1,2-di(2'-anthryl)ethane | 64306-20-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,2-di(2'-anthryl)ethane
• 英文别名: 2-(2-anthracen-2-ylethyl)anthracene
• CAS: 64306-20-3
• 化学式: C₃₀H₂₂
• 分子量: 382.505
• InChiKey: XYQALRYMZPEFEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.08
• 重原子数：
  30.0
• 可旋转键数：
  3.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  1,2-di(2'-anthraquinoyl)ethylene 在 palladium on activated charcoal 、 重铬酸吡啶 氢气 、 Al(c-C6H11O)3 、 环己醇 作用下， 反应 113.0h， 生成 1,2-di(2'-anthryl)ethane
  参考文献：
  名称：

  Ions derived from dianthrylethane species. How the mode of linking affects the intramolecular electron transfer

  摘要：

  Chemical and electrochemical reduction of dianthryl compounds affords mono-, di, tri-, and tetraanions via successive electron-transfer processes. The diamagnetic or paramagnetic ions are characterized by NMR and ESR spectroscopy, respectively, by cyclic voltammetry, and by quenching reactions. The title dianthryl systems have in common that two anthracene units are linked by ethane bridges in a sterically variable fashion. It appears that the mode of linking drastically affects the rate of intramolecular electron-transfer processes in radical monoanions as well as the charge-storage behavior.

  DOI：

  10.1021/ja00004a009

文献信息

• Ions derived from dianthrylethane species. How the mode of linking affects the intramolecular electron transfer
  作者：Bardo Becker、Angelika Bohnen、Marianne Ehrenfreund、Werner Wohlfarth、Yoshiteru Sakata、Walter Huber、Klaus Muellen

  DOI：10.1021/ja00004a009

  日期：1991.2

  Chemical and electrochemical reduction of dianthryl compounds affords mono-, di, tri-, and tetraanions via successive electron-transfer processes. The diamagnetic or paramagnetic ions are characterized by NMR and ESR spectroscopy, respectively, by cyclic voltammetry, and by quenching reactions. The title dianthryl systems have in common that two anthracene units are linked by ethane bridges in a sterically variable fashion. It appears that the mode of linking drastically affects the rate of intramolecular electron-transfer processes in radical monoanions as well as the charge-storage behavior.