diisononyl maleate | 53817-54-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: diisononyl maleate
• 英文别名: bis(7-methyloctyl) (Z)-but-2-enedioate
• CAS: 53817-54-2
• 化学式: C₂₂H₄₀O₄
• 分子量: 368.557
• InChiKey: CBWMVXMQKDYZDQ-NXVVXOECSA-N

物化性质

• 沸点：
  200-211 °C(Press: 0.3 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  26
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  diisononyl maleate 在 叔丁基过氧化氢 、 potassium tert-butylate 作用下， 以 四氢呋喃 、 癸烷 为溶剂， 反应 7.5h， 以99%的产率得到Bis(7-methyloctyl) oxirane-2,3-dicarboxylate
  参考文献：
  名称：

  Epoxide and cyclic carbonate with diisononyl succinate backbone as phthalate-free plasticizers

  摘要：

  Candidates for new phthalate-free plasticizers are synthesized based on epoxidized diisononyl maleate and carbonylated diisononyl tartrate. Although the carbonation of epoxidized diisononyl maleate with CO2 failed, the cyclic carbonate was synthesized successfully using triphosgene as carbonylation agent of the respective tartrate. The performance of the synthesized materials as plasticizer was analyzed under standard conditions as plastisols. Results showed potential for the epoxidized maleate and carbonylated derivative to be developed into phthalate free-plasticizers. (C) 2016 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2016.01.069
• 作为产物：
  描述：

  马来酸酐 、 异壬醇 在 硫酸 作用下， 以 甲苯 为溶剂， 反应 3.0h， 以93.7%的产率得到diisononyl maleate
  参考文献：
  名称：

  Epoxide and cyclic carbonate with diisononyl succinate backbone as phthalate-free plasticizers

  摘要：

  Candidates for new phthalate-free plasticizers are synthesized based on epoxidized diisononyl maleate and carbonylated diisononyl tartrate. Although the carbonation of epoxidized diisononyl maleate with CO2 failed, the cyclic carbonate was synthesized successfully using triphosgene as carbonylation agent of the respective tartrate. The performance of the synthesized materials as plasticizer was analyzed under standard conditions as plastisols. Results showed potential for the epoxidized maleate and carbonylated derivative to be developed into phthalate free-plasticizers. (C) 2016 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2016.01.069

文献信息

• DEFECT REDUCTION RINSE SOLUTION CONTAINING AMMONIUM SALTS OF SULFOESTERS
  申请人：BASF SE

  公开号：EP3322787B1

  公开（公告）日：2019-10-09
• Silicone Elastomer Gels and Related Hydrosilylation Processes
  申请人：ALZO INTERNATIONAL, INC

  公开号：US20160194455A1

  公开（公告）日：2016-07-07

  The invention provides improved silicone elastomer gels and related hydrosilylation processes and cosmetics. Cross-linked silicone elastomer gels made by processes of the invention exhibit superior characteristics, including improved organic solubility, consistent gelation, stability and enhanced lubricity.
• HEAT-EXPANDABLE MICROSPHERES AND APPLICATION THEREOF
  申请人：MATSUMOTO YUSHI-SEIYAKU CO., LTD.

  公开号：US20180056267A1

  公开（公告）日：2018-03-01

  Heat-expandable microspheres having an expansion temperature which can be decreased by a simple means without changing the polymerizable monomer and its ratio and/or changing the blowing agent and its ratio, and applications thereof. The heat-expandable microspheres are composed of a thermoplastic resin shell and a core material encapsulated therein. The core material contains a thermally-vaporizable blowing agent which imparts a swelling degree of less than 5% as defined by the following formula (I) and a component (A) which imparts a swelling degree of 5 to 30% as defined by the following formula (I), wherein an amount of the component (A) ranges from 0.0001 to 30 parts by weight to 100 parts by weight of the blowing agent: Swelling degree (%)=( M 2 −M 1 )/ M 1 }×100  (I) wherein M 2 and M 1 are as defined herein.
• US3950312A
  申请人：——

  公开号：US3950312A

  公开（公告）日：1976-04-13
• US6265517B1
  申请人：——

  公开号：US6265517B1

  公开（公告）日：2001-07-24