3,5-Dimethyl-1-adamantyl methacrylate | 23743-73-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 3,5-Dimethyl-1-adamantyl methacrylate
• 英文别名: 3,5-dimethyladamantyl (meth)acrylate；(3,5-Dimethyl-1-adamantyl) 2-methylprop-2-enoate
• CAS: 23743-73-9
• 化学式: C₁₆H₂₄O₂
• 分子量: 248.365
• InChiKey: ZGPJNXSGPFUODV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.81
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  甲基丙烯酸 、 3,5-二甲基-1-金刚烷醇 在 Acidic catalyst 作用下， 以 环己烷 为溶剂， 以95%的产率得到3,5-Dimethyl-1-adamantyl methacrylate
  参考文献：
  名称：

  Otsu, Takayuki; Matsumoto, Akikazu; Horie, Atsushi, Chemistry Letters, 1991, # 7, p. 1145 - 1148

  摘要：

  DOI：

文献信息

• Polymeric compound and resin composition for photoresist
  申请人：——

  公开号：US20020169266A1

  公开（公告）日：2002-11-14

  A photoresist polymeric compound includes a monomer unit represented by following Formula (I): 1 The polymeric compound may further include at least one of monomer units represented by following Formulae (IIa) to 2 wherein R 1 , R 13 , R 14 and R 15 are each a hydrogen atom or methyl group; R 2 and R 3 are each a hydrocarbon group having from 1 to 8 carbon atoms; R 4 , R 5 and R 6 are each a hydrogen atom, hydroxyl group or a methyl group; R 7 and R 8 are each a hydrogen atom, hydroxyl group or —COOR 9 group, where R 9 is a t-butyl group, 2-tetrahydropyranyl group, etc.; R 10 and R 11 are each a hydrogen atom, hydroxyl group or oxo group; R 12 is a hydrocarbon group having a tertiary carbon atom at a bonding site with an oxygen atom indicated in the formula; R 16 is a t-butyl group, 2-tetrahydropyranyl group, etc.; and n denotes an integer from 1 to 3. The photoresist polymeric compound can exhibit high adhesion to substrates and can highly precisely form fine patterns.

  一种光阻聚合物化合物包括以下式(I)所表示的单体单元：1该聚合物化合物还可以包括以下式(IIa)至(IIb)所表示的至少一种单体单元中的至少一种：其中，R1、R13、R14和R15均为氢原子或甲基基团；R2和R3均为具有1至8个碳原子的碳氢基团；R4、R5和R6均为氢原子、羟基或甲基基团；R7和R8均为氢原子、羟基或-COOR9基团，其中R9为叔丁基基团、2-四氢呋喃基团等；R10和R11均为氢原子、羟基或酮基；R12为具有在公式中指示的氧原子与三级碳原子成键位的碳氢基团；R16为叔丁基基团、2-四氢呋喃基团等；n表示1至3的整数。该光阻聚合物化合物可以表现出对基材的高粘附性，并可以高精度地形成细小图案。
• Isocyanate composition, microcapsule and production method thereof, and recording material
  申请人：Tamura Takashi

  公开号：US20050153839A1

  公开（公告）日：2005-07-14

  The present invention provides an isocyanate composition including an adduct of a multifunctional isocyanate compound having two or more isocyanate groups in the molecule thereof with a polymer obtained by radically polymerizing in the presence of a chain transfer agent having active hydrogen at least a vinyl monomer including a polymerizable compound having a polyether represented by the following Formula (I): A 1 -(L-O) n -B 1 Formula (I) wherein A 1 represents a group having an ethylenically unsaturated double bond; L represents an alkylene group; B 1 represents an alkyl group or an aryl group; and n is an average polymerization degree of the polyether and represents a number of 8 to 300.

  本发明提供了一种异氰酸酯组合物，包括多功能异氰酸酯化合物的加合物，其分子中有两个或更多的异氰酸基团，并与在链转移剂存在下的自由基聚合物共聚得到的聚合物，该链转移剂具有活性氢，至少包括一种乙烯单体，包括具有以下式子（I）所表示的聚醚的可聚合化合物：A1-(L-O)n-B1，其中A1表示具有乙烯双键的基团；L表示一个烷基基团；B1表示一个烷基基团或芳基基团；n是聚醚的平均聚合度，表示8至300的数字。
• Optical fiber
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0154339A2

  公开（公告）日：1985-09-11

  An optical fiber comprising a core and a cladding, wherein the core is made of a polymer comprising units of methyl methacrylate, and the cladding is made of a copolymer comprising units of vinylidene fluoride and 0.5 to 10 % by mole of units of hexafluoropropene, which has good heat resistance and flexibility and is excellent in adhesivity between the core and the cladding.

  一种由纤芯和包层组成的光纤，其中纤芯由包含甲基丙烯酸甲酯单元的聚合物制成，包层由包含偏氟乙烯基单元和 0.5%至 10%（以摩尔计）六氟丙烯单元的共聚物制成，它具有良好的耐热性和柔韧性，并且在纤芯和包层之间具有极佳的粘合性。
• Method for producing plastic optical fiber with heat resistance
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0190656A2

  公开（公告）日：1986-08-13

  A plastic optical fiber with excellent heat resistance comprising a core made of a polymer comprising units of methyl methacrylate and a cladding made of a polymer containing at least 20% by weight of fluorine is produced by washing the core polymer with an organic solvent in which the core polymer is substantially insoluble, forming the core from the washed core polymer and forming the cladding around the core.

  一种具有优异耐热性能的塑料光纤，包括由包含甲基丙烯酸甲酯单元的聚合物制成的芯材和由含氟量至少 20% （按重量计）的聚合物制成的包层，其生产方法是：用芯材聚合物基本不溶于其中的有机溶剂清洗芯材聚合物，用清洗后的芯材聚合物形成芯材，并在芯材周围形成包层。
• COATING COMPOSITION AND SURFACE-COATED MOLDING PRODUCED THEREWITH
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP0696621A1

  公开（公告）日：1996-02-14

  A coating composition comprising: (a) a cross-linking polymerizable compound (a-1) having at least two (meth)acryloyloxy groups in its molecule or a mixture of the compound (a-1) and a compound (a-2) copolymerizable therewith; (b) fine silica particles with their surfaces modified with a hydrolyzate of a mixture of a silane compound (b-1) capable of binding with the component (a) and another silane compound (b-2) incapable of binding with the component (a); and (c) an initiator for actinic radiation-induced polymerization. The composition can give a cured coating having a high surface strength and an excellent weathering resistance, and is applicable without using any solvent.

  一种涂料组合物，包括(a) 可交联聚合的化合物（a-1），其分子中至少有两个（甲基）丙烯酰氧基，或该 化合物（a-1）和可与之共聚的化合物（a-2）的混合物；(b) 细二氧化硅颗粒，其表面用能与组分（a）结合的硅烷化合物（b-1）和不能与组分 （a）结合的另一种硅烷化合物（b-2）的混合物的水解物改性；以及 (c) 用于光辐射诱导聚合的引发剂。该组合物可制成具有高表面强度和优异耐候性的固化涂层，且无需使用任何溶剂。