2,2,6,6-tetramethyl-4-[[5-bromo-1-oxopentyl]oxo]-1-piperidinyloxyl | 1025769-20-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2,2,6,6-tetramethyl-4-[[5-bromo-1-oxopentyl]oxo]-1-piperidinyloxyl
• CAS: 1025769-20-3
• 化学式: C₁₄H₂₇BrNO₃
• 分子量: 337.277
• InChiKey: SVNCRRWVADOYJF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  30.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,2,6,6-tetramethyl-4-[[5-bromo-1-oxopentyl]oxo]-1-piperidinyloxyl 在 苯肼 作用下， 生成
  参考文献：
  名称：

  Increasing the Persistency of Stable Free-Radicals: Synthesis and Characterization of a Nitroxide Based [1]Rotaxane

  摘要：

  A persistent paramagnetic [1]rotaxane based on beta-cyclodextrin showing an increased persistency under reductive conditions has been prepared and characterized for the first time.

  DOI：

  10.1021/ol800405b
• 作为产物：
  描述：

  5-溴戊酰氯 、 阻聚剂701 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以68%的产率得到2,2,6,6-tetramethyl-4-[[5-bromo-1-oxopentyl]oxo]-1-piperidinyloxyl
  参考文献：
  名称：

  Increasing the Persistency of Stable Free-Radicals: Synthesis and Characterization of a Nitroxide Based [1]Rotaxane

  摘要：

  A persistent paramagnetic [1]rotaxane based on beta-cyclodextrin showing an increased persistency under reductive conditions has been prepared and characterized for the first time.

  DOI：

  10.1021/ol800405b

文献信息

• Increasing the Persistency of Stable Free-Radicals: Synthesis and Characterization of a Nitroxide Based [1]Rotaxane
  作者：Paola Franchi、Michela Fanì、Elisabetta Mezzina、Marco Lucarini

  DOI：10.1021/ol800405b

  日期：2008.5.1

  A persistent paramagnetic [1]rotaxane based on beta-cyclodextrin showing an increased persistency under reductive conditions has been prepared and characterized for the first time.