1,2-cyclodecanediol | 30572-96-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,2-cyclodecanediol
• 英文别名: cis-1,2-Cyclodecanediol；cyclodecane-1,2-diol
• CAS: 30572-96-4
• 化学式: C₁₀H₂₀O₂
• 分子量: 172.268
• InChiKey: NVGYZORHPOIGFP-UHFFFAOYSA-N

物化性质

• 熔点：
  139-140 °C
• 沸点：
  303.8±10.0 °C(Predicted)
• 密度：
  1.005±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (Z)-cyclodecene 在 锇 、 Cu-Al-hydrotalcite 水 、 N-甲基吗啉氧化物 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以100%的产率得到1,2-cyclodecanediol
  参考文献：
  名称：

  The Os/Cu–Al-hydrotalcite catalysed hydroxylation of alkenes

  摘要：

  一种新型Os/Cu-Al-水滑石类催化剂被描述，其与N-甲基氧化吗啉作为共氧化剂，能够在异相催化下选择性地高产率地将烯烃羟基化生成二醇。

  DOI：

  10.1039/b310686a

文献信息

• [EN] METHODS FOR PREPARING FLUOROALKYL ARYLSULFINYL COMPOUNDS AND FLUORINATED COMPOUNDS THERETO<br/>[FR] PROCÉDÉS DE PRÉPARATION DE COMPOSÉS FLUOROALKYLE ARYLSULFINYLÉS ET COMPOSÉS FLUORÉS APPARENTÉS
  申请人：IM & T RES INC

  公开号：WO2010022001A1

  公开（公告）日：2010-02-25

  Novel preparative methods for fluoroalkyl arylsulfinyl compounds are disclosed. Fluorinated compounds as useful fluorinated compounds, intermediates, or builing blocks are disclosed. Useful applications of the fluoroalkyl arylsulfinyl compounds are shown.

  揭示了用于制备氟烷基芳基磺酰基化合物的新型制备方法。公开了氟化合物作为有用的氟化合物、中间体或构建块。展示了氟烷基芳基磺酰基化合物的有用应用。
• Methods For Preparing Fluoroalkyl Arylsulfinyl Compounds And Fluorinated Compounds Thereto
  申请人：Umemoto Teruo

  公开号：US20110190511A1

  公开（公告）日：2011-08-04

  Novel preparative methods for fluoroalkyl arylsulfinyl compounds are disclosed. Fluorinated compounds as useful fluorinated compounds, intermediates, or builing blocks are disclosed. Useful applications of the fluoroalkyl arylsulfinyl compounds are shown.

  本发明揭示了一种用于制备氟烷基芳基亚磺酰化合物的新型制备方法。本发明还揭示了氟化合物作为有用的氟化合物、中间体或构建块。同时，本发明还展示了氟烷基芳基亚磺酰化合物的有用应用。
• Methods for Preparing Fluoroalkyl Arylsulfinyl Compounds and Fluorinated Compounds Thereto
  申请人：Umemoto Teruo

  公开号：US20100152463A1

  公开（公告）日：2010-06-17

  Novel preparative methods for fluoroalkyl arylsulfinyl compounds are disclosed. Fluorinated compounds as useful fluorinated compounds, intermediates, or building blocks are disclosed. Useful applications of the fluoroalkyl arylsulfinyl compounds are shown.

  本发明公开了用于制备氟烷基芳基磺酰基化合物的新型制备方法。本发明还公开了作为有用的氟化合物、中间体或构建块的氟化合物。本发明还展示了氟烷基芳基磺酰基化合物的有用应用。
• POLYACETAL RESIN COMPOSITION
  申请人：POLYPLASTICS CO. LTD.

  公开号：EP0823456A1

  公开（公告）日：1998-02-11

  A polyacetal resin composition having excellent friction resistance and abrasion resistance performances is provided by improving the compatibility, dispersibility and interfacial adhesiveness between the polyacetal resin and an olefinic polymer. To a polyacetal resin (A), 1 to 100 parts by weight based on 100 parts by weight of the resin (A) of a modified olefinic polymer (B) modified with at least one member selected from the group consisting of an unsaturated carboxylic acid and an acid anhydride thereof, and their derivatives, and 0.1 to 100% by weight based on component (B) of an alkylene glycol polyme (C)r having a primary or secondary amino group(s) and having a number-average molecular weight of 400 to 500,000 are blended.

  通过改善聚缩醛树脂和烯烃聚合物之间的相容性、分散性和界面粘合性，提供了一种具有优异耐摩擦性和耐磨性的聚缩醛树脂组合物。 在聚缩醛树脂（A）中，以 100 份树脂（A）的重量为基准，掺入 1 至 100 份用至少一种 选自不饱和羧酸及其酸酐和它们的衍生物组成的组的成员进行改性的改性烯烃聚合物 （B），以及以组分（B）的重量为基准，掺入 0.1 至 100%的具有伯氨基或仲氨基且数 均分子量为 400,000 至 500,000 的烷二醇聚合物（C）。
• BRANCHED POLYACETAL RESIN COMPOSITION
  申请人：POLYPLASTICS CO. LTD.

  公开号：EP1273625A1

  公开（公告）日：2003-01-08

  To provide a polyacetal resin material in which an excellent sliding property is given and the appearance, dimensional precision, mechanical properties, etc. of the molded article thereof are improved as well. That is, a branched polyacetal resin composition, comprising 100 parts by weight of a branched polyacetal copolymer (A) having an oxymethylene group as the main repeating unit and having a specific branching unit, and    0.5 to 40 parts by weight of at least one polymer (B) selected from the group consisting of the following polymer (B-1) and (B-2), i.e.    polymer (B-1): a graft or block copolymer prepared from an olefin polymer (b-1) and at least one vinyl polymer (b-2); and    polymer (B-2): a modified olefin polymer in which an olefin polymer (b-3) is modified with at least one compound selected from the group consisting of an unsaturated carboxylic acid, an unsaturated carboxylic acid anhydride and derivatives thereof    and/or 0.1 to 5 parts by weight of a lubricant (C).

  为了提供一种聚缩醛树脂材料，使其具有优异的滑动性能，并改善模塑制品的外观、尺寸精度和机械性能等。即一种支化聚缩醛树脂组合物，它包括 100 重量份的支化聚缩醛共聚物 (A)，该共聚物以氧亚甲基为主要重复单元并具有特定的支化单元，以及 0.5 至 40 重量份的至少一种聚合物 (B)，选自以下聚合物 (B-1) 和 (B-2)，即 聚合物（B-1）：由烯烃聚合物（b-1）和至少一种乙烯基聚合物（b-2）制备的接枝或嵌段共聚物；以及 聚合物（B-2）：改性烯烃聚合物，其中烯烃聚合物（b-3）用至少一种选自不饱和羧酸、不饱和羧酸酐及其衍生物的化合物进行改性 和/或 0.1 至 5 重量份的润滑剂 (C)。