1-甲基-1-丙基环己烷 | 4258-93-9

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 中文名称: 1-甲基-1-丙基环己烷
• 英文名称: 1-Methyl-1-propyl-cyclohexan
• 英文别名: 1-Methyl-1-propylcyclohexane
• CAS: 4258-93-9
• 化学式: C₁₀H₂₀
• 分子量: 140.269
• InChiKey: SSOKTUYAEOXEPO-UHFFFAOYSA-N

物化性质

• 熔点：
  -84.33°C (estimate)
• 沸点：
  174.35°C
• 密度：
  0.8101

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2902199090

反应信息

• 作为反应物：
  描述：

  1-甲基-1-丙基环己烷 、 alkaline earth salt of/the/ methylsulfuric acid 生成 正丙基苯 、 甲苯
  参考文献：
  名称：

  Study in the Terpene Series. XXII.^1a Synthesis, Physical Constants and Catalytic Dehydrogenation of 1-Methyl-1-ethyl-, 1-Methyl-1-n-propyl- and 1-Methyl-1-isopropylcyclohexane^1b

  摘要：

  DOI：

  10.1021/ja01615a044
• 作为产物：
  描述：

  1-甲基环己醇 在 五氯化磷 、 甲苯 作用下， 生成 1-甲基-1-丙基环己烷
  参考文献：
  名称：

  Buck et al., Journal of the Institute of Petroleum, 1948, vol. 34, p. 350

  摘要：

  DOI：

文献信息

• High-performance ring-opening catalysts based on iridium-containing zeolite Beta in the hydroconversion of decalin
  作者：Dominic Santi、Tobias Holl、Vincenzo Calemma、Jens Weitkamp

  DOI：10.1016/j.apcata.2013.01.020

  日期：2013.3

  Decalin was converted in a flow-type reactor under a hydrogen pressure of 5.2 MPa on Ir/H,A-Beta zeolite catalysts, where A stands for an alkali metal cation. In one series of catalysts, the Ir content was 3 wt.%, and the nature of A was varied from lithium to cesium. In a second series, the iridium content in Ir/H,Cs-Beta was varied from 1 to 5 wt.%. On some of these catalysts, open-chain decanes (OCDs) were formed with unprecedented selectivities and yields of up to 47 and 44%, respectively. The term "High-Performance Ring-Opening Catalysts" (HIPEROCs) was defined. Evidence is presented for hydrogenolysis on the metal being the main ring-opening mechanism on HIPEROCs. The main function of the Bronsted-acid sites is a mild isomerization of six-membered into five-membered naphthenic rings which are much easier to open by hydrogenolysis. Valuable mechanistic information can be deduced from the carbon-number distributions and the naphthenes vs. alkanes content of the hydrocracked products (C-9-). (c) 2013 Elsevier B.V. All rights reserved.
• Radshabli-Seidowa et al., Zhurnal Obshchei Khimii, 1959, vol. 29, p. 2212,2216, 2217; engl. Ausg. S. 2179, 2180
  作者：Radshabli-Seidowa et al.

  DOI：——

  日期：——
• Bolestova, G. I.; Parnes, Z. N., Journal of Organic Chemistry USSR (English Translation), 1987, vol. 23, p. 32 - 36
  作者：Bolestova, G. I.、Parnes, Z. N.

  DOI：——

  日期：——
• Chromow et al., Doklady Akademii Nauk SSSR, 1954, vol. 96, p. 295
  作者：Chromow et al.

  DOI：——

  日期：——
• Bolestova, G. I.; Parnes, Z. N.; Kursanov, D. N., Journal of Organic Chemistry USSR (English Translation), 1983, p. 2175 - 2179
  作者：Bolestova, G. I.、Parnes, Z. N.、Kursanov, D. N.

  DOI：——

  日期：——