9-[4,6-di(thiophen-2-yl)-1,3,5-triazin-2-yl]-9H-carbazole | 1342315-94-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-[4,6-di(thiophen-2-yl)-1,3,5-triazin-2-yl]-9H-carbazole
• 英文别名: 9-(4,6-Dithiophen-2-yl-1,3,5-triazin-2-yl)carbazole；9-(4,6-dithiophen-2-yl-1,3,5-triazin-2-yl)carbazole
• CAS: 1342315-94-9
• 化学式: C₂₃H₁₄N₄S₂
• 分子量: 410.523
• InChiKey: FMUJQMOUROWBRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  29
• 可旋转键数：
  3
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  100
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2-chloro-4,6-di(thiophen-2-yl)-1,3,5-triazine 、 咔唑 在 正丁基锂 、 四(三苯基膦)钯 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 12.0h， 以50%的产率得到9-[4,6-di(thiophen-2-yl)-1,3,5-triazin-2-yl]-9H-carbazole
  参考文献：
  名称：

  Conjugated Asymmetric Donor-Substituted 1,3,5-Triazines: New Host Materials for Blue Phosphorescent Organic Light-Emitting Diodes

  摘要：

  AbstractConjugated asymmetric donor‐substituted 1,3,5‐triazines (ADTs) have been synthesized by nucleophilic substitution of organolithium catalyzed by [Pd(PPh3)4]. Theoretical and experimental investigations show that ADTs possess high solubility and thermostability, high fluorescent quantum yield (35 %), low HOMO (−6.0 eV) and LUMO (−2.8 eV), and high triplet energy (ET, 3.0 eV) according to the different substitution pattern of triazine. The application as host materials for blue PHOLEDs yielded a maximum current efficiency of 20.9 cd A−1, a maximum external quantum efficiency of 9.8 %, and a brightness of 9671 cd m−2 at 5.4 V, making ADTs good candidates for optoelectronic devices.

  DOI：

  10.1002/chem.201101118

文献信息

• ORGANIC ELECTROLUMINESCENCE DEVICE
  申请人：Samsung Display Co., Ltd.

  公开号：US20210098713A1

  公开（公告）日：2021-04-01

  An organic electroluminescence device of the present embodiments includes a first electrode, a second electrode on the first electrode, and a first emission layer and a second emission layer, both between the first electrode and the second electrode, wherein the first emission layer includes a first host and a first dopant including an anthracene-based compound, the second emission layer includes a second host represented by Formula H-1 and a second dopant including an organometal compound, and the first emission layer and the second emission layer are adjacent to each other. The device of the present embodiments thereby shows high emission efficiency and long-life characteristics.
• Conjugated Asymmetric Donor-Substituted 1,3,5-Triazines: New Host Materials for Blue Phosphorescent Organic Light-Emitting Diodes
  作者：Zhong-Fu An、Run-Feng Chen、Jun Yin、Guo-Hua Xie、Hui-Fang Shi、Taiju Tsuboi、Wei Huang

  DOI：10.1002/chem.201101118

  日期：2011.9.19

  AbstractConjugated asymmetric donor‐substituted 1,3,5‐triazines (ADTs) have been synthesized by nucleophilic substitution of organolithium catalyzed by [Pd(PPh3)4]. Theoretical and experimental investigations show that ADTs possess high solubility and thermostability, high fluorescent quantum yield (35 %), low HOMO (−6.0 eV) and LUMO (−2.8 eV), and high triplet energy (ET, 3.0 eV) according to the different substitution pattern of triazine. The application as host materials for blue PHOLEDs yielded a maximum current efficiency of 20.9 cd A−1, a maximum external quantum efficiency of 9.8 %, and a brightness of 9671 cd m−2 at 5.4 V, making ADTs good candidates for optoelectronic devices.