1H,1H,2H,2H-perfluorohexyl trifluoromethanesulfonate | 171182-86-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: 1H,1H,2H,2H-perfluorohexyl trifluoromethanesulfonate
• 英文别名: 1H,1H,2H,2H-perfluorohexyl triflate；perfluorobutyl ethylene triflate；2-(perfluorobutyl)ethyl trifluoromethanesulfonate；3,3,4,4,5,5,6,6,6-nonafluorohexyl trifluoromethanesulfonate
• CAS: 171182-86-8
• 化学式: C₇H₄F₁₂O₃S
• 分子量: 396.154
• InChiKey: BZPMRPBNUBBPDV-UHFFFAOYSA-N

物化性质

• 沸点：
  185.5±40.0 °C(Predicted)
• 密度：
  1.670±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  23
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  15

反应信息

• 作为反应物：
  描述：

  1H,1H,2H,2H-perfluorohexyl trifluoromethanesulfonate 在 盐酸 、 2,6-二叔丁基吡啶 、 potassium carbonate 、 O-(N-succinimidyl)-N,N,N',N'-tetramethyluronium tetrafluoroborate 、 N,N-二异丙基乙胺 、 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate 作用下， 以 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 反应 65.0h， 生成
  参考文献：
  名称：

  Synthesis and properties of chemiluminescent acridinium ester labels with fluorous tags

  摘要：

  乙酰基二甲基苯基酯是一种高灵敏度的化学发光标记，在临床诊断中得到广泛应用。

  DOI：

  10.1039/c4ob00456f
• 作为产物：
  描述：

  1H,1H,2H,2H-全氟己-1-醇 在 三氟甲磺酸酐 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以91.8%的产率得到1H,1H,2H,2H-perfluorohexyl trifluoromethanesulfonate
  参考文献：
  名称：

  Polymerizable compound, polymerizable resin composition, cured polymer and liquid crystal display device

  摘要：

  这项发明的可聚合化合物由通式（I）表示：其中R为H，R′，R′O，R′COO或R′OCO，R′为具有1至约15个碳原子的直链或支链烷基或烯基基团，A1和A2分别为环己烷环或苯环，可能包括下面通式（II）表示的取代基；X为H或CH3；Y1、Y2、Y3和Y4独立地为H、F、Cl、CH3、CH3O、CF3或CF3O，其中至少两个Y1、Y2、Y3和Y4为H，如果A1和A2均为环己烷环，则至少有一个Y1、Y2、Y3和Y4不为H：其中Y5、Y6、Y7和Y8独立地为H、F、Cl、CH3、CH3O、CF3或CF3O，至少两个Y5、Y6、Y7和Y8为H。

  公开号：

  US06388146B1

文献信息

• Polyoxazoline copolymers
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US09556340B2

  公开（公告）日：2017-01-31

  A copolymer derived from a monomer mixture that includes monomers having the formulas: (A) and (B) wherein: Q is O or N; R10 is H or CH3; R11 is an organic group comprising a hydrolyzable silyl group; R12 is H or CH3; P is: (I); R1 is selected from H, an alkyl group, an aryl group, and a combination thereof; R2 is selected from an alkyl group, an aryl group, a combination thereof, and a Rf—Y—(CH2)x— group; Rf is a perfluorinated alkyl group; Y is selected from a bond, —S(O)2—N(CH3)—, —S(O)2—N(CH2CH3)—, —S(O)2—O—, —S(O)2—, —C(O)—, —C(O)—S—, —C(O)—O—, —C(O)—NH—, —C(O)—N(CH3)—, —C(O)—N(CH2CH3)—, —(CH2CH2O)y—, —O—, and —O—C(O)—CH═CH—C(O)—O—; n is an integer of greater than 2; x is an integer of at least 2; and y is an integer of at least 1.

  这是一段关于由单体混合物制得的共聚物的描述，包括具有以下结构的单体：(A)和(B)，其中：Q为O或N；R10为H或CH3；R11为含有可水解硅基团的有机基团；R12为H或CH3；P为：(I)；R1从H，烷基，芳基或它们的组合中选择；R2从烷基，芳基，它们的组合以及Rf—Y—(CH2)x—基团中选择；Rf为全氟烷基基团；Y从键，—S(O)2—N(CH3)—，—S(O)2—N(CH2CH3)—，—S(O)2—O—，—S(O)2—，—C(O)—，—C(O)—S—，—C(O)—O—，—C(O)—NH—，—C(O)—N(CH3)—，—C(O)—N(CH2CH3)—，—(CH2CH2O)y—，—O—和—O—C(O)—CH═CH—C(O)—O—中选择；n为大于2的整数；x至少为2的整数；y至少为1的整数。
• Polymerizable compound and a liquid crystal display device using the same
  申请人：Sharp Kabushiki Kaisha

  公开号：US05814378A1

  公开（公告）日：1998-09-29

  The present invention provides a polymerizable compound represented by Formula (I): ##STR1## where X represents a hydrogen atom or a methyl group; 1 represents an integer in the range of 0 to 14; m represents 0 or 1; n represents 0 or 1; p represents an integer in the range of 0 to 6; and q represents an integer in the range of 0 to 9, wherein m is 0 under the condition 1=0, and 1 under the condition 1.noteq.0.

  本发明提供了一种可聚合化合物，其由式（I）表示：##STR1## 其中，X代表氢原子或甲基基团；1代表0到14范围内的整数；m代表0或1；n代表0或1；p代表0到6范围内的整数；q代表0到9范围内的整数，其中在1=0的条件下，m为0，在1.noteq.0的条件下，m为1。
• Chemically Altering the Solubility and Durability of Dyes for Sensitized Solar Cells
  作者：Subashani Maniam、Andrew B. Holmes、Gary A. Leeke、Ante Bilic、Gavin E. Collis

  DOI：10.1021/acs.orglett.5b01921

  日期：2015.8.21

  By designing dyes with fluoroalkyl groups, the optical and electronic properties of the alkyl analogue were maintained while dramatically altering the solubility. Dyes, F-TABTA (8) and its masked derivative F-TABTSi (9), that enable them to be deposited under conventional organic solvent and scCO(2) conditions, respectively, were developed, hi liquid DSSC devices, the fluoroalkyl dye (F-TABTA, 8) performs slightly better than its alkyl analogue (D21L6, 10), and interestingly, it was found that the former device showed better stability over time. Deploying the silyl-masked precursor F-TABTSi (9), this dye was deposited onto TiO2 photoanodes from scCO(2) in very short contact times (2.5 h), and ECEs of 7.70% were obtained that exceed the performance of the alkyl dye when deposited by conventional methods.
• Fluorine-containing chiral smectic liquid crystals
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0255236B1

  公开（公告）日：1994-05-04
• US4886619A
  申请人：——

  公开号：US4886619A

  公开（公告）日：1989-12-12