(E)-8:2 Fluorotelomer unsaturated aldehyde | 64906-51-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (E)-8:2 Fluorotelomer unsaturated aldehyde
• 英文别名: (E)-3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-hexadecafluorodec-2-enal
• CAS: 64906-51-0
• 化学式: C₁₀H₂F₁₆O
• 分子量: 442.1
• InChiKey: LQERGGUGOIACQD-HNQUOIGGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  27
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为产物：
  描述：

  全氟辛基碘烷 在 氢氧化钾 、 偶氮二异丁腈 作用下， 以 甲醇 为溶剂， 反应 6.0h， 生成 (E)-8:2 Fluorotelomer unsaturated aldehyde
  参考文献：
  名称：

  Synthése de fluoroalkyl éthanl : RFCH2CHO

  摘要：

  Aldehydes RFCH2CHO (R(F) is a linear perfluoroalkyl chain) have been obtained in the addition reaction of R(F)I to vinyl acetate in the presence of zinc. RFCH2CHIOAc is formed as an intermediate in the course of the reaction. Under appropriate conditions, RFCH2CHO and its acylal or acetal derivatives are obtained in good yields.

  DOI：

  10.1016/s0040-4039(00)92222-6

文献信息

• Synthése de fluoroalkyl éthanl : RFCH2CHO
  作者：Ph. Laurent、H. Blancou、A. Commeyras

  DOI：10.1016/s0040-4039(00)92222-6

  日期：1992.4

  Aldehydes RFCH2CHO (R(F) is a linear perfluoroalkyl chain) have been obtained in the addition reaction of R(F)I to vinyl acetate in the presence of zinc. RFCH2CHIOAc is formed as an intermediate in the course of the reaction. Under appropriate conditions, RFCH2CHO and its acylal or acetal derivatives are obtained in good yields.