1-methyl-1-isopropylcyclopropane | 13150-79-3

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 英文名称: 1-methyl-1-isopropylcyclopropane
• 英文别名: 1-methyl-1-(2-propyl)cyclopropane；2-<1-Methyl-cyclopropyl-(1)>-propan；1,1-methylisopropylcyclopropane；1-isopropyl-1-methyl-cyclopropane；1-Isopropyl-1-methyl-cyclopropan；1-Methyl-1-(1-methylethyl)-cyclopropane；1-methyl-1-propan-2-ylcyclopropane
• CAS: 13150-79-3
• 化学式: C₇H₁₄
• 分子量: 98.1882
• InChiKey: QEJFJGSJIQQWRC-UHFFFAOYSA-N

物化性质

• 保留指数：
  646

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  7
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-bromo-2,2-bis-bromomethyl-3-methyl-butane 在 sodium carbonate 、 sodium iodide 、 锌 作用下， 生成 1-methyl-1-isopropylcyclopropane
  参考文献：
  名称：

  Derfer; Greenlee; Boord, Journal of the American Chemical Society, 1949, vol. 71, p. 180

  摘要：

  DOI：

文献信息

• Development of Platinum(II) and -(IV) CNC Pincer Complexes and Their Application in a Hydrovinylation Reaction
  作者：Daniel Serra、Peng Cao、José Cabrera、Robin Padilla、Frank Rominger、Michael Limbach

  DOI：10.1021/om101128f

  日期：2011.4.11

  A series of new, dicationic platinum(II) CNC pincer complexes were prepared and characterized by NMR and X-ray diffraction analysis. Oxidative addition of methyl iodide and iodine yielded the mostly unstable platinum(IV) complexes, which readily underwent reductive elimination to yield the platinum(II) precursors. Nonetheless, a platinum(IV) iodide adduct was isolated and was characterized by X-ray

  制备了一系列新型的二价铂（II）CNC夹钳络合物，并通过NMR和X射线衍射分析对其进行了表征。甲基碘和碘的氧化加成生成了最不稳定的铂（IV）配合物，可以很容易地进行还原性消除以生成铂（II）的前体。尽管如此，仍分离出碘化铂（IV）加合物，并通过X射线衍射分析对其进行了表征。另外，分离出铂（II）乙烯络合物，发现其是2-甲基-2-丁烯与乙烯的共二聚中中等活性但选择性高的催化剂。
• Rearrangement of cyclopropyl, substituted vinyl and alkyl groups to divalent carbon.
  作者：A.R. Kraska、L.I. Cherney、H. Shechter

  DOI：10.1016/s0040-4039(00)87289-5

  日期：1982.1

  The relative carbenic migratory abilities of cyclopropyl, β,β-dimenthylvinyl, methyl, ethyl and isopropyl group have been determined.

  已经确定了环丙基，β，β-二薄荷基乙烯基，甲基，乙基和异丙基的相对羧迁移能力。
• Configuration and13C NMR spectra of alkylcyclopropane derivatives
  作者：R. Touillaux、M. Van Meerssche、J. M. Dereppe、G. Leroy、J. Weiler、C. Wilante

  DOI：10.1002/mrc.1270160120

  日期：1981.5

  AbstractEight alkylcyclopropane derivatives were prepared in a conventional manner and analysed by 13C NMR spectroscopy. Additivity parameters were calculated from the chemical shifts of the endocyclic carbons, and the configurational structures derived for these compounds are confirmed by the internal coherence found for this set of parameters.
• Slobodin et al., Zhurnal Obshchei Khimii, 1953, vol. 23, p. 1665;engl.Ausg.S.1747
  作者：Slobodin et al.

  DOI：——

  日期：——
• KRASKA, A. R.;CHERNEY, L. I.;SHECHTER, H., TETRAHEDRON LETT., 1982, 23, N 21, 2163-2166
  作者：KRASKA, A. R.、CHERNEY, L. I.、SHECHTER, H.

  DOI：——

  日期：——