[(2S,3R,4R,5R)-3,4,5-trihydroxy-6-oxohexan-2-yl] carbamate

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(2S,3R,4R,5R)-3,4,5-trihydroxy-6-oxohexan-2-yl] carbamate
• 化学式: C₇H₁₃NO₆
• 分子量: 207.18
• InChiKey: ANHKBSXVXMNDTO-BXKVDMCESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.4
• 重原子数：
  14
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  130
• 氢给体数：
  4
• 氢受体数：
  6

文献信息

• [EN] IMIDAZOISOQUINOLINE COMPOUNDS, COMPOSITIONS COMPRISING THE COMPOUNDS AND THEIR USE FOR CONTROLLING INVERTEBRATE PESTS<br/>[FR] COMPOSÉS IMIDAZOISOQUINOLÉINE, COMPOSITIONS COMPRENANT LES COMPOSÉS ET LEUR UTILISATION POUR LUTTER CONTRE DES ORGANISMES NUISIBLES INVERTÉBRÉS
  申请人：BASF SE

  公开号：WO2016113271A1

  公开（公告）日：2016-07-21

  The present invention relates to novel imidazoisoquinoline compounds of the formula I and the N-oxides, stereoisomers, tautomers and agriculturally or veterinarily acceptable salts thereof wherein A1 is N or C(R2), A2 is N or C(R3); A3 is N or C(R4); A4 is N or C(R5); A5 is N or C(R6); and where Ar, R, R1, R2, R3, R4,R5 and R6 are as defined in the claims. The compounds of formula (I), as well as the N-oxides, stereoisomers, tautomers and agriculturally or veterinarily acceptable salts thereof, are useful for combating or controlling invertebrate pests, in particular arthropod pests and nematodes. The invention also relates to a method for controlling invertebrate pests by using these compounds and to plant propagation material and to an agricultural and a veterinary composition comprising said compounds.

  本发明涉及具有以下结构的新型咪唑异喹啉化合物及其N-氧化物、立体异构体、互变异构体和农业或兽医可接受的盐：其中A1为N或C(R2)，A2为N或C(R3)；A3为N或C(R4)；A4为N或C(R5)；A5为N或C(R6)；Ar、R、R1、R2、R3、R4、R5和R6的定义如索赔中所述。式(I)的化合物及其N-氧化物、立体异构体、互变异构体和农业或兽医可接受的盐，可用于对抗或控制无脊椎动物害虫，特别是节肢动物害虫和线虫。该发明还涉及一种利用这些化合物控制无脊椎动物害虫的方法，以及包含所述化合物的植物繁殖材料和农业和兽医组合物。
• [EN] IMPROVED PROCESS FOR PREPARATION OF 4-(1-(4-(PERFLUOROETHOXY)PHENYL)-1H-1,2,4-TRIAZOL-3-YL)BENZOYL AZIDE<br/>[FR] PROCÉDÉ AMÉLIORÉ POUR LA PRÉPARATION DE 4-(1-(4-(PERFLUOROÉTHOXY)PHÉNYL)-1H-1,2,4-TRIAZOL-3-YL)BENZOYL AZOTURE
  申请人：DOW AGROSCIENCES LLC

  公开号：WO2016007726A1

  公开（公告）日：2016-01-14

  By either forming a triaryl acid halide or a triaryl mixed anhydride and subsequently treating with aqueous sodium azide, triaryl acyl azides are prepared in high yield using inexpensive reagents in a process in which by-products are easily removed from the triaryl acyl azide.

  通过形成三芳基酸卤化物或三芳基混合酸酐，然后用水合物钠叠氮处理，使用廉价试剂高收率地制备三芳基酰基叠氮化物，在该过程中，副产物很容易从三芳基酰基叠氮化物中去除。
• [EN] IMPROVED PROCESS FOR THE PREPARATION OF CERTAIN TRIARYL RHAMNOSE CARBAMATES<br/>[FR] PROCÉDÉ AMÉLIORÉ POUR PRÉPARER CERTAINS TRIARYL RHAMNOSE CARBAMATES
  申请人：DOW AGROSCIENCES LLC

  公开号：WO2014204622A1

  公开（公告）日：2014-12-24

  Triaryl rhamnose carbamate insecticides are prepared from triaryl acyl azides and tetrahydropyran-2-ols in good yield without the use of a hydride base.

  三芳基鼠李糖氨基甲酸酯杀虫剂可以在无需使用氢化物碱的情况下，通过三芳基酰基叠氮化合物和四氢吡喃-2-醇的反应得到高收率。
• PROCESS FOR THE PREPARATION OF CERTAIN TRIARYL RHAMNOSE CARBAMATES
  申请人：DOW AGROSCIENCES LLC

  公开号：US20140378674A1

  公开（公告）日：2014-12-25

  Triaryl rhamnose carbamate insecticides are prepared from triaryl acyl azides and tetrahydropyran-2-ols in good yield without the use of a hydride base.

  三芳基鼠李糖氨基甲酸酯杀虫剂可以在不使用氢化物碱的情况下，通过三芳基酰基叠氮化合物和四氢吡喃-2-醇高产率制备。
• PROCESS FOR PREPARATION OF 4-(1-(4-(PERFLUOROETHOXY)PHENYL)-1H-1,2,4-TRIAZOL-3-YL)BENZOYL AZIDE
  申请人：Dow AgroSciences LLC

  公开号：US20160009665A1

  公开（公告）日：2016-01-14

  By either forming a triaryl acid halide or a triaryl mixed anhydride and subsequently treating with aqueous sodium azide, triaryl acyl azides are prepared in high yield using inexpensive reagents in a process in which by-products are easily removed from the triaryl acyl azide.

  通过形成三芳基酸卤化物或三芳基混合酸酐，然后用水合硼酸钠处理，使用廉价试剂高产率地制备三芳基酰基叠氮化物，该过程中副产物容易从三芳基酰基叠氮化物中去除。