested. (C) 2008 Elsevier Ltd. All rights reserved.
• Syntheses, crystal structures and antimicrobial activities of thioether ligands containing quinoline and pyridine terminal groups and their transition metal complexes
  作者：Jing-An Zhang、Mei Pan、Ji-Jun Jiang、Zhi-Gang She、Zhi-Jin Fan、Cheng-Yong Su

  DOI：10.1016/j.ica.2011.02.073

  日期：2011.8

  Eleven transition metal complexes of three asymmetrical tridentate thioether ligands, 8-((pyridin-2-yl)methylthio) quinoline (TQMP2), 8-((pyridin-3-yl)methylthio) quinoline (TQMP3), 8-((pyridin-4-yl) methylthio) quinoline (TQMP4) and one symmetrical pentadentate ligand 2,6-bis (8-quinolinylthiomethyl) pyridine (DTQMP) were prepared. The structures of all these complexes were identified by means of elemental analysis (EA), infrared spectra (IR) and single-crystal diffraction, providing three different kinds of basic conformations, (1) discrete mononuclear structures, (2) dinuclear rings and (3) 1D polymer chains. The antibacterial, antifungal and pesticide activities of the four ligands and 11 complexes were also studied. (C) 2011 Elsevier B.V. All rights reserved.