[(4R)-5-(diphenylphosphanylmethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl-diphenylphosphane

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [(4R)-5-(diphenylphosphanylmethyl)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl-diphenylphosphane
• 化学式: C₃₁H₃₂O₂P₂
• 分子量: 498.5
• InChiKey: VCHDBLPQYJAQSQ-UFXYQILXSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  35
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Method Of Reducing A Functional Group In An Oxidized Form
  申请人：Mignani Gerard

  公开号：US20080214857A1

  公开（公告）日：2008-09-04

  A novel method of reducing a functional group in an oxidised form. The invention relates more particularly to the reduction of aldehyde, ketone, ester, lactone, nitrile or phosphine oxide groups. The reduction method according to the invention is characterised in that it comprises exposing the substrate including the functional group to be reduced to the presence of a siloxane-type compound of the following formula (I), combined with a Lewis acid-type catalyst. In said formula (I):—R1 and R2, which are the same or different, are an alkyl, cycloalkyle or aryl group, —X is a digit from 0 to 50.

  一种在氧化形式中减少官能团的新方法。该发明更特别地涉及醛、酮、酯、内酯、腈或膦氧化物基团的还原。根据该发明的还原方法的特征在于，它包括将包括待还原的官能团的底物暴露于具有以下式（I）的硅氧烷类化合物和一种Lewis酸型催化剂的存在下。在所述式（I）中：—R1和R2，它们相同或不同，是烷基、环烷基或芳基，—X是从0到50的数字。
• VERFAHREN ZUR HERSTELLUNG VON 3-METHYLAMINO-1-(THIEN-2-YL)-PROPAN-1-OL
  申请人：BASF SE

  公开号：EP1670779B1

  公开（公告）日：2010-11-24
• US7169935B2
  申请人：——

  公开号：US7169935B2

  公开（公告）日：2007-01-30