N-(2,2-dimethyl-4-pentylidene)aniline | 100747-86-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(2,2-dimethyl-4-pentylidene)aniline
• 英文别名: 2,2-dimethyl-N-phenylpent-4-en-1-imine
• CAS: 100747-86-2
• 化学式: C₁₃H₁₇N
• 分子量: 187.285
• InChiKey: VWSZWVLPNPRXTP-UHFFFAOYSA-N

物化性质

• 沸点：
  100-118 °C(Press: 6 Torr)
• 密度：
  0.84±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  dichloro(1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylylidene)(benzylidene)bis(pyridine)ruthenium(II) 、 N-(2,2-dimethyl-4-pentylidene)aniline 以 二氯甲烷 为溶剂， 以83%的产率得到
  参考文献：
  名称：

  Latent Olefin Metathesis Catalysts Featuring Chelating Alkylidenes

  摘要：

  The synthesis of a series of ruthenium-based metathesis catalysts featuring imine donors chelated through the alkylidene group is described. The relative placement of the imine carbon-nitrogen double bond (exocyclic vs endocyclic) has a major impact on the initiation behavior. When used in metathesis applications, catalysts with an endocyclic imine bond show latent behavior and a high degree of tunability. The incorporation of additional donor atoms is an additional strategy for controlling initiation behavior. These latent catalysts could be useful in high-temperature applications.

  DOI：

  10.1021/om060620u
• 作为产物：
  描述：

  N-烯丙基苯胺 在 Pd(PPh3) 、 对甲苯磺酸 、 三氟乙酸 作用下， 以 苯 为溶剂， 反应 20.0h， 生成 N-(2,2-dimethyl-4-pentylidene)aniline
  参考文献：
  名称：

  Palladium(0)-catalyzed rearrangement of N-allyl enamines. Synthesis of .delta.,.epsilon.-unsaturated imines and .gamma.,.delta.-unsaturated carbonyl compounds

  摘要：

  DOI：

  10.1021/jo00254a013

文献信息

• Palladium(0) catalyzed 3-aza-cope rearrangement of N-allylenamines
  作者：Shun-ichi Murahashi、Yoshiki Makabe

  DOI：10.1016/s0040-4039(01)80888-1

  日期：1985.1

  Pd(0) complexes catalyze the 3-Aza-Cope rearrangement of N-allylenamines to the corresponding δ,ε-unsaturated imines or γ,δ-unsaturated carbonyl compounds in the presence of trifluoro-acetic acid as co-catalyst.

  在三氟乙酸作为助催化剂的存在下，Pd（0）络合物催化N-烯丙胺的3-Aza-Cope重排为相应的δ，ε-不饱和亚胺或γ，δ-不饱和羰基化合物。
• Palladium(0)-catalyzed rearrangement of N-allyl enamines. Synthesis of .delta.,.epsilon.-unsaturated imines and .gamma.,.delta.-unsaturated carbonyl compounds
  作者：Shunichi Murahashi、Yoshiki Makabe、Kazuto Kunita

  DOI：10.1021/jo00254a013

  日期：1988.9
• Latent Olefin Metathesis Catalysts Featuring Chelating Alkylidenes
  作者：Andrew Hejl、Michael W. Day、Robert H. Grubbs

  DOI：10.1021/om060620u

  日期：2006.12.1

  The synthesis of a series of ruthenium-based metathesis catalysts featuring imine donors chelated through the alkylidene group is described. The relative placement of the imine carbon-nitrogen double bond (exocyclic vs endocyclic) has a major impact on the initiation behavior. When used in metathesis applications, catalysts with an endocyclic imine bond show latent behavior and a high degree of tunability. The incorporation of additional donor atoms is an additional strategy for controlling initiation behavior. These latent catalysts could be useful in high-temperature applications.