6,6'-二甲基-3,3'-联哒嗪 | 24049-45-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 中文名称: 6,6'-二甲基-3,3'-联哒嗪
• 英文名称: 6,6'-dimethyl-3,3'-bipyridazine
• 英文别名: 3-methyl-6-(6-methylpyridazin-3-yl)pyridazine
• CAS: 24049-45-4
• 化学式: C₁₀H₁₀N₄
• mdl: MFCD03411812
• 分子量: 186.216
• InChiKey: CMFATCQPFXCGRZ-UHFFFAOYSA-N

物化性质

• 熔点：
  240.0-240.2 °C
• 沸点：
  461.0±40.0 °C(Predicted)
• 密度：
  1.162±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2933990090

反应信息

• 作为反应物：
  描述：

  6,6'-二甲基-3,3'-联哒嗪 、 4-(二丁基氨基)苯甲醛 在 对甲苯磺酸 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以25%的产率得到4,4'-(1E,1'E)-2,2'-(3,3'-bipyridazine-6,6'-diyl)bis(ethene-2,1-diyl)bis(N,N-dibutylaniline)
  参考文献：
  名称：

  Rodlike Fluorescent π-Conjugated 3,3′-Bipyridazine Ligand: Optical, Electronic, and Complexation Properties

  摘要：

  We report on the design and synthesis of a new quadrupolar pi-conjugated 3,3'-bipyridazine D-A-D ligand Its electronic and optical properties were investigated. Besides high fluorescence and pronounced solvatochromism, it exhibits an inherent electroactivity exploited to build an organic green light emitting device. Moreover, the ability of this ligand to complex metallic centers (Cu-I, Ni-II, Pt-II, and Ir-III) was also investigated to access different geometries and to tune their electronic and optical properties These preliminary results open up the synthesis of heavy-metal complexes to obtain phosphorescent emitters

  DOI：

  10.1021/ic901925w
• 作为产物：
  描述：

  3-氯-6-甲基哒嗪 在 2,2'-bipyridine*NiBr₂ 2-溴甲苯 、 四丁基溴化铵 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 6,6'-二甲基-3,3'-联哒嗪
  参考文献：
  名称：

  Preparation of Functionalized Aryl- and Heteroarylpyridazines by Nickel-Catalyzed Electrochemical Cross-Coupling Reactions

  摘要：

  A general efficient electrochemical method for the preparation of aryl- and heteroarylpyridazines in a nickel-catalyzed cross-coupling reaction of 3-chloro-6-methoxypyridazine and 3-chloro-6-methylpyridazine with a range of functionalized aryl or heteroaryl halides is reported.

  DOI：

  10.1021/jo070429+

文献信息

• Pyridazine and Pyrrole Compounds, Processes For Obtaining Them and Uses
  申请人：Dubreuil Didier Max

  公开号：US20100298562A1

  公开（公告）日：2010-11-25

  The present invention relates to nonlinear oligopyridazine compounds, to processes for obtaining them, to their uses, and also to their reduction to oligopyrroles and to the uses of the pyridazinylpyrrole and oligopyrrole compounds obtained. The invention relates in particular to the uses as medicaments, in particular for treating pathologies such as cancer, bacterial infections or parasitic infections, and also the uses in the materials, environmental, electronics and optics field.

  本发明涉及非线性寡吡啶化合物，以及获得它们的方法，它们的用途，以及将它们还原为寡吡咯和所获得的吡啶基吡咯和寡吡咯化合物的用途。该发明特别涉及用作药物的用途，特别是用于治疗癌症、细菌感染或寄生虫感染等病理的用途，以及在材料、环境、电子和光学领域的用途。
• LINEAR PYRIDAZINE AND PYRROLE COMPOUNDS, METHOD FOR OBTAINING THEM AND APPLICATIONS
  申请人：Dubreuil Didier Max

  公开号：US20100004443A1

  公开（公告）日：2010-01-07

  The present invention relates to linear pyridazine compounds, and more particularly to those of these compounds which are oligopyridazine compounds, to processes for obtaining them, to their uses, and also to their reduction to pyrroles and to the uses of the pyrrole, pyridazinylpyrrole and oligopyrrole compounds obtained. The invention relates in particular to the uses as medicaments, in particular for treating pathologies such as cancer, bacterial infections or parasitic infections, and also the applications in the materials, environmental, electronics and optics field.

  本发明涉及线性吡啶二氮杂环化合物，更特别涉及这些化合物中的寡吡啶二氮杂环化合物，以及获取它们的方法、它们的用途，以及它们还原为吡咯并利用所得的吡咯、吡啶二氮杂吡咯和寡吡咯化合物的用途。本发明特别涉及作为药物的用途，特别是用于治疗癌症、细菌感染或寄生虫感染等病理情况，以及在材料、环境、电子和光学领域的应用。
• POLYMER COMPOUND, MATERIAL FOR ELECTRONIC ELEMENTS, MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENTS, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20150249215A1

  公开（公告）日：2015-09-03

  Provided are a polymer compound, which comprises a copolymer containing at least a unit B, and a unit A and/or a unit C referring to repeating units A, B and C, and which has a weight-average molecular weight of from 50,000 to 1,500,000; a material for electronic devices and a material for organic electroluminescent devices comprising the compound; an organic electroluminescent device having an anode, a cathode and an organic thin film layer, wherein at least one organic thin film layer contains the polymer compound; a coating liquid containing the polymer compound and a solvent; and a method for producing an organic electroluminescent device using the coating liquid. Also provided is a polymer compound suitable to a coating method; a material for electronic devices and a material for organic electroluminescent devices comprising the compound; and an organic EL device, a coating liquid and a method for producing an organic EL device using the compound.

  提供了一种聚合物化合物，包括至少含有一个单位B的共聚物，以及重复单元A、B和C所指的单位A和/或单位C，其重量平均分子量为50,000至1,500,000；一种用于电子器件的材料和一种用于有机电致发光器件的材料，包括该化合物；一种有阳极、阴极和有机薄膜层的有机电致发光器件，其中至少一个有机薄膜层含有该聚合物化合物；一种含有该聚合物化合物和溶剂的涂层液；以及使用该涂层液制备有机电致发光器件的方法。还提供了一种适用于涂层方法的聚合物化合物；一种包括该化合物的电子器件材料和有机电致发光器件材料；以及一种有机EL器件、涂层液和使用该化合物制备有机EL器件的方法。
• Polymer compound, material for electronic elements, material for organic electroluminescent elements, and organic electroluminescent element
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US10038143B2

  公开（公告）日：2018-07-31

  Provided are a polymer compound, which comprises a copolymer containing at least a unit B, and a unit A and/or a unit C referring to repeating units A, B and C, and which has a weight-average molecular weight of from 50,000 to 1,500,000; a material for electronic devices and a material for organic electroluminescent devices comprising the compound; an organic electroluminescent device having an anode, a cathode and an organic thin film layer, wherein at least one organic thin film layer contains the polymer compound; a coating liquid containing the polymer compound and a solvent; and a method for producing an organic electroluminescent device using the coating liquid. Also provided is a polymer compound suitable to a coating method; a material for electronic devices and a material for organic electroluminescent devices comprising the compound; and an organic EL device, a coating liquid and a method for producing an organic EL device using the compound.

  本发明提供了一种聚合物化合物，它由至少含有一个单元 B 和一个单元 A 和/或一个单元 C 的共聚物组成，单元 A、B 和 C 的重量平均分子量在 50,000 至 1,500,000 之间；一种电子设备材料和一种有机电致发光器件材料，其中包含该化合物；具有阳极、阴极和有机薄膜层的有机电致发光器件，其中至少一个有机薄膜层含有该聚合物化合物；含有该聚合物化合物和溶剂的涂覆液；以及使用该涂覆液生产有机电致发光器件的方法。此外，还提供了适用于涂层方法的聚合物化合物；包含该化合物的电子器件材料和有机电致发光器件材料；以及有机电致发光器件、涂层液和使用该化合物生产有机电致发光器件的方法。
• US9034873B2
  申请人：——

  公开号：US9034873B2

  公开（公告）日：2015-05-19