N,N′-(1,3-phenylenebis(methylene))bis(pyridin-3-amine) | 1052074-13-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N′-(1,3-phenylenebis(methylene))bis(pyridin-3-amine)
• 英文别名: 1,3-bis(3-pyridylaminomethyl)benzene；1,3-bis(3-pyridylaminomrthyl)benzene；N-[[3-[(pyridin-3-ylamino)methyl]phenyl]methyl]pyridin-3-amine
• CAS: 1052074-13-1
• 化学式: C₁₈H₁₈N₄
• 分子量: 290.368
• InChiKey: NKWUMQFTAKJGKT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  49.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N,N′-(1,3-phenylenebis(methylene))bis(pyridin-3-amine) 在 硝酸 作用下， 以 甲醇 为溶剂， 反应 0.08h， 以71%的产率得到
  参考文献：
  名称：

  无机阴离子诱导的柔性双（吡啶基）离子盐的超分子结构和发光特性†

  摘要：

  具有长的柔性间隔基的四个双（吡啶基）有机分子的自组装， 1,4-双（2-吡啶基氨基甲基）苯（M1），1,4-双（3-吡啶基氨基甲基）苯（M2），1,3-双（2-吡啶基氨基甲基）苯（M3）和1,3-双（3-吡啶基氨基甲基）苯（M4），并且不同的无机酸（HNO 3和高氯酸4）导致形成八个盐，H 2 M1 2 2 + + ·2NO 3 - （1），H 2 M2 2 2 + + ·2NO 3 - （2），H 2 M3 2 2 + + ·2NO 3 −（3），H 2 M4 2 2 + + ·2NO 3 −（4），H 2 M1 2 2 + + ·2ClO 4 −（5），H 2 M2 2 2 + + ·2ClO 4 −（6），H 2 M3 2 2 + + ·2ClO 4 −（7）和H 2 M4 2 2 + + ·2ClO 4 - （8），其已通过元素分析，IR，TG，PL和单晶X射线衍射。盐类1，3和7

  DOI：

  10.1039/c1ce05628j
• 作为产物：
  描述：

  3-氨基吡啶 、 间苯二甲醛 以 甲苯 为溶剂， 生成 N,N′-(1,3-phenylenebis(methylene))bis(pyridin-3-amine)
  参考文献：
  名称：

  Syntheses, structures, and properties of silver(I) polymeric architectures assembled by [2+2] or [2+3] metallomacrocyclic motif and angular ligands

  摘要：

  Four new silver(I) polymeric architectures with dimeric and trimeric units namely [Ag-2(L1)(2)(NO3)(2)](n) (1) [Ag-2(L2)(2)(NO3)(2)](n) (2) {[Ag-3(L3)(2)(NO3)(2)](NO3)}(n) 2nCH(3)OH (3) and [Ag-4(L4)(4)](NO3)(4) 6CH(3)CN (4) (L1 = terephthalaldioxime L2 = isophthalaldioxime L3 = (E) N-[2-(pyridin-2-yl)isoindolin-1-yl-idene] pyridine-2-amine and L4 = 1 3-bis(3-pyridylaminomethyl)benzene) have been synthesized and characterized by the element analysis IR TG PL, and single-crystal X ray diffraction Each ligand acts as bidentate or tridentate mode and every two ligands ligates a pair of silver(I) ions or three resulting in [2+2] or [2+3] metallomacrocyclic motif Complexes 1 and 2 which assemble from similar angular ligand exhibit layer or chain structure extended via interconnection of the dimeric units by NO3- anions Complex 3 is a 1 D helical chain extended via interconnection of trimeric units by NO3- anions in which the trimeric unit is further stabilized by intracyclic Ag Ag and pi-pi interactions Two independent dimeric units in complex 4 are separately linked through hydrogen bonding into a 2-D twofold interpenetrating networks The investigation of luminescent properties demonstrates that complexes 2 3 and 4 exhibit intraligand emission bands in the blue green and purple light region at room temperature respectively (C) 2010 Elsevier Ltd All rights reserved

  DOI：

  10.1016/j.poly.2010.08.028

文献信息

• Syntheses and structures of copper(i) complexes based on CunXn (X = Br and I; n = 1, 2 and 4) units and bis(pyridyl) ligands with longer flexible spacer
  作者：Zhao-Peng Deng、Hui-Ling Qi、Li-Hua Huo、Seik Weng Ng、Hui Zhao、Shan Gao

  DOI：10.1039/c0dt00336k

  日期：——

  Structural analyses show that the eight complexes possess an increasing dimensionality from 0D (1–3) to 1D (4) to 2D (5–8), in which 1 and 2 contain a CuX unit, 2–7 contain a Cu2X2 unit and 8 contains a Cu4X4 unit. Such evolvement indicates that the conformation of flexible bis(pyridyl) ligands and the participation of triphenylphosphine (PPh3) as a second ligand take an essential role in the framework

  自组装四 双（吡啶基） 具有更长的柔性间隔基的配体： 1,4-双（3-吡啶基氨基甲基）苯（L1），1,4-双（2-吡啶基氨基甲基）苯（L2），1,3-双（3-吡啶基氨基甲基）苯（L3）和1,3-双（2-吡啶基氨基甲基）苯（L4），以及铜 （X = 溴和I）导致形成八个基于[Cu n X n ]的（X =溴和我; n = 1、2和4）配合物[Cu 2 I 2 L1（PPh 3）4 ]（1），[Cu 4 Cl 2 Br 2（L4）2（PPh 3）6 ]·（CH 3 CN）2（2），[Cu 2 I 2（L3）2 ]（3），[Cu 2 Br 2 L2（PPh 3）2 ]·（CH 2 Cl 2）2 } n（ 4），[CuI L1 ] n ·nCH 2 Cl 2（ 5），[CuI L1 ] n（ 6），[CuI L4 ] n（ 7）和[Cu 2 I 2 L4 ] n（ 8） ，已通过元素分析，IR，
• Structure and luminescence variations in Cd(II) mixed-ligands coordination compounds influenced by coordination modes of naphthalene-1,5-disulfonate and configuration of flexible bis(pyridyl) ligands
  作者：Jing Han、Li-Hua Huo、Zhao-Peng Deng、Shan Gao

  DOI：10.1016/j.poly.2017.01.032

  日期：2017.4

  In compounds 1 and 2, the short bis(pyridyl) ligands L1 and L2 join adjacent Cd(II) cations into “8” shaped chains while the short protonated L3 ligand in compound 3 only coordinates to Cd(II) cation in terminal mode. In contrast, the long bis(pyridyl) ligands L4 and L5 in compounds 4 and 5 connect adjacent Cd(II) cations into 44 layer motifs. The 1,5-NDS2− acts as counter-anions in compounds 1, 3

  在化合物1和2中，短的双（吡啶基）配体L1和L2将相邻的Cd（II）阳离子连接成“ 8”形链，而化合物3中的短质子化的L3配体仅在末端模式下与Cd（II）阳离子配位。相反，化合物4和5中的长双（吡啶基）配体L4和L5将相邻的Cd（II）阳离子连接到44个层的图案中。1,5-NDS2-在化合物1、3中充当抗衡阴离子，在化合物2、4和5中形成桥连阴离子，从而形成不同的超分子网络（1和3），44（2）和36（4）层，以及pcu net（5）。此外，固态发光特性表明化合物1-5表现出强发射，范围从387 nm到468 nm。短的双（吡啶基）配体L1和L2将相邻的Cd（II）阳离子连接成“ 8”形链，而化合物3中的短质子化的L3配体仅在末端模式下与Cd（II）阳离子配位。相反，化合物4和5中的长双（吡啶基）配体L4和L5将相邻的Cd（II）阳离子连接到44个层的图案中。1,5-NDS2-在化合物1、
• Inorganic anion induced supramolecular architectures and luminescent properties of flexible bis(pyridyl) based ionic salts
  作者：Zhao-Peng Deng、Hui-Ling Qi、Li-Hua Huo、Hui Zhao、Shan Gao

  DOI：10.1039/c1ce05628j

  日期：——

  Self-assembly of four bis(pyridyl) organic molecules with long flexible spacer, 1,4-bis(2-pyridylaminomethyl)benzene (M1), 1,4-bis(3-pyridylaminomethyl)benzene (M2), 1,3-bis(2-pyridylaminomethyl)benzene (M3) and 1,3-bis(3-pyridylaminomethyl)benzene (M4), and different inorganic acids (HNO3 and HClO4) leads to the formation of eight salts, H2M122++·2NO3− (1), H2M222++·2NO3− (2), H2M322++·2NO3− (3),

  具有长的柔性间隔基的四个双（吡啶基）有机分子的自组装， 1,4-双（2-吡啶基氨基甲基）苯（M1），1,4-双（3-吡啶基氨基甲基）苯（M2），1,3-双（2-吡啶基氨基甲基）苯（M3）和1,3-双（3-吡啶基氨基甲基）苯（M4），并且不同的无机酸（HNO 3和高氯酸4）导致形成八个盐，H 2 M1 2 2 + + ·2NO 3 - （1），H 2 M2 2 2 + + ·2NO 3 - （2），H 2 M3 2 2 + + ·2NO 3 −（3），H 2 M4 2 2 + + ·2NO 3 −（4），H 2 M1 2 2 + + ·2ClO 4 −（5），H 2 M2 2 2 + + ·2ClO 4 −（6），H 2 M3 2 2 + + ·2ClO 4 −（7）和H 2 M4 2 2 + + ·2ClO 4 - （8），其已通过元素分析，IR，TG，PL和单晶X射线衍射。盐类1，3和7
• Syntheses, structures, and properties of silver(I) polymeric architectures assembled by [2+2] or [2+3] metallomacrocyclic motif and angular ligands
  作者：Zhao-Peng Deng、Li-Hua Huo、Li-Na Zhu、Hui Zhao、Shan Gao

  DOI：10.1016/j.poly.2010.08.028

  日期：2010.11

  Four new silver(I) polymeric architectures with dimeric and trimeric units namely [Ag-2(L1)(2)(NO3)(2)](n) (1) [Ag-2(L2)(2)(NO3)(2)](n) (2) [Ag-3(L3)(2)(NO3)(2)](NO3)}(n) 2nCH(3)OH (3) and [Ag-4(L4)(4)](NO3)(4) 6CH(3)CN (4) (L1 = terephthalaldioxime L2 = isophthalaldioxime L3 = (E) N-[2-(pyridin-2-yl)isoindolin-1-yl-idene] pyridine-2-amine and L4 = 1 3-bis(3-pyridylaminomethyl)benzene) have been synthesized and characterized by the element analysis IR TG PL, and single-crystal X ray diffraction Each ligand acts as bidentate or tridentate mode and every two ligands ligates a pair of silver(I) ions or three resulting in [2+2] or [2+3] metallomacrocyclic motif Complexes 1 and 2 which assemble from similar angular ligand exhibit layer or chain structure extended via interconnection of the dimeric units by NO3- anions Complex 3 is a 1 D helical chain extended via interconnection of trimeric units by NO3- anions in which the trimeric unit is further stabilized by intracyclic Ag Ag and pi-pi interactions Two independent dimeric units in complex 4 are separately linked through hydrogen bonding into a 2-D twofold interpenetrating networks The investigation of luminescent properties demonstrates that complexes 2 3 and 4 exhibit intraligand emission bands in the blue green and purple light region at room temperature respectively (C) 2010 Elsevier Ltd All rights reserved