1-(4-methyl-cyclohex-1-enyl)-propan-1-one | 22755-48-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(4-methyl-cyclohex-1-enyl)-propan-1-one
• 英文别名: 1-(4-Methyl-cyclohex-1-enyl)-propan-1-on；1-Methyl-4-propionyl-cyclohexen-(3)；1-Methyl-4-(propylon-(4¹))-cyclohexen-(3)；Aethyl-(4-methyl-cyclohexen-(1)-yl-(1))-keton；1-(4-Methylcyclohexen-1-yl)propan-1-one；1-(4-methylcyclohexen-1-yl)propan-1-one
• CAS: 22755-48-2
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: ZWVYEKKNKYYGJE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(4-methyl-cyclohex-1-enyl)-propan-1-one 在 乙醇 、 sodium 作用下， 生成 1-(4-Methyl-cyclohexyl)-propan-1-on
  参考文献：
  名称：

  Wallach; Rentschler, Justus Liebigs Annalen der Chemie, 1908, vol. 360, p. 61

  摘要：

  DOI：
• 作为产物：
  描述：

  1-(4-methyl-cyclohex-1-enyl)-propan-1-one oxime 在 硫酸 作用下， 生成 1-(4-methyl-cyclohex-1-enyl)-propan-1-one
  参考文献：
  名称：

  Wallach; Rentschler, Justus Liebigs Annalen der Chemie, 1908, vol. 360, p. 61

  摘要：

  DOI：

文献信息

• Study of induced hypohalogenation of 1-alkyl(4-methylcyclohex-1-enyl)alkanones, and chemical transformations of the obtained compounds
  作者：O. A. Sadygov

  DOI：10.1134/s1070363209080180

  日期：2009.8

  Induced hydroxyhalogenation of alkyl cyclohexenyl ketones in the systems [MHlg-HX or HHlg]-H2O2 or (NaClO) was performed and the optimal conditions of this reaction were elucidated. It is established that in the system in situ is induced a hypohaloid acid HClO or HBrO is produced that then enters into electrophilic addition at the ring double bond affording hydroxyhalo derivatives of the cycloaliphatic ketones. The alkyl cyclohexenyl ketone chloro(bromo)hydrines and the oxiranes obtained from them are very reactive compounds and can be used as initial compounds for the synthesis of many individual organic compounds
• Wallach, Justus Liebigs Annalen der Chemie, 1918, vol. 414, p. 227
  作者：Wallach

  DOI：——

  日期：——
• Wallach; Rentschler, Justus Liebigs Annalen der Chemie, 1908, vol. 360, p. 61
  作者：Wallach、Rentschler

  DOI：——

  日期：——