4,5-diphenyl-1-(1,1,2,2-tetrafluoroethyl)-1H-imidazole | 1242241-07-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 4,5-diphenyl-1-(1,1,2,2-tetrafluoroethyl)-1H-imidazole
• 英文别名: 4,5-Diphenyl-1-(1,1,2,2-tetrafluoroethyl)-1h-imidazole；4,5-diphenyl-1-(1,1,2,2-tetrafluoroethyl)imidazole
• CAS: 1242241-07-1
• 化学式: C₁₇H₁₂F₄N₂
• 分子量: 320.289
• InChiKey: QNVMPAGNBOLHDN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  17.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4,5-diphenyl-1-(1,1,2,2-tetrafluoroethyl)-1H-imidazole 、 碘甲烷 以 乙腈 为溶剂， 反应 10.0h， 以87%的产率得到1-methyl-3-(1,1,2,2-tetrafluoroethyl)-4,5-diphenyl-1H-imidazolium iodide
  参考文献：
  名称：

  N-(polyfluoroalkyl)imidazolium-2-carbodithioates

  摘要：

  Chemical properties of carbenes derived from 1-methyl-3-polyfluoroalkylimidazolium salts were studied. These unstable intermediate products reacted with carbon disulfide to give the corresponding imidazolium-2-carbodithioates which were subjected to methylation at the sulfur atom.

  DOI：

  10.1134/s1070428010060217
• 作为产物：
  描述：

  1-(2-bromotetrafluoroethyl)-4,5-diphenyl-1H-imidazole 在 盐酸 、 锌 作用下， 以 乙醇 、 水 为溶剂， 反应 4.0h， 以87%的产率得到4,5-diphenyl-1-(1,1,2,2-tetrafluoroethyl)-1H-imidazole
  参考文献：
  名称：

  N-(polyfluoroalkyl)imidazolium-2-carbodithioates

  摘要：

  Chemical properties of carbenes derived from 1-methyl-3-polyfluoroalkylimidazolium salts were studied. These unstable intermediate products reacted with carbon disulfide to give the corresponding imidazolium-2-carbodithioates which were subjected to methylation at the sulfur atom.

  DOI：

  10.1134/s1070428010060217

文献信息

• N-(polyfluoroalkyl)imidazolium-2-carbodithioates
  作者：L. M. Yagupol’skii、Yu. P. Kokhanovskii、K. I. Petko

  DOI：10.1134/s1070428010060217

  日期：2010.6

  Chemical properties of carbenes derived from 1-methyl-3-polyfluoroalkylimidazolium salts were studied. These unstable intermediate products reacted with carbon disulfide to give the corresponding imidazolium-2-carbodithioates which were subjected to methylation at the sulfur atom.