9,9,12,12-Tetramethyl-1,4,7,11-tetraoxacyclotetradecane

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 9,9,12,12-Tetramethyl-1,4,7,11-tetraoxacyclotetradecane
• 英文别名: 9,9,12,12-tetramethyl-1,4,7,11-tetraoxacyclotetradecane
• 化学式: C₁₄H₂₈O₄
• 分子量: 260.37
• InChiKey: KWTZNPGCSKOJNE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• METHOD FOR PRODUCING BRANCHED FUNCTIONALIZED DIENE (CO)POLYMERS
  申请人：Open Joint Stock Company "SIBUR Holding"

  公开号：US20140249276A1

  公开（公告）日：2014-09-04

  The invention relates to the field of producing synthetic rubbers, in particular diene (co)polymers, such as polybutadiene, polyisoprene and styrene-butadiene rubber (SBR), which can be used in the production of tyres and industrial rubber articles, in the modification of bitumens, in electrical engineering and in other fields. The method consists of a polymerization process or a copolymerization process which is carried out in two parallel reactors, and each of dienes are polymerized or copolymerized with each other and/or with arylvinyl compounds, wherein an organolithium initiator, an electron donor additive and a branching agent are fed into the first reactor, and an organo lithium initiator, an electron donor additive and a functionalizing agent are fed into the second reactor, and the resultant polymerized mixtures are subsequently mixed with each other. This method allows for producing branched functionalized (co)polymers of dienes that are characterized by a statistical distribution of monomer units, a high content of vinyl units (1,2-butadiene units and/or 3,4-isoprene units (more than 60%)), a narrow molecular weight distribution and a controllable content of branched and functionalized parts in the (co)polymer.
• US9611384B2
  申请人：——

  公开号：US9611384B2

  公开（公告）日：2017-04-04