4,8,12,16-tetraoxanonadecane-1,2,6,10,14,18,19-heptaol | 51555-31-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 4,8,12,16-tetraoxanonadecane-1,2,6,10,14,18,19-heptaol
• 英文别名: [14C]pentaglycerol；pentaglycerol；Einecs 257-282-5；3-[3-[3-[3-(2,3-dihydroxypropoxy)-2-hydroxypropoxy]-2-hydroxypropoxy]-2-hydroxypropoxy]propane-1,2-diol
• CAS: 51555-31-8
• 化学式: C₁₅H₃₂O₁₁
• 分子量: 388.412
• InChiKey: GJHUJABURIHIJO-UHFFFAOYSA-N

物化性质

• 熔点：
  201 °C
• 密度：
  1.252 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  -4.8
• 重原子数：
  26
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  179
• 氢给体数：
  7
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  丙三醇-Α,Α'-二烯丙基醚 在 palladium on activated charcoal sodium hydroxide 、 四丁基溴化铵 、 氢气 、 甲基三辛基氯化铵 、 sodium hydride 、 间氯过氧苯甲酸 作用下， 以 四氢呋喃 、 甲醇 、 正己烷 、 二氯甲烷 为溶剂， 反应 127.0h， 生成 4,8,12,16-tetraoxanonadecane-1,2,6,10,14,18,19-heptaol
  参考文献：
  名称：

  Original Synthesis of Linear, Branched and Cyclic Oligoglycerol Standards

  摘要：

  DOI：

  10.1002/1099-0690(200103)2001:5<875::aid-ejoc875>3.0.co;2-r

文献信息

• Polyglycerols and production thereof
  申请人：Endo Toshio

  公开号：US20070049775A1

  公开（公告）日：2007-03-01

  A polyglycerol composition contains diglycerol, triglycerol, and tetraglycerol each in a content of 5 percent by weight or more, has a total content of diglycerol, triglycerol, and tetraglycerol of 75 percent by weight or more, has a total content of higher polyglycerol components of 10 percent by weight or less, the higher polyglycerol components each having a degree of polymerization of 7 or higher, and is substantially free from chlorine atom. A process prepares a polyglycerol composition by reacting glycerol and/or a polyglycerol with glycidol in the presence of an activated carbon catalyst.

  一种聚甘油组合物，其中二甘油、三甘油和四甘油的含量均达到重量的5％或更多，其二甘油、三甘油和四甘油的总含量达到重量的75％或更多，高聚甘油成分的总含量不超过重量的10％，高聚甘油成分的聚合度均达到7或更高，并且基本上不含氯原子。一种方法通过在活性炭催化剂存在下将甘油和/或聚甘油与环氧丙烷反应来制备聚甘油组合物。
• Polyfunctional Polyglycerine Initiated Polyether Polyols and High Resilience Polyurethane Slabstock Therefrom
  申请人：Casati Francois M.

  公开号：US20140206787A1

  公开（公告）日：2014-07-24

  A polyglycerine initiated polyether polyol exhibiting a final functionality less than the nominal functionalities of the polyol initiator wherein the initiator is a polyglycerine formed by the polymerization of glycerin having an HEW less than about 35 and exhibiting a nominal functionality between 2 and 16 is provided. Also provided is a process for producing a polyfunctional polyurethane by the reaction of a mixture containing a polyol based on polyglycerine initiator wherein between 5 wt % and 100 wt % of the total initiator is polyglycerine having a nominal functionality between 2 and 16, at least one organic isocyanate, an amine and/or a metal salt catalyst, and optionally a blowing agent. Also provided is a flexible polyurethane foam comprising a reaction product of a polyglycerine or formed by the glycidol polymerization of glycerin, at least one organic isocyanate, and an amine catalyst.
• Original Synthesis of Linear, Branched and Cyclic Oligoglycerol Standards
  作者：Stephanie Cassel、Catherine Debaig、Thierry Benvegnu、Patrick Chaimbault、Michel Lafosse、Daniel Plusquellec、Patrick Rollin

  DOI：10.1002/1099-0690(200103)2001:5<875::aid-ejoc875>3.0.co;2-r

  日期：2001.3