neopentyl α-allyloxymethylacrylate | 1246676-27-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: neopentyl α-allyloxymethylacrylate
• 英文别名: 2,2-Dimethylpropyl 2-(prop-2-enoxymethyl)prop-2-enoate；2,2-dimethylpropyl 2-(prop-2-enoxymethyl)prop-2-enoate
• CAS: 1246676-27-6
• 化学式: C₁₂H₂₀O₃
• 分子量: 212.289
• InChiKey: CNNZOEVFLDZKJX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  15
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-(羟甲基)丙烯酸甲酯 在 三乙烯二胺 、 titanium(IV) isopropylate 、 阻聚剂701 、 4-甲氧基苯酚 作用下， 100.0 ℃ 、4.0 kPa 条件下， 反应 6.0h， 生成 neopentyl α-allyloxymethylacrylate
  参考文献：
  名称：

  ALPHA-(UNSATURATED ALKOXYALKYL) ACRYLATE COMPOSITION AND PROCESS FOR PRODUCTION THEREOF

  摘要：

  公开号：

  EP2415751B1

文献信息

• a-(UNSATURATED ALKOXYALKYL) ACRYLATE COMPOSITION AND PROCESS FOR PRODUCTION THEREOF
  申请人：Saito Makoto

  公开号：US20120016095A1

  公开（公告）日：2012-01-19

  An α-(unsaturated alkoxyalkyl)acrylate composition is provided which enables an α-(unsaturated alkoxyalkyl)acrylate product to be stored at a high purity for an extended period of time and can fully suppress problems such as coloration and gelation from arising during polymerization, and also a method of preparing α-(unsaturated alkoxyalkyl)acrylate compositions for enabling to obtain industrially α-(unsaturated alkoxyalkyl)acrylates safely in a high purity is also provided. The composition includes an α-(unsaturated alkoxyalkyl)acrylate of a specific structure and an antioxidant, the content of the antioxidant being from 0.03 to 0.5 wt % per 100 wt % of the α-(unsaturated alkoxyalkyl)acrylate.

  提供了一种α-(不饱和烯氧烷基)丙烯酸酯组合物，使α-(不饱和烯氧烷基)丙烯酸酯产品可以在长时间内高纯度地储存，并且可以完全抑制聚合过程中出现的着色和凝胶等问题，同时还提供了一种制备α-(不饱和烯氧烷基)丙烯酸酯组合物的方法，以安全地获得高纯度的工业用α-(不饱和烯氧烷基)丙烯酸酯。该组合物包括具有特定结构的α-(不饱和烯氧烷基)丙烯酸酯和抗氧剂，抗氧剂的含量为α-(不饱和烯氧烷基)丙烯酸酯的100 wt％中的0.03至0.5 wt％。
• Ink Composition For Three-Dimensional Modeling, Ink Set, And Method For Producing Three-Dimensional Model
  申请人：KONICA MINOLTA, INC.

  公开号：US20180037758A1

  公开（公告）日：2018-02-08

  The purpose of the present invention is to provide: an ink composition for three-dimensional modeling by an inkjet method, which has low viscosity and high ejectability, and which is capable of producing a three-dimensional model having higher tensile strength and higher impact resistance; an ink set which includes this ink composition; and a method for producing a three-dimensional model, which uses this ink composition. This ink composition for three-dimensional modeling contains a photopolymerizable monomer, a polymer and a photopolymerization initiator. The polymer has a weight average molecular weight of from 5,000 to 80,000 (inclusive); the photopolymerizable monomer contains a monomer that is capable of forming a ring structure in the main chain by polymerization; and the difference between the solubility parameter of the photopolymerizable monomer and the solubility parameter of the polymer is from 0.30 (cal/cm 3 ) 1/2 to 2.0 (cal/cm 3 ) 1/2 (inclusive).
• CURABLE RESIN COMPOSITION AND METHOD OF MANUFACTURING ARTICLE
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20220282013A1

  公开（公告）日：2022-09-08

  A curable resin composition that is capable of forming a cured product having impact resistance and a high elastic modulus, and has a low viscosity, thereby being suitable for three-dimensional shaping. The curable resin composition contains: (A) an α-(unsaturated alkoxyalkyl)acrylic acid or an ester thereof; (B) a bifunctional radically polymerizable oligomer; optionally (C) a radically polymerizable compound other than the component (A) and the component (B); (D) rubber particles; and (E) a radical polymerization initiator, wherein the component (A) is represented by the following formula (1).
• US8796492B2
  申请人：——

  公开号：US8796492B2

  公开（公告）日：2014-08-05
• [EN] CURABLE RESIN COMPOSITION<br/>[FR] COMPOSITION DE RÉSINE DURCISSABLE<br/>[JA] 硬化性樹脂組成物
  申请人：CANON KK

  公开号：WO2020162475A1

  公开（公告）日：2020-08-13

  成分（Ａ）：単官能２－（アリルオキシメチル）アクリル酸またはそのエステル、成分（Ｂ）：イソシアヌレート環を有する多官能ラジカル重合性化合物、成分（Ｃ）：ラジカル重合性化合物、成分（Ｄ）：ゴム粒子、及び成分（Ｅ）：ラジカル重合開始剤、を含有し、成分（Ｃ）は、成分（Ａ）及び成分（Ｂ）とは異なるラジカル重合性化合物であり、成分（Ａ）と成分（Ｂ）と成分（Ｃ）の合計１００が質量部であるとき、成分（Ｂ）が２０質量部以上８０質量部以下、成分（Ｃ）が０質量部以上４０質量部以下であることを特徴とする硬化性樹脂組成物。