3-(9-ethyl-9H-carbazol-3-yl)-1-(2-thienyl)prop-2-en-1-one | 382155-85-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3-(9-ethyl-9H-carbazol-3-yl)-1-(2-thienyl)prop-2-en-1-one
• 英文别名: 3-(9-ethylcarbazol-3-yl)-1-thiophen-2-ylprop-2-en-1-one
• CAS: 382155-85-3
• 化学式: C₂₁H₁₇NOS
• 分子量: 331.438
• InChiKey: ADAFURAUUUCJFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  50.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-(9-ethyl-9H-carbazol-3-yl)-1-(2-thienyl)prop-2-en-1-one 在 双氧水 、 potassium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 反应 1.5h， 生成 4-(9-ethyl-9H-carbazol-3-yl)-6-(2-thienyl)pyrimidin-2-amine
  参考文献：
  名称：

  New carbazole-containing chalcones and pyrimidines based thereon: Synthesis and electrochemical study

  摘要：

  Condensations of aromatic carbo- and heterocyclic ketones and aldehydes in methanol gave new chalcones containing carbazole fragments, 1,3-diaryl(9-R-9H-carbazol-3-yl)prop-2-en-1-ones. Some of the synthesized chalcones reacted with guanidine sulfate to produce 2-amino-4,6-diarylpyrimidines that are promising materials for the design of light emitting diodes. Study on electrochemical polymerization of both chalcones and pyrimidines derived therefrom showed that almost all the examined substrates give rise to stable colored conjugated polymer films on the surface of working electrode under conditions of cyclic voltammetry.

  DOI：

  10.1134/s1070428011040117
• 作为产物：
  描述：

  咔唑 在 苄基三乙基氯化铵 、 potassium hydroxide 、 sodium hydroxide 、 三氯氧磷 作用下， 以 甲醇 、 水 、 氯苯 、 丙酮 为溶剂， 反应 41.0h， 生成 3-(9-ethyl-9H-carbazol-3-yl)-1-(2-thienyl)prop-2-en-1-one
  参考文献：
  名称：

  New carbazole-containing chalcones and pyrimidines based thereon: Synthesis and electrochemical study

  摘要：

  Condensations of aromatic carbo- and heterocyclic ketones and aldehydes in methanol gave new chalcones containing carbazole fragments, 1,3-diaryl(9-R-9H-carbazol-3-yl)prop-2-en-1-ones. Some of the synthesized chalcones reacted with guanidine sulfate to produce 2-amino-4,6-diarylpyrimidines that are promising materials for the design of light emitting diodes. Study on electrochemical polymerization of both chalcones and pyrimidines derived therefrom showed that almost all the examined substrates give rise to stable colored conjugated polymer films on the surface of working electrode under conditions of cyclic voltammetry.

  DOI：

  10.1134/s1070428011040117

文献信息

• New carbazole-containing chalcones and pyrimidines based thereon: Synthesis and electrochemical study
  作者：R. V. Syutkin、G. G. Abashev、E. V. Shklyaeva、P. G. Kudryavtsev

  DOI：10.1134/s1070428011040117

  日期：2011.4

  Condensations of aromatic carbo- and heterocyclic ketones and aldehydes in methanol gave new chalcones containing carbazole fragments, 1,3-diaryl(9-R-9H-carbazol-3-yl)prop-2-en-1-ones. Some of the synthesized chalcones reacted with guanidine sulfate to produce 2-amino-4,6-diarylpyrimidines that are promising materials for the design of light emitting diodes. Study on electrochemical polymerization of both chalcones and pyrimidines derived therefrom showed that almost all the examined substrates give rise to stable colored conjugated polymer films on the surface of working electrode under conditions of cyclic voltammetry.