1-(4-{[4-(1-Naphthyloxy)phenyl]sulfonyl}phenoxy)naphthalene

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(4-{[4-(1-Naphthyloxy)phenyl]sulfonyl}phenoxy)naphthalene
• 英文别名: 1-[4-(4-naphthalen-1-yloxyphenyl)sulfonylphenoxy]naphthalene
• 化学式: C₃₂H₂₂O₄S
• 分子量: 502.6
• InChiKey: YXDVFKLDISXBSU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  37
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  61
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Process for producing a film-like and fibrous article of a wholly aromatic polyester
  申请人：TEIJIN LIMITED

  公开号：EP0070539A1

  公开（公告）日：1983-01-26

  A wholly aromatic polyester composition comprising (a) 100 parts by weight of a wholly aromatic polyester containing as a main component at least one compound selected from the group consisting of aromatic dicarboxylic acids, aromatic dihydroxy compounds and aromatic hydroxycarboxylic acids, and (b) from 5 to 300 parts by weight of a low-molecular-weight compound being substantially non-reactive with the wholly aromatic polyester and having a boiling point of at least about 200°C under atmospheric pressure and a molecular weight of not more than 1.000. The wholly aromatic polyester composition is produced advantageously by polycondensing in the molten state the polyester-forming starting mixture in the presence of the low-molecular-weight compound. A film-like or fibrous article of a wholly aromatic polyester may be produced by extracting the low-molecular-weight compound from a film-like or fibrous article of the wholly aromatic polyester composition.

  全芳香族聚酯组合物，包括 (a) 100 份（按重量计）全芳香族聚酯，其主要成分含有至少一种选自芳香族二 羧酸、芳香族二羟基化合物和芳香族羟基羧酸的化合物，以及 (b) 5 至 300 重量份的低分子量化合物，该化合物与全芳香族聚酯基本不发生 反应，在常压下沸点至少约为 200℃，分子量不超过 1.000。 全芳香族聚酯组合物的有利生产方法是在低分子量化合物存在下，在熔融状态下对聚酯形成起始混合物进行缩聚。 全芳香族聚酯的薄膜状或纤维状制品可通过从全芳香族聚酯组合物的薄膜状或纤维状制品中提取低分子量化合物而制成。
• Wholly aromatic polyester composition and process for producing it
  申请人：TEIJIN LIMITED

  公开号：EP0156966A1

  公开（公告）日：1985-10-09

  A wholly aromatic polyester composition comprising (a) 100 parts by weight of a wholly aromatic polyester containing as a main component at least one compound selected from the group consisting of aromatic dicarboxylic acids, aromatic dihydroxy compounds and aromatic hydroxycarboxylic acids, and (b) from 5 to 300 parts by weight of a low-molecular-weight compound, which is non-reactive with the wholly caromatic polyester and has a boiling point of at least 200 °C under atmospheric pressure and a molecular weight of not more than 1,000 and is selected from the group consisting of imide compounds of the formula (1)-a wherein A' represents a divalent aromatic group which may be substituted; R1 represents an aromatic group or linear or cyclic aliphatic group having a valence of n, each of which may be substituted; n is 1 or 2; and the imide ring is 5- or 6-membered, imide compounds of formula (1)-b wherein A2 represents a tetravalent aromatic group which may be substituted; R2 represents a monovalent linear or cyclic aliphatic group which may be substituted; and the imide rings are 5- or 6-membered, trialkyl isocyanurates of formula (1)-c wherein R3 represents a monovalent alkyl group,and diphenyl sulfone compounds of formula (1)-d wherein the phenyl rings may be substituted.

  全芳香族聚酯组合物，包括 (a) 100 份（按重量计）全芳香族聚酯，其主要成分含有至少一种选自芳香族二 羧酸、芳香族二羟基化合物和芳香族羟基羧酸的化合物，以及 (b) 5 至 300 重量份的低分子量化合物，该化合物与全芳香族聚酯不发生反应，在常 压下沸点至少为 200 °C，分子量不超过 1,000，且选自由式 (1)-a 的酰亚胺化 合物组成的组。 其中 A'代表可被取代的二价芳香族基团；R1 代表芳香族基团或价数为 n 的线性或环状脂肪族基团，每个基团均可被取代；n 为 1 或 2；亚胺环为 5 或 6 元环；式 (1)-b 的亚胺化合物 其中 A2 代表可被取代的四价芳香族基团；R2 代表可被取代的一价线性或环状脂肪族基团；亚胺环是式 (1)-c 的 5 或 6 元三烷基异氰尿酸酯 式(1)-d的二苯砜化合物，其中R3代表一价烷基。 其中的苯基环可能被取代。
• Poly(dinaphthyl arylene ether)and preparation thereof
  申请人：THE B.F. GOODRICH COMPANY

  公开号：EP0282096A2

  公开（公告）日：1988-09-14

  When two 4-naphthoxyphenyl moieties are connected through a polar linking group, Y, it does not interfere with an oxidation process which results in dehydrogena­tive polymerization to yield polyarylene polyether (PAPE) polymers having a weight average mol wt greater than 10,000. Homo- and copolymers having a repeating unit in which a 4,4ʹ-di(1-naphthoxyphenyl) moiety is connected through its phenyl rings to a bivalent polar residue are descrbed. A specific monomer is selected from the group consisting of 4,4ʹ-di(1-naphthoxy)diphenyl sulfone (DNDPS, Y= SO₂) and, 4,4ʹ-di(1-naphthoxy)benzophenone (DNBP, Y= CO). Because the process provides thermoplastic PAPE poly­mers having a Tg in the range from about 250°C to about 350°C with excellent physical properties, the polymers are suitable for use in the fabrication of composites for aerospace vehicles subjected to elevated temperatures.

  当两个 4-萘氧苯基分子通过极性连接基团 Y 连接时，不会干扰氧化过程，而氧化过程会导致脱氢聚合，生成平均摩尔质量大于 10,000 的聚芳基聚醚（PAPE）聚合物。描述了具有重复单元的均聚物和共聚物，在重复单元中，4,4ʹ-二（1-萘氧基苯基）分子通过其苯基环与二价极性残基相连。特定单体选自 4,4ʹ-二（1-萘氧基）二苯砜（DNDPS，Y= SO₂）和 4,4ʹ-二（1-萘氧基）二苯甲酮（DNBP，Y= CO）组成的组。由于该工艺提供的热塑性 PAPE 聚合物的 Tg 范围在约 250°C 至约 350°C 之间，且具有优异的物理性能，因此该聚合物适用于制造用于高温环境下航空航天飞行器的复合材料。
• US4188276A
  申请人：——

  公开号：US4188276A

  公开（公告）日：1980-02-12
• US4416839A
  申请人：——

  公开号：US4416839A

  公开（公告）日：1983-11-22