11-Hydroxy-undec-2-ensaeure-methylester | 65716-47-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 11-Hydroxy-undec-2-ensaeure-methylester
• 英文别名: methyl (E)-11-hydroxyundec-2-enoate
• CAS: 65716-47-4
• 化学式: C₁₂H₂₂O₃
• 分子量: 214.305
• InChiKey: QNSCKFXSWFKXJR-CSKARUKUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  11-Hydroxy-undec-2-ensaeure-methylester 在 sodium periodate 、 cerium(III) chloride 作用下， 以 乙酸乙酯 、 乙腈 为溶剂， 以44 mg的产率得到(2S,3R)-2,3,11-trihydroxyundecanoic acid methyl ester
  参考文献：
  名称：

  Ruthenium-Catalyzed Tandem Olefin Metathesis−Oxidations

  摘要：

  The utility of Grubbs' 2nd generation metathesis catalyst has been expanded by the development of two tandem olefin metathesis/oxidation protocols. These ruthenium-catalyzed processes provide cis-diols or r-hydroxy ketones from simple olefinic starting materials.

  DOI：

  10.1021/ol061837n
• 作为产物：
  描述：

  9-十烯-1-醇 、 丙烯酸甲酯（MA） 在 RuCl2(1,3-dimesityl-imidazolidin-2-yl)(PCy3)(=CHPh) 作用下， 以 二氯甲烷 为溶剂， 生成 11-Hydroxy-undec-2-ensaeure-methylester
  参考文献：
  名称：

  Ruthenium-Catalyzed Tandem Olefin Metathesis−Oxidations

  摘要：

  The utility of Grubbs' 2nd generation metathesis catalyst has been expanded by the development of two tandem olefin metathesis/oxidation protocols. These ruthenium-catalyzed processes provide cis-diols or r-hydroxy ketones from simple olefinic starting materials.

  DOI：

  10.1021/ol061837n

文献信息

• Preparation of amino acids and amino acid derivatives
  申请人：Umicore AG & Co. KG

  公开号：US10774035B2

  公开（公告）日：2020-09-15

  The invention relates to a method for synthesizing amino acids or amino acid derivatives involving cross metathesis of functionalized olefins and a tandem amination-reduction process. Amino acids and amino acid derivatives present many interesting physical and chemical properties finding many uses in the automotive, fuel, electronic, and textile industries.

  本发明涉及一种合成氨基酸或氨基酸衍生物的方法，包括官能化烯烃的交叉偏析和串联胺化还原过程。氨基酸和氨基酸衍生物具有许多有趣的物理和化学特性，在汽车、燃料、电子和纺织工业中用途广泛。
• POLYURETHANES CONTAINING DISPERSED CRYSTALLINE POLYESTERS
  申请人：DOW GLOBAL TECHNOLOGIES INC.

  公开号：EP1326909A2

  公开（公告）日：2003-07-16
• PREPARATION OF AMINO ACIDS AND AMINO ACID DERIVATIVES
  申请人：Umicore AG & Co. KG

  公开号：US20190276388A1

  公开（公告）日：2019-09-12

  The invention relates to a method for synthesizing amino acids or amino acid derivatives involving cross metathesis of functionalized olefins and a tandem amination-reduction process. Amino acids and amino acid derivatives present many interesting physical and chemical properties finding many uses in the automotive, fuel, electronic, and textile industries.
• US6849666B2
  申请人：——

  公开号：US6849666B2

  公开（公告）日：2005-02-01
• [EN] POLYURETHANES CONTAINING DISPERSED CRYSTALLINE POLYESTERS<br/>[FR] POLYURETHANES CONTENANT DES POLYESTERS CRISTALLINS DISPERSES
  申请人：DOW CHEMICAL CO

  公开号：WO2001088005A2

  公开（公告）日：2001-11-22

  A process is disclosed for producing resilient polyurethane foams by foaming an organic polyisocyanate, an isocyanate-reactive compound and a fusible polymer. The improvement in the hardness of the foams is achieved without adversely affecting the other properties of the foams, such as tensile strength and elongation.