4-allyl-1,2,4-dithiazolidine-3,5-dione | 21597-11-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 4-allyl-1,2,4-dithiazolidine-3,5-dione
• 英文别名: 4-allyl[1,2,4]dithiazolidine-3,5-dione；N-allyl-1,2,4-dithiazolidine-3,5-dione；N-Allyl-3,5-dioxo-1,2,4-dithiazolidin；4-prop-2-enyl-1,2,4-dithiazolidine-3,5-dione
• CAS: 21597-11-5
• 化学式: C₅H₅NO₂S₂
• 分子量: 175.232
• InChiKey: DXQJYLJUMSUWAZ-UHFFFAOYSA-N

物化性质

• 沸点：
  260.2±33.0 °C(Predicted)
• 密度：
  1.449±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  88
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,2,4-二噻唑烷-3,5-二酮 、 3-溴丙烯 在 碳酸氢钠 作用下， 以 乙腈 为溶剂， 反应 16.0h， 以90%的产率得到4-allyl-1,2,4-dithiazolidine-3,5-dione
  参考文献：
  名称：

  Synthetic and structural studies on 1,2,4-dithiazolidine-3,5-dione derivatives

  摘要：

  已经开发出1,2,4-二噁唑烷-3,5-二酮 2 的N-烷基化方法，以及将N-烷基化衍生物转化为异氰酸酯 5 的后续过程。还报告了该方法在固相上的扩展。对钾盐1,2,4-二噁唑烷-3,5-二酮 3进行了X射线晶体学分析，以与母体杂环化合物 2 进行结构比较。

  DOI：

  10.1039/b305096c

文献信息

• Efficient Synthesis of 1,2,4-Dithiazolidine-3,5-diones [Dithiasuccinoyl-Amines] from Bis(chlorocarbonyl)disulfane Plus Bis(trimethylsilyl)amines
  作者：Michael J. Barany、Robert P. Hammer、R. B. Merrifield、George Barany

  DOI：10.1021/ja0455446

  日期：2005.1.1

  dithiasuccinoyl (Dts)-amine, serves as a readily removable amino protecting group for building blocks used in syntheses of peptides, glycopeptides, and PNA; it is also useful as a masked isocyanate and (inversely) as a sulfurization reagent for trivalent phosphorus. Bis(chlorocarbonyl)disulfane, the two-sulfur analogue of succinyl chloride, has been envisioned as a reagent for facile single-step elaboration of the

  1,2,4-二噻唑烷-3,5-二酮杂环，也称为二硫代琥珀酰 (Dts)-胺，作为一种易于去除的氨基保护基团，用于合成肽、糖肽和 PNA 的结构单元；它也可用作掩蔽异氰酸酯和（相反）用作三价磷的硫化试剂。双（氯羰基）二硫烷是琥珀酰氯的双硫类似物，已被设想为用于轻松单步制备杂环的试剂。然而，由于所讨论的原因，双（氯羰基）二硫烷直接与伯胺反应不能产生 Dts-胺。受到有机硅化学文献中的几个先例的启发，即三甲基甲硅烷基可以作为“大质子”，成功地，已开发出通过双（氯羰基）二硫烷与双（三甲基甲硅烷基）胺反应制备 Dts-胺的高产率方法。还介绍了旨在阐明这些观察结果的机械原因的研究。
• A New and Simple Synthesis of Sulfonyl Ureas from Sulfonamides and N-Alkyl-1,2,4-dithiazolidine-3,5-diones
  作者：Kelly Chibale、Richard Gessner

  DOI：10.1055/s-0029-1217960

  日期：2009.10

  A new, short, and simple synthetic approach to sulfonyl ureas is reported. The method involves the transformation of readily synthesized N-alkyl-1,2,4-dithiazolidine-3,5-diones by reaction with primary sulfonamides. Sulfonyl ureas were obtained in moderate to high yields.

  本报告介绍了一种新的、简短的磺酰基脲类合成方法。该方法是将容易合成的 N-烷基-1,2,4-二噻唑烷-3,5-二酮与伯氨基磺酰胺反应转化。磺酰基脲以中等至高产率获得。
• Polymer compound for use in electrodematerial, electrode using the same and nonaqueous solutlion battery using the same
  申请人：Uemachi Hiroshi

  公开号：US20050142441A1

  公开（公告）日：2005-06-30

  The present invention provides a polymer compound for an electrode material permitting operation at low temperatures and attainment of large capacities, an electrode using the polymer compound, and a nonaqueous solution battery involving the electrode as the positive electrode thereof. The polymer compound includes a structure capable of intramolecularly forming at least one S—S bond in a single side chain of the repeating unit thereof. The S—S bond constitutes a part of a 4- to 6-membered heterocycle. The electrode includes as an electrode material the polymer compound including a structure capable of intramolecularly forming at least one S—S bond in the single side chain of the repeating unit thereof. The nonaqueous solution battery includes a positive electrode, an electrolyte and a negative electrode, and the positive electrode is an electrode including as an electrode material the polymer compound comprising a structure capable of forming at least one S—S bond in the single side chain of the repeating unit thereof.

  本发明提供一种聚合物化合物，用于电极材料，允许在低温下操作并达到大容量，以及使用聚合物化合物的电极和涉及电极作为正极的非水溶液电池。聚合物化合物包括一种结构，能够在其重复单元的单侧链中分子内形成至少一种S-S键。S-S键构成4至6成员杂环的一部分。电极包括作为电极材料的聚合物化合物，其中包括一种结构，能够在其重复单元的单侧链中分子内形成至少一种S-S键。非水溶液电池包括正极、电解质和负极，正极是一个电极，包括作为电极材料的聚合物化合物，其中包括一种结构，能够在其重复单元的单侧链中形成至少一种S-S键。
• Polymer compound for use in electrode material, electrode using the same and nonaqueous solution battery using the same
  申请人：Sensa Corporation

  公开号：US07442758B2

  公开（公告）日：2008-10-28

  The present invention provides a polymer compound for an electrode material permitting operation at low temperatures and attainment of large capacities, an electrode using the polymer compound, and a nonaqueous solution battery involving the electrode as the positive electrode thereof. The polymer compound includes a structure capable of intramolecularly forming at least one S—S bond in a single side chain of the repeating unit thereof. The S—S bond constitutes a part of a 4- to 6-membered heterocycle. The electrode includes as an electrode material the polymer compound including a structure capable of intramolecularly forming at least one S—S bond in the single side chain of the repeating unit thereof. The nonaqueous solution battery includes a positive electrode, an electrolyte and a negative electrode, and the positive electrode is an electrode including as an electrode material the polymer compound comprising a structure capable of forming at least one S—S bond in the single side chain of the repeating unit thereof.

  本发明提供了一种聚合物化合物，用于电极材料，可在低温下操作并获得大容量，以及使用聚合物化合物的电极和涉及电极作为其正极的非水溶液电池。聚合物化合物包括一种结构，能够在其重复单元的单侧链中分子内形成至少一个S-S键。S-S键构成4-到6元杂环的一部分。电极包括作为电极材料的聚合物化合物，其包括一种结构，能够在其重复单元的单侧链中分子内形成至少一个S-S键。非水溶液电池包括正极、电解质和负极，正极是包括作为电极材料的聚合物化合物，其包括一种结构，能够在其重复单元的单侧链中形成至少一个S-S键。
• Cane-Honeysett; Dowle; Wood, Synlett, 2000, # 11, p. 1622 - 1624
  作者：Cane-Honeysett、Dowle、Wood

  DOI：——

  日期：——