[(2R,3R,4S)-2,3,4,6-tetrahydroxy-5-oxohexyl] [(3S,4R,5R)-4,5,6-trihydroxy-3-[hydroxy-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyphosphoryl]oxy-2-oxohexyl] hydrogen phosphate

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(2R,3R,4S)-2,3,4,6-tetrahydroxy-5-oxohexyl] [(3S,4R,5R)-4,5,6-trihydroxy-3-[hydroxy-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyphosphoryl]oxy-2-oxohexyl] hydrogen phosphate
• 化学式: C₁₈H₃₄O₂₂P₂
• 分子量: 664.4
• InChiKey: RPFBPVVDZYGWIL-NAQKDTEPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -9.3
• 重原子数：
  42
• 可旋转键数：
  19
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  377
• 氢给体数：
  13
• 氢受体数：
  22

文献信息

• EP2909318A1
  申请人：——

  公开号：EP2909318A1

  公开（公告）日：2015-08-26
• [EN] A THERMOSTABLE SUCROSE AND SUCROSE-6'-PHOSPHATE PHOSPHORYLASE<br/>[FR] SACCHAROSE ET PHOSPHORYLASE DE SACCHAROSE-6'-PHOSPHATE THERMOSTABLES
  申请人：UNIV GENT

  公开号：WO2014060452A1

  公开（公告）日：2014-04-24

  The present invention relates to the identification, recombinant expression and characterization of a sucrose and sucrose-6'-phosphate phosphorylase of the thermophilic bacterium Thermoanaerobacterium thermosaccharolyticum. The enzyme has an optimal temperature of about 55°C and has a high specificity for its substrates. More importantly, the sucrose and sucrose-6'-phosphate phosphorylase of the present invention has a half-life of at least 60 hours at the industrially relevant temperature of about 60°C. This enzyme is thus -for example-useful for the industrial production of D-fructose,D-fructose-6-phosphate,alpha-D-glucose -1-phosphate or alpha-D-glucosides.