(E)-1,1-bis(2,2,2-trifluoroethoxy)oct-2-ene

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (E)-1,1-bis(2,2,2-trifluoroethoxy)oct-2-ene
• 化学式: C₁₂H₁₈F₆O₂
• 分子量: 308.26
• InChiKey: QQTIGDNVPRDFMN-VOTSOKGWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  8

文献信息

• [EN] (6R,10R)-6,10,14-TRIMETYLPENTADECAN-2-ONE PREPARED FROM 3,7-DIMETYLOCT-2-ENAL OR 3,7-DIMETYLOCTA-2,6-DIENAL<br/>[FR] (6R,10R)-6,10,14-TRIMÉTHYLPENTADÉCAN-2-ONE PRÉPARÉE À PARTIR DE 3,7-DIMÉTHYLOCT-2-ÉNAL OU 3,7-DIMÉTHYLOCTA-2,6-DIÉNAL
  申请人：DSM IP ASSETS BV

  公开号：WO2014096063A1

  公开（公告）日：2014-06-26

  The present invention relates to a process of manufacturing (6R,10R)-6,10,14-trimetylpentadecan-2-one in a multistep synthesis from 3,7-dimetyloct-2-enal or 3,7-dimetylocta-2,6-dienal. The process is very advantageous in that it forms the desired chiral product from a mixture of stereoisomers of the starting product in an efficient way.

  本发明涉及一种以3,7-二甲基辛-2-烯醛或3,7-二甲基辛-2,6-二烯醛为起始物，通过多步合成法制备(6R,10R)-6,10,14-三甲基十五烷-2-酮的过程。该工艺的非常有利之处在于它能从起始产品的立体异构体混合物中以高效的方式形成所需的手性产物。
• NITROGEN MONOXIDE AS CIS/TRANS ISOMERIZATION CATALYSTS FOR UNSATURATED COMPOUNDS
  申请人：DSM IP Assets B.V.

  公开号：EP2935178A1

  公开（公告）日：2015-10-28
• POLYTHIOLS AS CIS/TRANS ISOMERIZATION CATALYSTS FOR UNSATURATED COMPOUNDS
  申请人：DSM IP Assets B.V.

  公开号：EP2935186A1

  公开（公告）日：2015-10-28
• (6R,10R)-6,10,14-TRIMETYLPENTADECAN-2-ONE PREPARED FROM 3,7-DIMETYLOCT-2-ENAL OR 3,7-DIMETYLOCTA-2,6-DIENAL
  申请人：DSM IP Assets B.V.

  公开号：EP2935191A1

  公开（公告）日：2015-10-28
• [EN] POLYTHIOLS AS CIS/TRANS ISOMERIZATION CATALYSTS FOR UNSATURATED COMPOUNDS<br/>[FR] POLYTHIOLS À TITRE DE CATALYSEURS D'ISOMÉRISATION CIS/TRANS POUR COMPOSÉS INSATURÉS
  申请人：DSM IP ASSETS BV

  公开号：WO2014097171A1

  公开（公告）日：2014-06-26

  The present invention relates to a process of a cis/trans isomerization of an unsaturated compound A being selected from the group consisting of unsaturated ketones, unsaturated ketals, unsaturated aldehydes, unsaturated acetals, unsaturated carboxylic acids, esters of an unsaturated carboxylic acid and amides of an unsaturated carboxylic acid using polythiol as cis/trans isomerization catalyst. It has been observed that the isomerization is very efficient and fast.