Propyl-cycloheptan | 13705-36-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 英文名称: Propyl-cycloheptan
• 英文别名: propyl-cycloheptane；Propylcycloheptane
• CAS: 13705-36-7
• 化学式: C₁₀H₂₀
• 分子量: 140.269
• InChiKey: CJZNZUMUPIJOMM-UHFFFAOYSA-N

物化性质

• 沸点：
  181.4 °C(Press: 750 Torr)
• 密度：
  0.8178 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Propyl-cycloheptan 、 alkaline earth salt of/the/ methylsulfuric acid 生成 1-甲基-1-丙基环己烷 、 正丙基苯
  参考文献：
  名称：

  New and interesting Biscogniauxia taxa, with a key to the world species

  摘要：

  Six new taxa of Biscogniauxia are described from Taiwan, including four new species: B. ambiens, B. cylindrispora, B. formosana, and B. latirima; and two new varieties: B. albosticta var. orientalis and B. formosana var. kentingensis. Their cultural and anamorphic data are also provided. A description is provided for B, doidgeae based on its type. Cultural and anamorphic data are given for B. philippinensis var. microspora. A key to the 57 known species of Biscogniauxia in the world is also given.

  DOI：

  10.1016/s0953-7562(08)61976-0
• 作为产物：
  描述：

  环庚烷甲醛 生成 Propyl-cycloheptan
  参考文献：
  名称：

  环辛四烯氧化物与格氏试剂的反应

  摘要：

  发现环辛四烯氧化物与乙基溴化镁、苯基溴化镁和叔丁基溴化镁的反应分别产生 2, 4, 6-环庚三烯基-1-乙基-、苯基-和叔丁基甲醇。用催化量的溴化镁在乙醚中处理环辛四烯氧化物，得到苯乙醛，产率为 76%。甲醇与催化量的对甲苯磺酸脱水导致它们进一步重排为反式-β-取代的苯乙烯。

  DOI：

  10.1246/bcsj.40.174

文献信息

• Zelinsky, Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1906, vol. 38, p. 473
  作者：Zelinsky

  DOI：——

  日期：——
• New and interesting Biscogniauxia taxa, with a key to the world species
  作者：Yu-Ming Ju、Jack D. Rogers

  DOI：10.1016/s0953-7562(08)61976-0

  日期：2001.9

  Six new taxa of Biscogniauxia are described from Taiwan, including four new species: B. ambiens, B. cylindrispora, B. formosana, and B. latirima; and two new varieties: B. albosticta var. orientalis and B. formosana var. kentingensis. Their cultural and anamorphic data are also provided. A description is provided for B, doidgeae based on its type. Cultural and anamorphic data are given for B. philippinensis var. microspora. A key to the 57 known species of Biscogniauxia in the world is also given.
• The Reaction of Cyclooctatetraene Oxide with Grignard Reagents
  作者：Tsutomu Matsuda、Masahiko Sugishita

  DOI：10.1246/bcsj.40.174

  日期：1967.1

  The reaction of cyclooctatetraene oxide with ethylmagnesium bromide, phenylmagnesium bromide and t-butylmagnesium bromide was found to yield 2, 4, 6-cycloheptatrienyl-1-ethyl-, phenyl- and t-butylcarbinol respectively. The treatment of cyclooctatetraene oxide with a catalytic amount of magnesium bromide in ether afforded phenyl acetaldehyde in a 76% yield. The dehydration of the carbinols with a catalytic

  发现环辛四烯氧化物与乙基溴化镁、苯基溴化镁和叔丁基溴化镁的反应分别产生 2, 4, 6-环庚三烯基-1-乙基-、苯基-和叔丁基甲醇。用催化量的溴化镁在乙醚中处理环辛四烯氧化物，得到苯乙醛，产率为 76%。甲醇与催化量的对甲苯磺酸脱水导致它们进一步重排为反式-β-取代的苯乙烯。