Hexan-2-ol;hexan-3-ol

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: Hexan-2-ol;hexan-3-ol
• 英文别名: hexan-2-ol;hexan-3-ol
• 化学式: C12H28O2
• 分子量: 204.35
• InChiKey: MVDMNXPDKXVGGC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.11
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• Water-insoluble Ruthenium catalyst composition for use in aqueous hydrogenation reactions
  申请人：Jost, Sonja

  公开号：EP2774674A1

  公开（公告）日：2014-09-10

  The invention relates to a method for converting a precatalyst complex to an active catalyst complex, wherein the precatalyst complex and the active catalyst complex comprise a ruthenium atom and an optically active ligand that is insoluble in water, and the active catalyst complex furthermore comprises a monohydride and a water molecule. The method comprises the steps of providing water as an activation solvent system with a pH value equal or below 2, and solving said precatalyst complex, an acid, and hydrogen therein. The invention further relates to a method for manufacturing a catalyst composition, a method for hydrogenating a substrate molecule and a reaction mixture.

  本发明涉及一种将前催化剂复合物转化为活性催化剂复合物的方法，其中前催化剂复合物和活性催化剂复合物包括一种钌原子和一种在水中不溶的光学活性配体，而活性催化剂复合物还包括一种单氢化物和一种水分子。该方法包括提供水作为激活溶剂体系，其pH值等于或低于2，并在其中溶解所述前催化剂复合物、酸和氢。本发明还涉及一种制备催化剂组合物的方法、一种加氢底物分子的方法和反应混合物。
• Conductive ink compositions
  申请人：ELECTRONINKS INCORPORATED

  公开号：US10301497B2

  公开（公告）日：2019-05-28

  A conductive structure is provided. The conductive ink composition includes a silver complex formed by mixing a silver carboxylate, at least one dissolving agent that dissolves the silver carboxylate, and a catalyst. The catalyst includes an amine that decarboxylates the silver carboxylate to make the conductive ink composition. The catalyst decarboxylates the silver carboxylate at a temperature of 100° C. or less. An ink composition comprising a metallic salt with a sterically bulky counter ion and a ligand is also provided. An ink composition for making a conductive structure, comprising a reducible metal complex formed by mixing: a reducing agent, wherein the reducing agent is dissolved in a dissolving agent; and at least one metal salt or metal complex comprising a Group 4, 5, 6, 7, 8, 9, 10, 11, or 12 metal, wherein the reducing agent reduces the metal to form the conductive structure is further provided.

  提供了一种导电结构。导电油墨组合物包括由羧酸银、至少一种溶解羧酸银的溶解剂和催化剂混合形成的银络合物。催化剂包括一种胺，它能使羧酸银脱羧，从而制成导电油墨组合物。催化剂在 100 摄氏度或更低的温度下使羧酸银脱羧。此外，还提供了一种油墨组合物，该组合物由带有固态笨重反离子的金属盐和配体组成。还提供了一种用于制造导电结构的油墨组合物，该组合物包含通过混合以下物质形成的可还原金属复合物：还原剂，其中还原剂溶解在溶解剂中；以及至少一种金属盐或金属复合物，其中金属盐或金属复合物包含第 4、5、6、7、8、9、10、11 或 12 族金属，其中还原剂还原金属以形成导电结构。
• CONDUCTIVE INK COMPOSITIONS
  申请人：ELECTRONINKS INCORPORATED

  公开号：US20170210930A1

  公开（公告）日：2017-07-27

  A conductive structure is provided. The conductive ink composition includes a silver complex formed by mixing a silver carboxylate, at least one dissolving agent that dissolves the silver carboxylate, and a catalyst. The catalyst includes an amine that decarboxylates the silver carboxylate to make the conductive ink composition. The catalyst decarboxylates the silver carboxylate at a temperature of 100° C. or less. An ink composition comprising a metallic salt with a sterically bulky counter ion and a ligand is also provided. An ink composition for making a conductive structure, comprising a reducible metal complex formed by mixing: a reducing agent, wherein the reducing agent is dissolved in a dissolving agent; and at least one metal salt or metal complex comprising a Group 4, 5, 6, 7, 8, 9, 10, 11, or 12 metal, wherein the reducing agent reduces the metal to form the conductive structure is further provided.