2-(3-Methylbutan-2-yloxy)acetic acid | 169566-98-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2-(3-Methylbutan-2-yloxy)acetic acid
• CAS: 169566-98-7
• 化学式: C₇H₁₄O₃
• 分子量: 146.186
• InChiKey: ZZXPAZWWOWEAMA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(3-Methylbutan-2-yloxy)acetic acid 在 dirhodium tetraacetate 、 (COCl₂)2 作用下， 以 二氯甲烷 为溶剂， 反应 10.0h， 生成 5-Isopropyl-5-methyl-dihydro-furan-3-one
  参考文献：
  名称：

  Tertiary alcohol synthesis from secondary alcohols via C–H insertion

  摘要：

  次级醇通过C-H插入反应转化为3(2H)-呋喃酮衍生物，然后通过保留立体化学的方式合成三级醇。

  DOI：

  10.1039/c39950000321
• 作为产物：
  描述：

  3-甲基-2-丁醇 、 sodium monochloroacetic acid 在 sodium hydride 作用下， 以 四氢呋喃 、 二甲基亚砜 为溶剂， 生成 2-(3-Methylbutan-2-yloxy)acetic acid
  参考文献：
  名称：

  Tertiary alcohol synthesis from secondary alcohols via C–H insertion

  摘要：

  次级醇通过C-H插入反应转化为3(2H)-呋喃酮衍生物，然后通过保留立体化学的方式合成三级醇。

  DOI：

  10.1039/c39950000321

文献信息

• LIQUID COMPOSITION, RECORDING METHOD, AND RECORDED MATTER
  申请人：Gotou Hiroshi

  公开号：US20130101814A1

  公开（公告）日：2013-04-25

  A liquid composition for agglutinating particles having a negative charge which are dispersed in a dispersion liquid, the liquid composition including: an organic acid ammonium salt represented by Formula (1), and water, Formula (1) where R 1 represents a hydroxyl group, a methyl group or a hydrogen atom; and R 2 represents a hydroxyl group or a methyl group.

  一种用于凝聚分散在分散液中的带有负电荷的颗粒的液态组合物，该液态组合物包括：由式（1）表示的有机酸铵盐和水，其中，式（1）中R1表示羟基、甲基或氢原子；R2表示羟基或甲基。
• IMAGE FORMING METHOD, AND IMAGE FORMED MATTER
  申请人：Goto Hiroshi

  公开号：US20120128949A1

  公开（公告）日：2012-05-24

  An image forming method including: applying a pre-treatment liquid onto a coating layer provided on at least one surface of a support of a recording medium, jetting an inkjet ink onto the coating layer, onto which the pre-treatment liquid has been applied, so as to form an image, and applying or jetting a post-treatment liquid onto the coating layer, onto which the inkjet ink has been jetted, so as to form a transparent protective layer on the coating layer, wherein the inkjet ink contains the water-dispersible colorant, a water-soluble organic solvent, a surfactant, a penetrant and water, and wherein an amount of pure water transferred into the recording medium, provided with the coating layer, measured at a contact time of 100 ms with a dynamic scanning liquid absorptometer is 1 ml/m 2 to 10 ml/m 2 , and the pre-treatment liquid contains a water-soluble aliphatic organic acid.
• INKJET TREATMENT LIQUID AND INKJET RECORDING APPARATUS
  申请人：Fujii Hidetoshi

  公开号：US20120320137A1

  公开（公告）日：2012-12-20

  An inkjet treatment liquid including: a water-soluble coagulating agent; a water-soluble organic solvent; a fluoro-chemical surfactant; a foam inhibitor; and water, wherein the foam inhibitor is a compound represented by General Formula (I), and the fluorochemical surfactant contains a compound represented by General Formula (II): HOR 1 R 3 C—[CH 2 ] n —CR 2 R 4 OH General Formula (I) in General Formula (I), R 1 and R 2 each denote an alkyl group having 3 to 6 carbon atoms; R 3 and R 4 each denote an alkyl group having 1 to 2 carbon atoms; and n denotes an integer of 1 to 6; and Rf-Q-Z General Formula (II) in General Formula (II), Rf denotes a perfluoroalkyl group; Q denotes a bonding group; and Z denotes a hydrophilic group containing —(CH 2 CH 2 O) n —, —COO − , —SO 3 − , —SO 4 − , or —PO 4 − ; and n denotes an integer of 1 to 50.
• INKJET INK, INK CARTRIDGE, INKJET RECORDING METHOD, INKJET RECORDING DEVICE, AND INKJET RECORDED MATTER
  申请人：GOTOU Hiroshi

  公开号：US20150307729A1

  公开（公告）日：2015-10-29

  To provide an inkjet ink, which contains: water; a wetting agent; a surfactant; and a colorant, wherein the wetting agent contains at least an amide compound represented by the following structural formula (I)
• US8722175B2
  申请人：——

  公开号：US8722175B2

  公开（公告）日：2014-05-13