[3,4,5-Triacetoxy-6-[3,4,5-triacetoxy-6-(acetoxymethyl)tetrahydropyran-2-yl]sulfanyl-tetrahydropyran-2-yl]methyl acetate

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [3,4,5-Triacetoxy-6-[3,4,5-triacetoxy-6-(acetoxymethyl)tetrahydropyran-2-yl]sulfanyl-tetrahydropyran-2-yl]methyl acetate
• 英文别名: [3,4,5-triacetyloxy-6-[3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]sulfanyloxan-2-yl]methyl acetate
• 化学式: C₂₈H₃₈O₁₈S
• 分子量: 694.7
• InChiKey: VJUMXLNMLSEYRN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  47
• 可旋转键数：
  20
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  254
• 氢给体数：
  0
• 氢受体数：
  19

文献信息

• GLYCOSYL DONOR, PREPARATION METHOD THEREFOR, AND USE THEREOF
  申请人：SICHUAN UNIVERSITY

  公开号：US20220127239A1

  公开（公告）日：2022-04-28

  A glycosyl donor represented by formula (I) is used for preparing an S-glycoside compound represented by formula (III), an O-glycoside compound represented by formula (V), and a C-glycoside compound represented by formula (V). The glycosyl donor is a raw material in the preparation of O-glycoside, S-glycoside, and C-glycoside compounds by means of a free radical reaction, most of which have a special α configuration.

  使用式(I)所代表的糖基供体，可用于制备式(III)所代表的S-糖苷化合物，式(V)所代表的O-糖苷化合物和式(V)所代表的C-糖苷化合物。该糖基供体是通过自由基反应制备O-糖苷化合物、S-糖苷化合物和C-糖苷化合物的原料之一，其中大部分具有特殊的α构型。