3-Benzyl-1,5-dihydro-1,5-benzodiazepine-2,4-dione

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯二氮卓类
• 英文名称: 3-Benzyl-1,5-dihydro-1,5-benzodiazepine-2,4-dione
• 化学式: C₁₆H₁₄N₂O₂
• 分子量: 266.299
• InChiKey: JWJIRPBZVBRHDF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-(N-叔丁氧羰基氨基)苯甲酸 、 4-苄基噁唑烷-2,5-二酮 在 盐酸 、 4-二甲氨基吡啶 、 N,N'-二环己基碳二亚胺 作用下， 生成 3-Benzyl-1,5-dihydro-1,5-benzodiazepine-2,4-dione
  参考文献：
  名称：

  新型应用酸酐N-羧基氨基酸：合成1,4-苯并二氮杂-2,5-二酮

  摘要：

  通过将氨基酸N-羧酸酐（NCA）与Boc-邻氨基苯甲酸偶合，然后将Boc基团脱保护并通过Boc脱保护，从而完成了1,4-苯并二氮杂-2,5-二酮（BZD）的新合成方法。环膨胀。

  DOI：

  10.1016/s0040-4039(00)74168-2

文献信息

• Polarizing plate composition, polarizing plate protective film, polarizer, polarizing plate, and liquid crystal display device
  申请人：FUJIFILM Corporation

  公开号：US10254456B2

  公开（公告）日：2019-04-09

  A polarizing plate composition, a polarizing plate protective film, a polarizer, a polarizing plate, and a liquid crystal display device contain a compound represented by the following Formula (I). In Formula (I), R represents a specific substituent, and each of EWG1 and EWG2 represents an electron-withdrawing group. EWG1 and EWG2 may form a ring by being bonded to each other. Here, there is no such case where EWG1 and EWG2 become the following group by being bonded to each other and form a ring by being bonded to a carbon atom substituted with R. Each of Rx and Ry represents a hydrogen atom or a substituent. * represents a position of bonding to a carbon atom substituted with R.

  一种偏光板组合物、偏光板保护膜、偏光板、偏光板和液晶显示装置含有下式 (I) 所代表的化合物。 在式（I）中，R 代表一个特定的取代基，EWG1 和 EWG2 分别代表一个抽电子基团。EWG1 和 EWG2 可通过相互键合形成一个环。在此，不存在 EWG1 和 EWG2 通过相互键合而成为下一个基团，并通过与被 R 取代的碳原子键合而形成环的情况。 Rx 和 Ry 各自代表氢原子或取代基。* 代表与被 R 取代的碳原子成键的位置。
• POLARIZING PLATE COMPOSITION, POLARIZING PLATE PROTECTIVE FILM, POLARIZER, POLARIZING PLATE, AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20160370523A1

  公开（公告）日：2016-12-22

  A polarizing plate composition, a polarizing plate protective film, a polarizer, a polarizing plate, and a liquid crystal display device contain a compound represented by the following Formula (I). In Formula (I), R represents a specific substituent, and each of EWG 1 and EWG 2 represents an electron-withdrawing group. EWG 1 and EWG 2 may form a ring by being bonded to each other. Here, there is no such case where EWG 1 and EWG 2 become the following group by being bonded to each other and form a ring by being bonded to a carbon atom substituted with R. Each of Rx and Ry represents a hydrogen atom or a substituent. * represents a position of bonding to a carbon atom substituted with R.