2-[3-(Trifluoromethoxy)phenyl]furan

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2-[3-(Trifluoromethoxy)phenyl]furan
• 英文别名: 2-[3-(trifluoromethoxy)phenyl]furan
• 化学式: C₁₁H₇F₃O₂
• 分子量: 228.17
• InChiKey: WTPRQMMTWZYXLZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  22.4
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  3-三氟甲氧基苯胺 、 呋喃 在 iron oxide 、 亚硝酸特丁酯 作用下， 以 二甲基亚砜 为溶剂， 以75%的产率得到2-[3-(Trifluoromethoxy)phenyl]furan
  参考文献：
  名称：

  10.1002/chem.202401617

  摘要：

  A magnetically isolable iron oxide nanoparticles is introduced as an efficient heterogeneous photocatalyst for non‐directed C‒H arylation employing aryl diazonium salts as the aryl precursors. This first‐row transition metal‐based photocatalyst revealed versatile activities and is applicable to a wide range of substrates, demonstrating brilliant efficacy and superior recyclability. Detailed catalytic characterization describes the physical properties and redox behavior of the Fe‐catalyst. Adequate control experiments helped to establish the radical‐based mechanism for the C‒H arylation.

  DOI：

  10.1002/chem.202401617

文献信息

• 10.1002/chem.202401617
  作者：Mandal, Tanumoy、Chaturvedi, Ashwin、Azim, Aznur、Maji, Rohan、De Sarkar, Suman

  DOI：10.1002/chem.202401617

  日期：——

  A magnetically isolable iron oxide nanoparticles is introduced as an efficient heterogeneous photocatalyst for non‐directed C‒H arylation employing aryl diazonium salts as the aryl precursors. This first‐row transition metal‐based photocatalyst revealed versatile activities and is applicable to a wide range of substrates, demonstrating brilliant efficacy and superior recyclability. Detailed catalytic characterization describes the physical properties and redox behavior of the Fe‐catalyst. Adequate control experiments helped to establish the radical‐based mechanism for the C‒H arylation.